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Co/Ni–HITP family

This family merges chemical shorthand and formula variants only after verification against source articles. Per-paper composition and phase details remain separate below.

5primary papers
18material records
30linked samples
84linked measurements
257linked results
2020–2026publication span

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  • Several formulas or formula descriptions are reported
  • Pristine, composite, derived or model contexts are mixed

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5 papers

Primary study2025

A conductive MOF with bimetallic spontaneously recycled systems as a signal enhancer for the ultrasensitive detection of T-2 toxin using an electrochemical aptasensor

Yu H., Xu G., Liu Y. et al. · Microchemical Journal · 2025

Reported here: Au-Thi-Au@C-Ni1.5Co1.5(HITP)2 · C-Ni1.5Co1.5(HITP)2 · CP1 bioconjugate/C-Ni1.5Co1.5(HITP)2 aptasensor · Ni0.6Co2.4(HITP)2 · Ni2.4Co0.6(HITP)2

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Show 18 material identity records
Paper and reported nameFormula and componentsStructure contextSource
Co/Ni-HITP2026 · In-situ growth of high-crystallinity M3(hexaaminotriphenylene)2 (M = Co, Ni) thin film for field-effect transistor-based glucose biosensorM3(HITP)2, M = Co, NiCo and Ni bimetallic centres · 2,3,6,7,10,11-hexaaminotriphenylene (HITP)2D · PristineBimetallic conductive HITP MOF thin film; XRD peaks attributed to M3(HITP)2 with nanosheet film morphology.1 · Abstract
Au-Thi-Au@C-Ni1.5Co1.5(HITP)22025 · A conductive MOF with bimetallic spontaneously recycled systems as a signal enhancer for the ultrasensitive detection of T-2 toxin using an electrochemical aptasensorAu/Thi/Au@Ni1.5Co1.5(HITP)2Ni/Co MOF nodes plus Au nanoparticles · HITP; thionine signal molecule2D · CompositeComposite signal probe formed by loading AuNPs and thionine onto C-Ni1.5Co1.5(HITP)2 through Au-S binding.6 · 3.3 · Fig. 3A-B
C-Ni1.5Co1.5(HITP)22025 · A conductive MOF with bimetallic spontaneously recycled systems as a signal enhancer for the ultrasensitive detection of T-2 toxin using an electrochemical aptasensorNi1.5Co1.5(HITP)2Ni/Co mixed metal nodes · HITP2D · PristineConductive bimetallic HITP framework selected as the optimal signal-amplification material.5 · 3.2 · Fig. 2
CoNi-HITP2025 · Micro-sized conductive metal–organic framework nanosheets for the electrochemical hydrogen evolution reaction in acidic mediaCoNi-HITP mixed-metal HITP frameworkCo and Ni · HITP2D · PristineBimetallic HITP conductive MOF nanosheets with Co and Ni uniformly distributed; Co/Ni atomic ratio 1.82 by ICP.p004 / 42276 · Results and discussion · Fig. 1l
CP1 bioconjugate/C-Ni1.5Co1.5(HITP)2 aptasensor2025 · A conductive MOF with bimetallic spontaneously recycled systems as a signal enhancer for the ultrasensitive detection of T-2 toxin using an electrochemical aptasensorCP1/Au-Thi-Au@Ni1.5Co1.5(HITP)2 on DNA-modified Au/GCENi/Co MOF nodes and Au electrodeposited/AuNP components · HITP plus DNA aptamer/probe layers and BSAunknown · CompositeElectrochemical aptasensor assembly using the conductive bimetallic MOF composite as signal enhancer.3 · 2.3 · Scheme 1B
Ni0.6Co2.4(HITP)22025 · A conductive MOF with bimetallic spontaneously recycled systems as a signal enhancer for the ultrasensitive detection of T-2 toxin using an electrochemical aptasensorNi0.6Co2.4(HITP)2Ni/Co mixed metal nodes with excess Co · HITP2D · PristineHigh-Co member of the NixCo3-x(HITP)2 series; main text states excess Co disrupts the Ni3(HITP)2 structure.4 · 3.1 · Fig. 1
Ni2.4Co0.6(HITP)22025 · A conductive MOF with bimetallic spontaneously recycled systems as a signal enhancer for the ultrasensitive detection of T-2 toxin using an electrochemical aptasensorNi2.4Co0.6(HITP)2Ni/Co mixed metal nodes · HITP2D · PristineCo-doped Ni3(HITP)2 analogue; characteristic Ni3(HITP)2 PXRD peaks retained according to the main-text summary of Fig. S1.3 · 3.1 · Fig. 1A
Co0.6Ni2.4(HITP)22024 · High-Performance H2S Sensors to Detect SF6 LeakageCo0.6Ni2.4(HITP)2Co/Ni mixed nodes, nominal Co:Ni = 1:4 · HITP2D · PristineMixed-metal 2D CoxNi3-x(HITP)2 phase.22 · Table S1 · Table S1
Co1.2Ni1.8(HITP)22024 · High-Performance H2S Sensors to Detect SF6 LeakageCo1.2Ni1.8(HITP)2Co/Ni mixed nodes, nominal Co:Ni = 2:3 · HITP2D · PristineMixed-metal 2D CoxNi3-x(HITP)2 phase.22 · Table S1 · Table S1
Co1.5Ni1.5(HITP)22024 · High-Performance H2S Sensors to Detect SF6 LeakageCo1.5Ni1.5(HITP)2Co/Ni mixed nodes, nominal Co:Ni = 1:1 · HITP2D · PristineMixed-metal 2D CoxNi3-x(HITP)2 phase.22 · Table S1 · Table S1
Co1.8Ni1.2(HITP)22024 · High-Performance H2S Sensors to Detect SF6 LeakageCo1.8Ni1.2(HITP)2Co/Ni mixed nodes, optimal nominal Co:Ni = 3:2 · HITP2D · PristineGenuine bimetallic 2D layered honeycomb phase; EDS mapping shows homogeneous C, N, Co and Ni distribution.3 · 2.1. Sample Preparation and Characterization · Figure 1
Co2.4Ni0.6(HITP)22024 · High-Performance H2S Sensors to Detect SF6 LeakageCo2.4Ni0.6(HITP)2Co/Ni mixed nodes, nominal Co:Ni = 4:1 · HITP2D · PristineMixed-metal 2D CoxNi3-x(HITP)2 phase.22 · Table S1 · Table S1
CoxNi3-x(HITP)2 mixed-metal conductive MOF family2024 · High-Performance H2S Sensors to Detect SF6 LeakageCoxNi3-x(HITP)2Co and Ni square-planar metal nodes · 2,3,6,7,10,11-hexaiminotriphenylene (HITP)2D · PristineLayered 2D honeycomb lattice; metal atoms coordinated by four nitrogen atoms from the ligand and stacked through pi-pi interactions.2 · 2.1. Sample Preparation and Characterization · Figure S1
(Co0.60Ni2.40)(HITP)22020 · Continuous Electrical Conductivity Variation in M3(Hexaiminotriphenylene)2(M = Co, Ni, Cu) MOF AlloysCo0.60Ni2.40(HITP)2Co0.60 · HITP = 2,3,6,7,10,11-hexaiminotriphenylene2D · PristineLayered electrically conducting MOF; synchrotron PXRD Pawley refinements fit orthorhombic Cmcm for pure M3(HITP)2; alloys are isostructural solid solutions following Vegard-type trends.12369-12370 · Results and Discussion · Figures 2b, 5; Table S5
(Co1.14Ni1.86)(HITP)22020 · Continuous Electrical Conductivity Variation in M3(Hexaiminotriphenylene)2(M = Co, Ni, Cu) MOF AlloysCo1.14Ni1.86(HITP)2Co1.14 · HITP = 2,3,6,7,10,11-hexaiminotriphenylene2D · PristineLayered electrically conducting MOF; synchrotron PXRD Pawley refinements fit orthorhombic Cmcm for pure M3(HITP)2; alloys are isostructural solid solutions following Vegard-type trends.12369-12370 · Results and Discussion · Figures 2b, 5; Table S5
(Co1.54Ni1.45)(HITP)22020 · Continuous Electrical Conductivity Variation in M3(Hexaiminotriphenylene)2(M = Co, Ni, Cu) MOF AlloysCo1.54Ni1.45(HITP)2Co1.54 · HITP = 2,3,6,7,10,11-hexaiminotriphenylene2D · PristineLayered electrically conducting MOF; synchrotron PXRD Pawley refinements fit orthorhombic Cmcm for pure M3(HITP)2; alloys are isostructural solid solutions following Vegard-type trends.12369-12370 · Results and Discussion · Figures 2b, 5; Table S5
(Co1.83Ni1.17)(HITP)22020 · Continuous Electrical Conductivity Variation in M3(Hexaiminotriphenylene)2(M = Co, Ni, Cu) MOF AlloysCo1.83Ni1.17(HITP)2Co1.83 · HITP = 2,3,6,7,10,11-hexaiminotriphenylene2D · PristineLayered electrically conducting MOF; synchrotron PXRD Pawley refinements fit orthorhombic Cmcm for pure M3(HITP)2; alloys are isostructural solid solutions following Vegard-type trends.12369-12370 · Results and Discussion · Figures 2b, 5; Table S5
(Co2.38Ni0.62)(HITP)22020 · Continuous Electrical Conductivity Variation in M3(Hexaiminotriphenylene)2(M = Co, Ni, Cu) MOF AlloysCo2.38Ni0.62(HITP)2Co2.38 · HITP = 2,3,6,7,10,11-hexaiminotriphenylene2D · PristineLayered electrically conducting MOF; synchrotron PXRD Pawley refinements fit orthorhombic Cmcm for pure M3(HITP)2; alloys are isostructural solid solutions following Vegard-type trends.12369-12370 · Results and Discussion · Figures 2b, 5; Table S5