Source-verified familyIdentity or context cautions

Co₂(DOBDC) / Co–MOF-74 / CPO-27-Co

This family merges chemical shorthand and formula variants only after verification against source articles. Per-paper composition and phase details remain separate below.

7primary papers
7material records
40linked samples
59linked measurements
271linked results
2017–2025publication span

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  • Several formulas or formula descriptions are reported

This metal-specific MOF-74/CPO-27 discovery family includes source-verified coordinated-solvent states, whose full formula and activation state remain attached to each record. Reviewed members are classified as 3D frameworks containing 1D channels; pore-direction and structural descriptions remain visible below. Guest-loaded, substituted-linker, mixed-metal and phase-unverified M₂(DOBDC) films remain separate materials.

Evidence coverage

Paper counts are material-linked through samples and measurements; technique groups are not value rankings.

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Primary papers

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7 papers

Per-paper identity records

Raw names, formulas and structural assignments remain separate; no consensus value is inferred.

Show 7 material identity records
Paper and reported nameFormula and componentsStructure contextSource
Co-MOF-742025 · Ligand engineering of Co-MOF-74 with hexaaminotriphenylene for enhanced oxygen reduction reaction in zinc-air batteriesCo-MOF-74; cobalt 2,5-dihydroxyterephthalate MOFCo active sites, assigned as Co-O5 coordination environment · 2,5-dihydroxyterephthalic acid / H4DOBDC-derived linker3D · PristineMOF-74/CPO-27 type framework; hexagonal prism morphology; XRD peaks assigned to (110), (300), and (511).2 · Experimental; Results and discussion · Fig. 1(a), Fig. 1(f)
Co-MOF-74 nanoparticles2023 · Toward High-Performance Metal–Organic-Framework-Based Quasi-Solid-State Electrolytes: Tunable Structures and Electrochemical PropertiesCo2(DOBDC)Open Co2+ sites; redox-active metal centre. · DOBDC linker from H4DOBDC3D · PristineMOF-74 framework confirmed by PXRD.SI p.S-19 · Supplementary Figures and Tables · Figure S6
MOF-74(Co)2021 · MOF-74(M) Films Obtained through Vapor-Assisted Conversion - Impact on Crystal Orientation and Optical PropertiesCo-MOF-74; framework built from divalent Co ions and 2,5-dihydroxyterephthalateCo2+ metal-oxo columns · 2,5-dihydroxyterephthalic acid / 2,5-dihydroxyterephthalate (DOT)3D · PristineMOF-74 structure; XRD patterns agree with MOF-74(Co) bulk material5900 · Results and Discussion · Figure 4 and Figures S24-S25
Co-MOF-74 / CPO-27-Co2020 · Humidity-mediated anisotropic proton conductivity through the 1d channels of co-mof-74Co2(dobdc), dobdc = 2,5-dioxido-1,4-benzenedicarboxylateCo(II) ions; penta-coordinated by linkers in the solvent-free state with an open sixth coordination site toward the pore interior · 2,5-dioxido-1,4-benzenedicarboxylate, prepared from 2,5-dihydroxy-terephthalic acid (DHBDC)3D · PristineMOF-74 honeycomb framework; trigonal space group 148, R-3; linear 1D micropores with ca. 1.1 nm hexagonal cross-section running parallel to the crystallographic c axis.1-2 · Introduction · Figure 1
MOF-74(Co)2019 · A highly crystalline anthracene-based MOF-74 series featuring electrical conductivity and luminescencenot explicitly reportedCo2+ in regular MOF-74 metal-oxo chains · 2,5-dihydroxy-1,4-benzenedicarboxylic acid / 2,5-dihydroxyterephthalic acid3D · PristineOriginal MOF-74 isostructure prepared as pristine control for conductivity comparison.20949-20951 · Abstract; Results and discussion · Table 1
Co-MOF-742018 · High Proton Mobility with High Directionality in Isolated Channels of MOF-74Co-MOF-74; Co2(dobdc)-type framework, exact empirical formula not reported in this paperCo2+ open-metal-site nodes · 2,5-dioxido-1,4-benzenedicarboxylate / DOBDC-derived linker3D · PristineMOF-74/CPO-27-type framework with isolated one-dimensional channels aligned along the crystallographic c-axis and separated by framework walls.p001 / journal page 35354 · Introduction
Co2(DOBDC)(DMF)22017 · Is iron unique in promoting electrical conductivity in MOFs?Co2(C8H2O6)(C3H7NO)2(CH2Cl2)0.8Co2+ · DOBDC; DMF-coordinated3D · Pristinehoneycomb structure with 1D tubular pores4451 · Experimental results · Fig. 1