Primary study2025
Metal–Organic Frameworks Coordination-Oriented Polymer Dielectrics for Neuromorphic Vision Sensors
Zhu D., Du J., Peng Z. et al. · SmartMat · 2025
Reported here: MOF-545
Source-verified familyIdentity or context cautions
PCN-222 / MOF-545
This family merges chemical shorthand and formula variants only after verification against source articles. Per-paper composition and phase details remain separate below.
5primary papers
14material records
32linked samples
50linked measurements
207linked results
2020–2025publication span
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- Several formulas or formula descriptions are reported
- More than one known dimensionality is reported
- Pristine, composite, derived or model contexts are mixed
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Paper counts are material-linked through samples and measurements; technique groups are not value rankings.
Diffraction Structure4 papers6 measurements · 18 resultsMicroscopy Morphology4 papers6 measurements · 11 resultsPorosity4 papers6 measurements · 26 resultsSpectroscopy4 papers7 measurements · 18 resultsElectrochemistry Application2 papers8 measurements · 51 resultsOther2 papers2 measurements · 12 resultsSensing Application2 papers14 measurements · 59 resultsElectrical Transport1 paper1 measurement · 12 results
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Primary study2022
Polythiophene hybrid film with zirconium–porphyrin metal–organic framework for improved charge carrier transport and NO2 gas sensing
Lee J.I., Kim M., Park K.C. et al. · Materials Chemistry and Physics · 2022
Reported here: Fe porous coordination network 222 (PCN-222) · PCN-222/P3HT blend film
Primary study2021
Effective visible-light CO2 photoreduction over (metallo)porphyrin-based metal–organic frameworks to achieve useful hydrocarbons
Hariri R., Dehghanpour S. · Applied Organometallic Chemistry · 2021
Reported here: PCN-222 (no metal) · PCN-222(Co) · PCN-222(Cu) · PCN-222(Fe) · PCN-222(Ni)
Primary study2020
Colloidal crystal engineering with metal–organic framework nanoparticles and DNA
Wang S., Park S.S., Buru C.T. et al. · Nature Communications · 2020
Reported here: Ag-stabilized PCN-222 2D nanorod superlattice · PCN-222 / MOF-545 zirconium porphyrinic MOF nanorods
Primary study2020
Ultrasmall Au(0) Inserted Hollow PCN-222 MOF for the High-Sensitive Detection of Estradiol
Biswas S., Chen Y., Xie Y. et al. · Analytical Chemistry · 2020
Reported here: AuHPCN-222 · AuSPCN-222 · hollow PCN-222 (HPCN-222) · solid PCN-222 (SPCN-222)
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Show 14 material identity records
| Paper and reported name | Formula and components | Structure context | Source |
|---|---|---|---|
| MOF-5452025 · Metal–Organic Frameworks Coordination-Oriented Polymer Dielectrics for Neuromorphic Vision Sensors | Zr6O8(H2O)8(TCPP-H2)2Zr6O8(H2O)8 clusters · TCPP-H2 | unknown · PristineZr MOF control with different particle sizes and rod-like morphologies. | 6 · 3.2 Preparation and Light Detection Properties of NeuVS Devices · Supporting Information Figure S17E |
| Fe porous coordination network 222 (PCN-222)2022 · Polythiophene hybrid film with zirconium–porphyrin metal–organic framework for improved charge carrier transport and NO2 gas sensing | Not specifiedZr6 cluster nodes with Fe(III) porphyrin centres · 5,10,15,20-tetrakis-(4-carboxyphenyl)-porphine-Fe(III) chloride (Fe-TCPP-Cl) | 3D · Pristine3D hemoglobin-like zirconium-porphyrin MOF; powder XRD matched the simulated PCN-222 pattern. | 2 · Introduction |
| PCN-222/P3HT blend film2022 · Polythiophene hybrid film with zirconium–porphyrin metal–organic framework for improved charge carrier transport and NO2 gas sensing | Not specifiedPCN-222 Zr6/Fe-porphyrin component · Fe-TCPP-Cl within PCN-222; P3HT polymer matrix | 3D · CompositeComposite organic semiconductor/MOF thin film with PCN-222 nanocrystals embedded in P3HT. | 4 · 3. Results and discussion · Fig. 3 |
| PCN-222 (no metal)2021 · Effective visible-light CO2 photoreduction over (metallo)porphyrin-based metal–organic frameworks to achieve useful hydrocarbons | not reported; Zr6-cluster porphyrinic PCN-222 without porphyrinic metalZr6 oxo clusters; no porphyrinic metal centre · free-base tetrakis(4-carboxyphenyl)porphyrin (H2TCPP) | 3D · PristinePorphyrinic PCN-222 control framework | 2 · Photocatalytic reaction · Figure 6; Table 1 |
| PCN-222(Co)2021 · Effective visible-light CO2 photoreduction over (metallo)porphyrin-based metal–organic frameworks to achieve useful hydrocarbons | not reported; Zr6-cluster PCN-222 with CoTCPP linkerZr6 oxo clusters and Co porphyrinic metal centres · tetrakis(4-carboxyphenyl)porphyrin metallated with Co (CoTCPP / MTCPP) | 3D · Pristine3D mesoporous needle-shaped PCN-222(M) framework; PXRD confirms PCN-222(M) structure | 2-3 · Introduction; Characterization of catalyst · Figure 1; Figure 2 |
| PCN-222(Cu)2021 · Effective visible-light CO2 photoreduction over (metallo)porphyrin-based metal–organic frameworks to achieve useful hydrocarbons | not reported; Zr6-cluster PCN-222 with CuTCPP linkerZr6 oxo clusters and Cu porphyrinic metal centres · tetrakis(4-carboxyphenyl)porphyrin metallated with Cu (CuTCPP / MTCPP) | 3D · Pristine3D mesoporous needle-shaped PCN-222(M) framework; PXRD confirms PCN-222(M) structure | 2-3 · Introduction; Characterization of catalyst · Figure 1; Figure 2 |
| PCN-222(Fe)2021 · Effective visible-light CO2 photoreduction over (metallo)porphyrin-based metal–organic frameworks to achieve useful hydrocarbons | not reported; Zr6-cluster PCN-222 with FeTCPP linkerZr6 oxo clusters and Fe porphyrinic metal centres · tetrakis(4-carboxyphenyl)porphyrin metallated with Fe (FeTCPP / MTCPP) | 3D · Pristine3D mesoporous needle-shaped PCN-222(M) framework; PXRD confirms PCN-222(M) structure | 2-3 · Introduction; Characterization of catalyst · Figure 1; Figure 2 |
| PCN-222(Ni)2021 · Effective visible-light CO2 photoreduction over (metallo)porphyrin-based metal–organic frameworks to achieve useful hydrocarbons | not reported; Zr6-cluster PCN-222 with NiTCPP linkerZr6 oxo clusters and Ni porphyrinic metal centres · tetrakis(4-carboxyphenyl)porphyrin metallated with Ni (NiTCPP / MTCPP) | 3D · Pristine3D mesoporous needle-shaped PCN-222(M) framework; PXRD confirms PCN-222(M) structure | 2-3 · Introduction; Characterization of catalyst · Figure 1; Figure 2 |
| Ag-stabilized PCN-222 2D nanorod superlattice2020 · Colloidal crystal engineering with metal–organic framework nanoparticles and DNA | PCN-222 nanorods + DNA linkers + Ag+ stabilizationPCN-222 Zr6 clusters; Ag+ stabilises DNA bonds · TCPP porphyrin linkers and DNA linker strands | 2D · CompositeAg+-stabilized PCN-222 nanorod superlattice retaining PCN-222 crystallinity after thermal/chemical treatments and catalysis. | 6 · Photocatalytic activity of the 2D PCN-222 nanorod superlattices · Fig. 5 |
| AuHPCN-2222020 · Ultrasmall Au(0) Inserted Hollow PCN-222 MOF for the High-Sensitive Detection of Estradiol | Au(0)-functionalised hollow PCN-222; XPS Au atomic percent 1.03%Zr-based PCN-222 nodes plus subnanometre Au(0) anchored in porphyrin coordination sites · TCPP porphyrin linker with postsynthetically inserted Au(0) | 3D · CompositeAu inserted into hollow PCN-222 with retained PCN-222 PXRD; XPS Au 4f peaks at 83.59 and 87.23 eV attributed to porphyrin-coordinated Au(0); EDX maps show homogeneous Zr, C, N, O and Au distribution. | rendered page 3 / article p.4568 · Results and Discussion · Figure 1b,c; Figure 2d; Table S1 |
| AuSPCN-2222020 · Ultrasmall Au(0) Inserted Hollow PCN-222 MOF for the High-Sensitive Detection of Estradiol | Au(0)-functionalised solid PCN-222Zr-based PCN-222 nodes plus postsynthetically inserted Au(0) · TCPP porphyrin linker with postsynthetically inserted Au(0) | 3D · CompositeAu-inserted solid PCN-222 with retained MOF PXRD, used as morphology control against AuHPCN-222. | rendered page 3 / article p.4568 · Results and Discussion · Figure 1a; Figure 2b |
| hollow PCN-222 (HPCN-222)2020 · Ultrasmall Au(0) Inserted Hollow PCN-222 MOF for the High-Sensitive Detection of Estradiol | Zr-porphyrin MOF, PCN-222 structureZr-based nodes from zirconium tetrachloride · meso-tetra(carboxyphenyl)porphyrin (TCPP) | 3D · PristinePowder X-ray diffraction peaks at 4.9, 7.2, 8.37 and 9.79 degrees match reported PCN-222; morphology described as hollow porous tube assembled from smaller nanocubes. | rendered page 2 / article p.4567 · Experimental Section; Results and Discussion · Figure 1a |
| PCN-222 / MOF-545 zirconium porphyrinic MOF nanorods2020 · Colloidal crystal engineering with metal–organic framework nanoparticles and DNA | Zr6O8(H2O)8(TCPP-H2)2Zr6 secondary building units · TCPP-H2 = tetrakis(4-carboxyphenyl)porphyrin linker | 3D · PristineRod-shaped porphyrinic zirconium MOF, also referred to as PCN-222/MOF-545, assembled into 2D hexagonal or tetragonal superlattices. | 4 · Building block shape as a structure-influencing factor · Fig. 4d |
| solid PCN-222 (SPCN-222)2020 · Ultrasmall Au(0) Inserted Hollow PCN-222 MOF for the High-Sensitive Detection of Estradiol | Zr-porphyrin MOF, PCN-222 structureZr-based nodes from zirconium tetrachloride · meso-tetra(carboxyphenyl)porphyrin (TCPP) | 3D · PristinePXRD pattern assigned to PCN-222; solid morphology used as comparison to hollow PCN-222. | rendered page 2 / article p.4567 · Experimental Section · Figure 1a |