Structure–Property Engineering of Redox-Active Tetrathiafulvalene- and Bipyridine-Based Metal–Organic Frameworks for Battery Cathodes
Wakamatsu K., Oshima H., Kobayashi N. et al. · Chemistry - A European Journal · 2026
Reported here: Cd2(TTFTB) MOF
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5 papers
Wakamatsu K., Oshima H., Kobayashi N. et al. · Chemistry - A European Journal · 2026
Reported here: Cd2(TTFTB) MOF
Wang Y., Miao X., Kempler P.A. et al. · Journal of the American Chemical Society · 2025
Reported here: Cd2(TTFTB)
Ukaj D., Bunzen H., Berger J. et al. · Chemistry of Materials · 2021
Reported here: Cd2TTFTB
Sun L., Park S.S., Sheberla D. et al. · Journal of the American Chemical Society · 2016
Reported here: Cd2(TTFTB)
Park S.S., Hontz E.R., Sun L. et al. · Journal of the American Chemical Society · 2015
Reported here: Cd2(TTFTB)
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Raw names, formulas and structural assignments remain separate; no consensus value is inferred.
| Paper and reported name | Formula and components | Structure context | Source |
|---|---|---|---|
| Cd2(TTFTB) MOF2026 · Structure–Property Engineering of Redox-Active Tetrathiafulvalene- and Bipyridine-Based Metal–Organic Frameworks for Battery Cathodes | C34H19Cd2O9.5S4Cd2+ nodes · TTFTB tetracarboxylate linker | unknown · PristineCd-TTFTB framework with pi-stacked TTF columns and shortened S...S contacts | S38 · Table S1 · Table S1 |
| Cd2(TTFTB)2025 · Screening-Enabled Chemiresistive Moisture Sensing with Tetrathiafulvalene-Based Electrically Conductive Metal–Organic Frameworks | Cd2(TTFTB)Cd2+ metal-carboxylate chains; some metal ions coordinated by water · TTFTB4- = tetrathiafulvalene tetrabenzoate | 3D · PristineIsostructural microporous conductive MOF with nanoscale pores and pi-stacked TTF columns along the crystallographic c axis. | 48160 · Results and Discussion · Figure 3 |
| Cd2TTFTB2021 · Charge-Transfer-Induced Electrical Conductivity in a Tetrathiafulvalene-Based Metal-Organic Framework | Cd2TTFTB; TTFTB4- = tetrathiafulvalene tetrabenzoateCd2+ nodes in the isostructural M2TTFTB framework · TTFTB4- tetrathiafulvalene tetrabenzoate | 3D · PristineIsostructural M2TTFTB framework with infinite one-dimensional helical TTF pi-stacks and cylindrical one-dimensional pores aligned parallel to the TTFTB pi-stacks. | p002 / 2533 · Introduction · Figure 1 |
| Cd2(TTFTB)2016 · Measuring and Reporting Electrical Conductivity in Metal-Organic Frameworks: Cd2(TTFTB) as a Case Study | Cd2(TTFTB)cadmium-carboxylate chains · TTFTB4- = tetrathiafulvalene tetrabenzoate / tetrathiafulvalene tetracarboxylate | 3D · PristineAnisotropic semiconducting MOF; TTF moieties form one-dimensional helical pi-stacks parallel to crystallographic c axis. | p001-002 / 14772-14773 · Introduction · Figure 1 |
| Cd2(TTFTB)2015 · Cation-dependent intrinsic electrical conductivity in isostructural tetrathiafulvalene-based microporous metal-organic frameworks | [Cd2(C34H16O8S4)(mu2-OH2)(H2O)]·(DMF)1.5(H2O)2; activated formula C34H19Cd2O9.5S4Helical cadmium-oxygen chains; alternating seven- and six-coordinate Cd ions with a bridging water ligand · TTFTB4- = tetrathiafulvalene tetrabenzoate, from H4TTFTB | 3D · PristineIsostructural M2(TTFTB) framework with pi-stacked TTF columns; Cd analogue has alternating seven- and six-coordinate metal ions. | p002 / article p.1775 · Results · Figure 2 |