Linker-Based Bandgap Tuning in Conductive MOF Solid Solutions
Choi J.Y., Wang M., Check B. et al. · Small · 2023
Reported here: Cu-HAB / Cu3(HAB)2
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6 papers
Choi J.Y., Wang M., Check B. et al. · Small · 2023
Reported here: Cu-HAB / Cu3(HAB)2
Ross R.D., Sheng H., Ding Y. et al. · Journal of the American Chemical Society · 2022
Reported here: Cu-HAB
Choi J.Y., Park J. · ACS Applied Electronic Materials · 2021
Reported here: Cu3(HAB)2
Liu C., Gu Y., Liu C. et al. · ACS Sensors · 2021
Reported here: missing-linker amorphous Cu-HAB (aCu-HAB)
Hinckley A.C., Park J., Gomes J. et al. · Journal of the American Chemical Society · 2020
Reported here: Cu-HAB
Park J., Chen Z., Flores R.A. et al. · ACS Applied Materials and Interfaces · 2020
Reported here: Cu-HAB
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Raw names, formulas and structural assignments remain separate; no consensus value is inferred.
| Paper and reported name | Formula and components | Structure context | Source |
|---|---|---|---|
| Cu-HAB / Cu3(HAB)22023 · Linker-Based Bandgap Tuning in Conductive MOF Solid Solutions | Cu3(HAB)2Copper nodes · HAB (hexaaminobenzene) | 2D · PristineHAB end-member of the Cu3(HAB)x(TATHB)2-x hexagonal series; calculated in-plane electronic structure is metallic. | S2 · Synthesis of Cu3(HAB)x(TATHB)2-x |
| Cu-HAB2022 · Operando Elucidation of Electrocatalytic and Redox Mechanisms on a 2D Metal Organic Framework Catalyst for Efficient Electrosynthesis of Hydrogen Peroxide in Neutral Media | Cu3HAB2 inferred from M3HAB2 family; exact formula not restated for this sampleCu-N4 nodes · Hexaaminobenzene / HAB | 2D · PristineDirectly analogous structure to Ni-HAB; PXRD shown with Ni-HAB and Ni-HITP. | 15847 · Results · Figure S3 and Figure S8 |
| Cu3(HAB)22021 · Enhancing Electrical Conductivity of Semiconducting MOFs via Defect Healing | Cu3(HAB)2Cu nodes, square planar geometry · deprotonated hexaaminobenzene (HAB) | 2D · Pristine2D honeycomb-eclipsed conductive MOF; synchrotron PXRD refined against Pawley fit agreed with the reported structure. | 2 · Introduction · Figure 1 |
| missing-linker amorphous Cu-HAB (aCu-HAB)2021 · Missing-Linker 2D Conductive Metal Organic Frameworks for Rapid Gas Detection | Cu-HAB missing-linker framework; empirical formula not reportedCu ions · oxidized hexaaminobenzene-derived linker mixture | 2D · PristineIsostructural missing-linker amorphous M-HAB analogue used for vapour/RH response comparison. | 432-433 · Relative humidity detection · Figure 3b |
| Cu-HAB2020 · Air-Stability and Carrier Type in Conductive M3(Hexaaminobenzene)2,(M = Co, Ni, Cu) | Cu3(hexaaminobenzene)2 / M3(HAB)2 with M = Cudivalent copper cations · hexaaminobenzene (HAB) | 2D · PristineSquare-planar M-HAB conductive MOF; same crystal packing structure as the Co and Ni analogues. | 11128 · Conclusion |
| Cu-HAB2020 · Two-Dimensional Conductive Ni-HAB as a Catalyst for the Electrochemical Oxygen Reduction Reaction | Cu-HAB 2D M-N4/HAB framework; empirical formula not statedCu species in square-planar M-N4 units · hexaaminobenzene (HAB) | 2D · PristineConductive 2D M-HAB framework with Cu as the metal species; PXRD is stated to agree with previously reported 2D honeycomb eclipsed structures. | 39076 · Results and Discussion - Synthesis of Ni-HAB-H and Ni-HAB-L · Figure 2; Figure S3 |