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ZIF-67 / Co(mIm)₂

This family merges chemical shorthand and formula variants only after verification against source articles. Per-paper composition and phase details remain separate below.

19primary papers
32material records
73linked samples
194linked measurements
557linked results
2016–2025publication span

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19 papers

Primary study2025

Catalytic Metal-Organic Framework-Functionalized Inverse-Opal Architectured Polymeric Separator for High-Performance Li-S Batteries

Yang X., An Z., Zhang P. et al. · Advanced Functional Materials · 2025

Reported here: ZIF-67 cobalt-imidazole metal-organic framework · ZIF-67-functionalized PEEK inverse-opal separator (ZIF-PIO)

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Show 32 material identity records
Paper and reported nameFormula and componentsStructure contextSource
ZIF-67 cobalt-imidazole metal-organic framework2025 · Catalytic Metal-Organic Framework-Functionalized Inverse-Opal Architectured Polymeric Separator for High-Performance Li-S BatteriesCo(2-methylimidazolate)2; exact empirical formula not reportedCo2+ cobalt centres · 2-methylimidazole (2mIm)3D · PristineZIF-67 phase assigned by XRD peaks matching simulated ZIF-67; used as pure reference and as in situ layer on PIO.4 · Results and Discussion · Figure 2d
ZIF-67-functionalized PEEK inverse-opal separator (ZIF-PIO)2025 · Catalytic Metal-Organic Framework-Functionalized Inverse-Opal Architectured Polymeric Separator for High-Performance Li-S BatteriesZIF-67 layer on PEEK inverse-opal membraneCo2+ centres in ZIF-67 · 2-methylimidazole in ZIF-67; PEEK polymer support3D · CompositeComposite separator with in situ grown ZIF-67 functional layer coating inner/outer PIO pore surfaces.4 · Results and Discussion · Figure 2
ZIF67 nanocubes2024 · High-performance hybrid supercapacitors enabled by CoTe@CoFeTe double-shelled nanocubesZIF-67, cobalt 2-methylimidazolate frameworkCo · 2-methylimidazole (C4H6N2)3D · PristineZeolitic imidazolate framework nanocubes; cubic morphology assigned by FE-SEM/TEM.4592 · 2.2 Fabrication of ZIF67 nanocubes
ZIF67@CoFe-PBA nanocubes2024 · High-performance hybrid supercapacitors enabled by CoTe@CoFeTe double-shelled nanocubesZIF67@CoFe-Prussian blue analogueCo, Fe · 2-methylimidazolate and ferricyanide/cyanide framework linkages3D · CompositeHybrid ZIF/PBA core-shell nanocubes formed by anion exchange with ferricyanide ions.4592 · 2.3 Fabrication of ZIF67@CoFe-PBA nanocubes
hollow ZIF-67 / MOF Co hollow spheres precursor2023 · Partial selenium surface modulation of metal organic framework assisted cobalt sulfide hollow spheres for high performance bifunctional oxygen electrocatalysis and rechargeable zinc-air batteriesCo-based zeolitic imidazolate framework from CoSO4 and 2-methylimidazoleCo2+ · 2-methylimidazole (2-MIM)3D · PristineSpherical hollow ZIF-67/MOF-Co precursor, template-free, ca. 500-600 nm diameter.2 and 4 (render p002 and p004) · 2.2 Synthesis of ZIF-67 hollow spheres; 3.1 Synthesis, morphological and structural characterizations · Fig. 1; Fig. S1 referenced
C1-ZIF-672022 · In-Built Fabrication of MOF Assimilated Porous Hollow Carbon from Pre-Hydrolysate for SupercapacitorZIF-67/carbon composite; exact composition not reportedCo species introduced from cobalt nitrate/ZIF-67 chemistry · Dimethylimidazole-derived nitrogen-containing residues plus biomass carbonunknown · CompositeOne-step ZIF-67/carbon material with coral-like cross-linked structure and porous carbon features.p003 / article p.3 · 2.1.3 Preparation of the ZIF-67/Carbon
C2-ZIF-672022 · In-Built Fabrication of MOF Assimilated Porous Hollow Carbon from Pre-Hydrolysate for SupercapacitorZIF-67/carbon composite; exact composition not reportedCo species from pre-formed ZIF-67; metallic Co and Co3O4 signatures reported · ZIF-67 imidazolate-derived nitrogen-containing residues plus biomass carbonunknown · CompositeTwo-step ZIF-67/carbon material with rough hollow dandelion-like structure and hierarchical pores.p003 / article p.3 · 2.1.3 Preparation of the ZIF-67/Carbon
Co-MOF (ZIF-67)2022 · In-Built Fabrication of MOF Assimilated Porous Hollow Carbon from Pre-Hydrolysate for SupercapacitorZIF-67; cobalt imidazolate framework, exact formula not reportedCobalt from cobalt nitrate hexahydrate · Dimethylimidazole as reported by the authors3D · PristineRegular dodecahedral ZIF-67 coordination structure; used as the pristine Co-MOF component and morphology/porosity modifier.p002 / article p.2 · Introduction
Co-MOF precursor2022 · Boron-doped cobalt-iron bimetal phosphides nanosheets for enhanced oxygen evolutionCo 2-methylimidazolate framework, ZIF-67-likeCo · 2-methylimidazole3D · PristineXRD peaks match simulated ZIF-67 pattern3 · Results and discussion · Fig. S2
Co-ZIF-67 zeolitic imidazolate framework2022 · Bifunctional 3D-MOF-based nanoprobes for electrochemical sensing and nanozyme enhanced with peroxidase mimicking for colorimetric detection of acetaminophenCo(2-methylimidazolate)2, commonly ZIF-67Cobalt ions coordinated by imidazolate linkers; described as Co2+ and 2-MeIm nucleation into ZIF-67. · 2-methylimidazole (2-MeIm)3D · PristineSodalite crystalline ZIF framework; ZIF-67-C forms rhombic dodecahedral particles, while ageing and hydrothermal variants show more aggregation or irregular morphology.2-3 · 2.2 Synthesis procedure; 3.1 Structural and morphological analysis · Fig. 1
IrOx@Ni/Co-ZIF-672022 · Electrocatalytic oxygen evolution reaction at IrOx supported by Ni/Co-ZIF-67: Controlled ratio of metallic Ir and Ir3+ statesIrOx nanoparticles supported on Ni/Co-ZIF-67 nanosheetsNi/Co ZIF nodes plus supported Ir0/Ir3+/Ir4+ oxide/metal species · 2-methylimidazolate / imidazolate linkers in the Ni/Co-ZIF-67 support2D · CompositeComposite of ultrafine IrOx nanoparticles on Ni/Co-ZIF-67; XRD retains Ni/Co-ZIF-67 peaks, while TEM/XPS indicate metallic Ir, crystalline IrO2, and amorphous IrOx species.article p4 · Results and discussion · Figure 2
Ni/Co-ZIF-67 nanosheets2022 · Electrocatalytic oxygen evolution reaction at IrOx supported by Ni/Co-ZIF-67: Controlled ratio of metallic Ir and Ir3+ statesNi/Co mixed-metal ZIF-67; exact empirical formula not reportedCo and Ni ions coordinated by imidazolate linkers; optimized Ni/Co atomic ratio reported as 1:6.5 · 2-methylimidazolate / imidazolate linkers2D · PristineNi-incorporated ZIF-67 nanosheets retaining native ZIF-67 XRD features with no secondary phases; Ni ions are coordinated by imidazole linkers as Co is in ZIF-67.article p3 · Results and discussion · Figure 1
ZIF-67 nanosheets2022 · Electrocatalytic oxygen evolution reaction at IrOx supported by Ni/Co-ZIF-67: Controlled ratio of metallic Ir and Ir3+ statesCo(2-methylimidazolate) framework; exact empirical formula not reportedCo ions coordinated by imidazolate linkers · 2-methylimidazolate / dimethylimidazolate as described in FTIR discussion2D · PristineNanosheet-shaped zeolitic imidazolate framework-67; XRD peaks at 12.5 and 25 deg match standard ZIF-67 (211) and (422) planes.article p2 · Experimental procedure, 2.1
ZIF-67@cotton fabric2022 · Flexible Smart Wearable Co@C@Carbon Fabric for Efficient Electromagnetic Shielding, Thermal Therapy, and Human Movement MonitoringZIF-67@CF; Co(2-methylimidazolate)2 on cotton fabricCo · 2-methylimidazole3D · CompositeZIF-67 diffraction peaks assigned to the (011), (002), (112), (013), (222), (233), and (224) planes; dodecahedral ZIF-67 particles anchored on cotton fibres.8 (11832) · 3.3 XRD and XPS Analysis · Figure 4a
ZCPL MOF-incorporated polymeric interlayer2021 · Stabilization of NASICON-Type Electrolyte against Li Anode via an Ionic Conductive MOF-Incorporated Adhesive InterlayerZIF-67/PEO/LiTFSI composite; weight ratio 4:8:1 in coating slurryCo2+ nodes from ZIF-67 component · 2-methylimidazolate in ZIF-67; PEO polymer matrix; LiTFSI lithium saltunknown · CompositeComposite polymer interlayer retaining ZIF-67 diffraction peaks plus PEO peaks around 19 and 23 degrees.3143 · Results · Figure 1b
ZIF-67 nanoparticles2021 · Stabilization of NASICON-Type Electrolyte against Li Anode via an Ionic Conductive MOF-Incorporated Adhesive InterlayerCo(2-methylimidazolate)2 framework; ZIF-67Co2+ coordinated by four N atoms · 2-methylimidazolate anions3D · PristineSodalite topology ZIF-67; XRD matched simulated ZIF-67; dodecahedral nanoparticles.4 · Supplementary Figures · Figures S1-S3
ZIF-672020 · Encapsulating metal organic framework into hollow mesoporous carbon sphere as efficient oxygen bifunctional electrocatalystCo(2-methylimidazolate) frameworkCo2+ · 2-methylimidazole / 2-methylimidazolate3D · PristineZeolitic imidazolate framework ZIF-67 with Co-N4 structural motifs610 · Introduction
ZIF-672020 · Underpinning the conductivity mechanism in wide bandgap metal organic framework through chemical sensingCo(methylimidazolate)2 / Co-based zeolitic imidazolate framework; exact empirical formula not reportedCo2+ metal ion sites · 2-methylimidazolate / methyl imidazole ligand3D · PristineIsostructural zeolitic imidazolate framework; cubic I-43m structure assigned from XRD.p002-p003 · Introduction; Structural characterizations · Fig. 1
ZIF-67@HMCS yolk-shell hybrid2020 · Encapsulating metal organic framework into hollow mesoporous carbon sphere as efficient oxygen bifunctional electrocatalystZIF-67@N-doped hollow mesoporous carbonCo2+ in ZIF-67 · 2-methylimidazolate3D · CompositeYolk-shell composite with ZIF-67 core/particles confined inside HMCS shell610 · Introduction
ILE@MOF ionogel electrolyte2019 · A Li+ conductive metal organic framework electrolyte boosts the high-temperature performance of dendrite-free lithium batteriesZIF-67 + [Py13][TFSI] + LiTFSICo from ZIF-67 · 2-methyl imidazolate framework with N-propyl-N-methylpyrrolidinium/TFSI ionic liquid and LiTFSI salt3D · CompositeGuest-loaded ionogel; XRD peaks retained after introducing ILE, indicating the MOF structure remained stable.9531 · Introduction/Results and discussion · Fig. 1
ZIF-672019 · A Li+ conductive metal organic framework electrolyte boosts the high-temperature performance of dendrite-free lithium batteriesCo(2-methylimidazolate) framework; exact framework formula not statedCo · 2-methyl imidazole / imidazolate3D · PristineImidazolate framework-67 with rhombic dodecahedral particles; assigned by XRD against ZIF-67 literature pattern.9531 · Results and discussion · Fig. 1a, Fig. S1
Co-MOF powder reference / pristine ZIF-672018 · In situ growth of ultrathin Co-MOF nanosheets on Α-Fe2O3 hematite nanorods for efficient photoelectrochemical water oxidationCo(2-methylimidazolate)2-like; exact formula not reportedCo2+ · 2-methylimidazolate3D · PristinePowder particles show diffraction peaks consistent with simulated sodalite structure; used as pristine ZIF-67 reference in XPS comparison.p004 / journal p391 · 3 Results and discussion · Fig. S2 / Fig. 7
Co-MOF precursor, shown as ZIF-672017 · CoP nanoparticles embedded in P and N co-doped carbon as efficient bifunctional electrocatalyst for water splittingCo-based imidazolate MOF; exact formula not reported in main textCo ions · N-containing organic ligand; Scheme 1 depicts a methylimidazole ligand3D · PristineCo-MOF precursor converted to CoP nanoparticles and P,N co-doped carbon during phosphidation/carbonisation; Scheme 1 labels the precursor as ZIF-67.p002 / article p.1224 · Introduction; Experimental · Scheme 1; Section 2.1
ZIF-672017 · Conductive Metal–Organic Framework Nanowire Array Electrodes for High-Performance Solid-State Supercapacitorsnot specified in this papernot specified in this paper · not specified in this paper3D · PristineLow-conductivity MOF control; highest capacitance among the low-conductive MOF controls in this paper.p.4 · Supercapacitors Performance · Figure 3f
ZIF-67 nanocrystals2017 · 2D MOF nanoflake-assembled spherical microstructures for enhanced supercapacitor and electrocatalysis performances[Co(MeIm)2]nCo2+ imidazolate framework · 2-methylimidazolate (MeIm)3D · PristineZIF-67 rhombododecahedron nanoseeds; XRD matches simulated ZIF-67.4 · Results and Discussion · Scheme 1; Fig. S1a
Co-MOF (ZIF-67)2016 · Hollow Cobalt-Based Bimetallic Sulfide Polyhedra for Efficient All-pH-Value Electrochemical and Photocatalytic Hydrogen EvolutionCo(2-methylimidazolate) frameworkCo2+ · 2-methylimidazole3D · PristineZIF-67-type Co-MOF precursor; purple rhombic dodecahedral polyhedra.S4 · 1. Experimental
Ti/CdS/ZIF-672016 · In-situ Growth of Ultrathin ZIF-67 Nanosheets on Conductive Ti@TiO2/CdS Substrate for High-efficient Electrochemical CatalysisZIF-67 on Ti/CdSCo in ZIF-67; Ti/CdS support · 2-methylimidazole-derived imidazolate linkers3D · CompositeControl electrode prepared by direct growth of CdS nanoparticles and ZIF-67 on non-annealed Ti nanowire substrate.SI text · Fabrication · Fig. S7
Ti@TiO2/CdS/ZIF-672016 · In-situ Growth of Ultrathin ZIF-67 Nanosheets on Conductive Ti@TiO2/CdS Substrate for High-efficient Electrochemical CatalysisZIF-67 nanosheets on Ti@TiO2/CdSCo in ZIF-67; Ti/TiO2/CdS conductive substrate · 2-methylimidazole-derived imidazolate linkers3D · CompositeUnique 3D hierarchical electrode consisting of ultrathin ZIF-67 nanosheets grown on CdS-decorated Ti@TiO2 nanowire arrays.1 · Abstract
Ti@TiO2/CdS/ZIF-67-P2016 · In-situ Growth of Ultrathin ZIF-67 Nanosheets on Conductive Ti@TiO2/CdS Substrate for High-efficient Electrochemical Catalysisdrop-cast ZIF-67 powder on Ti@TiO2/CdSCo in ZIF-67; Ti/TiO2/CdS support · 2-methylimidazole-derived imidazolate linkers3D · CompositePowder-cast ZIF-67 control prepared by drop-casting ZIF-67 powder ink on Ti@TiO2/CdS.SI text · Fabrication · Fig. S9
Ti@TiO2/ZIF-672016 · In-situ Growth of Ultrathin ZIF-67 Nanosheets on Conductive Ti@TiO2/CdS Substrate for High-efficient Electrochemical CatalysisZIF-67 on Ti@TiO2Co in ZIF-67; Ti/TiO2 support · 2-methylimidazole-derived imidazolate linkers3D · CompositeZIF-67 in situ grown on Ti@TiO2 substrate by the same Co(OH)2 self-sacrificial route.SI text · Fabrication · Fig. S8, Fig. S10
ZIF-672016 · In-situ Growth of Ultrathin ZIF-67 Nanosheets on Conductive Ti@TiO2/CdS Substrate for High-efficient Electrochemical CatalysisCo(2-methylimidazolate)2Co(II) nodes / tetrahedral CoN4 units · 2-methylimidazole-derived imidazolate linkers3D · PristineZeolitic imidazolate framework ZIF-67; experimental XRD of separately prepared powder is consistent with simulated ZIF-67 pattern.2-3 · Introduction / Results and discussion · Fig. S1, Fig. S3
ZIF-672016 · Novel CoS2 embedded carbon nanocages by direct sulfurizing metal-organic frameworks for dye-sensitized solar cellsCo(mim)2; mim = 2-methylimidolateCo · 2-methylimidazolate3D · PristineZeolitic imidazolate framework-67, polyhedral MOF template11984 · Abstract