Primary study2025
Ammonia-Assisted Chemical Vapor Deposition Growth of Two-Dimensional Conjugated Coordination Polymer Thin Films
Liu J., Fu S., Fu Y. et al. · Journal of the American Chemical Society · 2025
Reported here: Cu-BHT
Source-verified familyIdentity or context cautions
Cu₃(C₆S₆) / Cu–BHT
This family merges chemical shorthand and formula variants only after verification against source articles. Per-paper composition and phase details remain separate below.
15primary papers
25material records
92linked samples
205linked measurements
740linked results
2015–2025publication span
Read this group with context
- Several formulas or formula descriptions are reported
- Pristine, composite, derived or model contexts are mixed
- Model-system or unresolved records are present
Cu₃BHT structures with different stacking or vacancy states remain separate members. Cu₅BHT is a distinct phase and is excluded from this family.
Evidence coverage
Paper counts are material-linked through samples and measurements; technique groups are not value rankings.
Electrical Transport14 papers60 measurements · 214 resultsDiffraction Structure12 papers23 measurements · 73 resultsMicroscopy Morphology12 papers24 measurements · 59 resultsSpectroscopy11 papers34 measurements · 141 resultsComputational Modelling8 papers17 measurements · 80 resultsOther8 papers9 measurements · 25 resultsElectrochemistry Application5 papers14 measurements · 56 resultsSensing Application4 papers15 measurements · 55 resultsPorosity3 papers3 measurements · 5 resultsThermoelectric2 papers6 measurements · 32 results
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Distinct primary papers in this browse group by publication year.
Primary papers
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15 papers
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Primary study2025
An optoelectronic synapse based on Cu-BHT MOF for multi-wavelength optical logic gates and neuromorphic vision system
Li Z., Zhang L., Chen Y. et al. · Applied Materials Today · 2025
Reported here: Cu-BHT conductive metal-organic framework
Primary study2025
Metal-Organic Framework-Based Tribovoltaic Textile for Human Body Signal Monitoring
Li Y., Wu Y., Shokurov A.V. et al. · Advanced Science · 2025
Reported here: copper-benzenehexathiol metal-organic framework · Cu-BHT tribovoltaic textile device · Cu-BHT-modified cotton
Primary study2025
Two-dimensional conductive metal-organic framework with 2,3,6,7,14,15-triptycenehexathiol (TCHT) ligand: synthesis, structure, electrical conductivity and CO2RR activity
Murakami W., Kitayama T., Chiba Y. et al. · Journal of Materials Chemistry A · 2025
Reported here: Cu-BHT
Primary study2025
Unveiling high-mobility hot carriers in a two-dimensional conjugated coordination polymer
Fu S., Huang X., Gao G. et al. · Nature Materials · 2025
Reported here: Cu3BHT DFT model systems with varied Cu valence ratios · Cu3BHT two-dimensional conjugated coordination polymer
Primary study2024
Synthesis and structure of a non-van-der-Waals two-dimensional coordination polymer with superconductivity
Pan Z., Huang X., Fan Y. et al. · Nature Communications · 2024
Reported here: Cu3BHT · Cu3BHT DFT model
Primary study2023
Chemical Vapor Deposition and High-Resolution Patterning of a Highly Conductive Two-Dimensional Coordination Polymer Film
Rubio-Gimenez V., Arnauts G., Wang M. et al. · Journal of the American Chemical Society · 2023
Reported here: Cu-BHT / copper benzenehexanothiolate coordination polymer
Primary study2023
Semiconducting Conjugated Coordination Polymer with High Charge Mobility Enabled by “4 + 2” Phenyl Ligands
Huang X., Fu S., Lin C. et al. · Journal of the American Chemical Society · 2023
Reported here: 2D-Cu3BHT model · Cu3BHT conjugated coordination polymer
Primary study2022
Defect Engineering to Tailor Metal Vacancies in 2D Conductive Metal-Organic Frameworks: An Example in Electrochemical Sensing
Luo Y., Wu Y., Braun A. et al. · ACS Nano · 2022
Reported here: Cu-BHT · Cu-BHT computational models
Primary study2021
Electrically Conductive Metal–Organic Framework Thin Film-Based On-Chip Micro-Biosensor: A Platform to Unravel Surface Morphology-Dependent Biosensing
Chen X., Dong J., Chi K. et al. · Advanced Functional Materials · 2021
Reported here: Cu-benzenehexathiol conductive MOF thin film · Cu3C6S6 Cu-BHT DFT slab model
Primary study2021
Semiconducting to Metallic Electronic Landscapes in Defects-Controlled 2D π-d Conjugated Coordination Polymer Thin Films
Ogle J., Lahiri N., Jaye C. et al. · Advanced Functional Materials · 2021
Reported here: Copper(I) benzenehexathiol coordination polymer (Cu-BHT)
Primary study2020
Highly Conductive Two-Dimensional Metal-Organic Frameworks for Resilient Lithium Storage with Superb Rate Capability
Wu Z., Adekoya D., Huang X. et al. · ACS Nano · 2020
Reported here: Cu-BHT · Li-loaded Cu-BHT model
Primary study2020
Ultrafast in Situ Synthesis of Large-Area Conductive Metal-Organic Frameworks on Substrates for Flexible Chemiresistive Sensing
Chen X., Lu Y., Dong J. et al. · ACS Applied Materials and Interfaces · 2020
Reported here: Copper benzenehexathiol conductive metal-organic framework (Cu-BHT) · Cu3C6S6 surface model for NH3 adsorption
Primary study2020
Unique Thermoelectric Properties Induced by Intrinsic Nanostructuring in a Polycrystalline Thin-Film Two-Dimensional Metal–Organic Framework, Copper Benzenehexathiol
Tsuchikawa R., Lotfizadeh N., Lahiri N. et al. · Physica Status Solidi (A) Applications and Materials Science · 2020
Reported here: copper benzenehexathiol
Primary study2015
A two-dimensional π-d conjugated coordination polymer with extremely high electrical conductivity and ambipolar transport behaviour
Huang X., Sheng P., Tu Z. et al. · Nature Communications · 2015
Reported here: Cu-BHT copper bis(dithiolene) two-dimensional coordination polymer · Cu3C6S6 computational model structures
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Per-paper identity records
Raw names, formulas and structural assignments remain separate; no consensus value is inferred.
Show 25 material identity records
| Paper and reported name | Formula and components | Structure context | Source |
|---|---|---|---|
| copper-benzenehexathiol metal-organic framework2025 · Metal-Organic Framework-Based Tribovoltaic Textile for Human Body Signal Monitoring | Cu-BHT; exact empirical formula not reportedCu ions / copper(II) chloride precursor forming Cu-S coordination nodes · 1,2,3,4,5,6-benzenehexathiol (BHT) | 2D · PristineConductive 2D MOF; crystalline Cu-BHT powder has peaks at 11.8 deg (100), 26.6 deg (001), and 35 deg (201). | p002 · Introduction / Results and Discussion · Figure S2 |
| Cu-BHT2025 · Two-dimensional conductive metal-organic framework with 2,3,6,7,14,15-triptycenehexathiol (TCHT) ligand: synthesis, structure, electrical conductivity and CO2RR activity | Not specifiedCu with benzenehexathiol-derived thiolate framework, from cited prior procedure · benzenehexathiol (BHT) | 2D · PristineConventional horizontal-ligand 2D conductive MOF used as comparison for CO2RR. | 25725 · Chemicals |
| Cu-BHT2025 · Ammonia-Assisted Chemical Vapor Deposition Growth of Two-Dimensional Conjugated Coordination Polymer Thin Films | Cu-BHT; CuS4-linked benzenehexathiol 2D conjugated coordination polymerCu centers from Cu(acac)2 or previous Cu-BHT CVD recipe · BHT = hexathiolbenzene / benzenehexathiol | 2D · Pristine2D c-CP thin film with CuS4 coordination linkages. | SI p31-32 · Figure S25-S26 discussion · Figures S25-S26 |
| Cu-BHT conductive metal-organic framework2025 · An optoelectronic synapse based on Cu-BHT MOF for multi-wavelength optical logic gates and neuromorphic vision system | Cu-BHT; exact bulk stoichiometry not explicitly quantified in this paperCopper centres with Cu+ and Cu2+ detected by Cu 2p XPS; Cu+/Cu2+ peak-area ratio approximately 2:1. · Benzenehexathiol (BHT, C6H6S6) / benzenehexathiolate units bonded through S-Cu and S-C interactions. | 2D · PristineTwo-dimensional layered pi-d conjugated coordination/MOF structure; XRD consistent with reported Cu-BHT, HRTEM shows periodic lattice with 0.536 nm interlayer spacing. | p002 / 2 · Introduction |
| Cu-BHT tribovoltaic textile device2025 · Metal-Organic Framework-Based Tribovoltaic Textile for Human Body Signal Monitoring | Cu-BHT cotton / aluminium fabricCu-BHT semiconductor paired with aluminium metal textile · BHT in Cu-BHT cotton | unknown · CompositeTwo-layer textile Schottky junction device comprising Cu-BHT cotton and Al fabric. | p004 · Results and Discussion · Figure 2a |
| Cu-BHT-modified cotton2025 · Metal-Organic Framework-Based Tribovoltaic Textile for Human Body Signal Monitoring | Cu-BHT grown on cellulose cotton textileCu ions bound to cotton hydroxyl groups and reacted with BHT through Cu-S bonds · BHT | 2D · CompositeComposite textile with Cu-BHT film/network on cotton fibres; Cu-BHT peaks are not resolved by XRD because cellulose dominates the pattern. | p002 · Results and Discussion · Figure 1, Figure S2 |
| Cu3BHT DFT model systems with varied Cu valence ratios2025 · Unveiling high-mobility hot carriers in a two-dimensional conjugated coordination polymer | Cu3BHT models, Cu2+/Cu+ ratios 3:0, 2:1, 1:2 and 0:3Cu+/Cu2+ configurations imposed in DFT · BHT framework model | 2D · Model SystemDFT model of Cu3BHT band structure and DOS with different copper valence-state configurations. | 3 · Computational details · Supplementary Fig. 7 |
| Cu3BHT two-dimensional conjugated coordination polymer2025 · Unveiling high-mobility hot carriers in a two-dimensional conjugated coordination polymer | Cu3BHT; benzenehexathiolato copper coordination polymerCu atoms / Cu2+ source; mixed Cu+/Cu2+ valence reported · BHT (benzenehexathiol / benzenehexathiolate) | 2D · PristineCrystalline 2D d-pi conjugated coordination polymer; high-symmetry non-distorted kagome lattice; slipped-AA-stacked triclinic structure, preferential face-on orientation. | 2 · Synthesis and characterization of Cu3BHT films · Fig. 1 |
| Cu3BHT2024 · Synthesis and structure of a non-van-der-Waals two-dimensional coordination polymer with superconductivity | Cu3BHTCopper ions in mixed Cu+ and Cu2+ valence; square-planar and square-pyramidal coordination environments · Benzenehexathiolate (BHT) | 2D · PristineQuasi-2D kagome coordination polymer with monoclinic P21/c ABAB double-layer stacking, in-plane pi-d conjugation, and non-van der Waals interlayer Cu-S covalent bonds. | 1 · Abstract |
| Cu3BHT DFT model2024 · Synthesis and structure of a non-van-der-Waals two-dimensional coordination polymer with superconductivity | Cu3BHTCopper sites from the experimentally solved structure · Benzenehexathiolate (BHT) | 2D · Model SystemAtomic-precise Cu3BHT crystal structure used for DFT, DFPT phonon, EPC, and band-unfolding calculations. | 5 · Band structure calculation · Figure 4 |
| 2D-Cu3BHT model2023 · Semiconducting Conjugated Coordination Polymer with High Charge Mobility Enabled by “4 + 2” Phenyl Ligands | 2D monolayer Cu3BHT modelCu model nodes · BHT | 2D · Model SystemFully planar 2D monolayer model used to compare metallic band structure. | SI p. 9 · Calculation details · Figure S10 |
| Cu-BHT / copper benzenehexanothiolate coordination polymer2023 · Chemical Vapor Deposition and High-Resolution Patterning of a Highly Conductive Two-Dimensional Coordination Polymer Film | [Cu3(C6S6)]nCu(I) ions in Cu-thiolate coordination within a Kagome-type planar lattice. · Benzenehexanothiolate (BHT) linker generated from H6BHT. | 2D · PristineKagome-type planar lattice; eclipsed AA vertical stacking in the main schematic; crystalline CVD films assigned to AA stacking, monoclinic C2, preferentially oriented with 2D ab planes parallel to the substrate. | main p.1-p.3 / article p.A-C · Abstract; Results and Discussion · Figure 1; Figure 2e |
| Cu3BHT conjugated coordination polymer2023 · Semiconducting Conjugated Coordination Polymer with High Charge Mobility Enabled by “4 + 2” Phenyl Ligands | Cu3BHT; BHT = benzenehexathiolCopper coordination network based on BHT ligand; cited as metallic Cu3BHT · benzenehexathiol (BHT) | 2D · PristinePreviously reported 2D pi-d conjugated coordination polymer with metallic behaviour, used here as a control/comparator for THz transport. | 2435 · Results and Discussion · Figure 4 |
| Cu-BHT2022 · Defect Engineering to Tailor Metal Vacancies in 2D Conductive Metal-Organic Frameworks: An Example in Electrochemical Sensing | Cu3(C6S6)n nominal; Cu-deficient variantsCu(I) centres; Cu vacancies intentionally varied · benzenehexathiolato (BHT, C6S6) | 2D · Pristine2D pi-d conjugated copper benzenehexathiolato coordination polymer film; XRD indexed to the Cu-BHT phase. | 20822-20823 · Results and Discussion · Figures 1-3 |
| Cu-BHT computational models2022 · Defect Engineering to Tailor Metal Vacancies in 2D Conductive Metal-Organic Frameworks: An Example in Electrochemical Sensing | 3 x 3 Cu-BHT supercell; perfect and double-Cu-vacancy defective modelsCu nodes in perfect or double-vacancy configurations · benzenehexathiolato (BHT) | 2D · Model SystemDFT model systems based on a 3 x 3 Cu-BHT supercell with six double-Cu-vacancy configurations. | 8-10 · 2.1 Density Functional Theory (DFT) Method and Models · Figures S3-S4 |
| Copper(I) benzenehexathiol coordination polymer (Cu-BHT)2021 · Semiconducting to Metallic Electronic Landscapes in Defects-Controlled 2D π-d Conjugated Coordination Polymer Thin Films | Cu-BHT; ideal S-Cu:S-C coordination ratio 2:1Cu(I) ions; formed from Cu(II) precursors reduced during polymer formation · benzenehexathiol (BHT) | 2D · Pristine2D Kagome lattice; square-planar Cu-S coordination; non-porous continuous 2D Cu-S network; C2/m assignment for V-V HRTEM pattern and hexagonal/slipped AB stacking for S-V sample | 2 · Results and Discussion · Figure 1A |
| Cu-benzenehexathiol conductive MOF thin film2021 · Electrically Conductive Metal–Organic Framework Thin Film-Based On-Chip Micro-Biosensor: A Platform to Unravel Surface Morphology-Dependent Biosensing | Cu-BHT; model stoichiometry Cu3C6S6Cu sites in a 2D Cu-BHT coordination network; surface s-Cu and defect ts-Cu sites discussed · benzenehexathiol / benzenehexathiolate (BHT) | 2D · Pristine2D kagome lattice conductive MOF film with eclipsed AA stacking, face-on crystallite orientation, and pi-stacked layers. | p001 · Introduction |
| Cu3C6S6 Cu-BHT DFT slab model2021 · Electrically Conductive Metal–Organic Framework Thin Film-Based On-Chip Micro-Biosensor: A Platform to Unravel Surface Morphology-Dependent Biosensing | Cu3C6S6Cu sites including simulated s-Cu and ts-Cu active sites · deprotonated benzenehexathiolate framework represented as C6S6 | 2D · Model SystemCu3C6S6 (001) sheet model with p(3 x 2) periodicity and an open-edge defect generated by removing two Cu3C6S6 units. | p008 · Experimental Section - Computational Method |
| copper benzenehexathiol2020 · Unique Thermoelectric Properties Induced by Intrinsic Nanostructuring in a Polycrystalline Thin-Film Two-Dimensional Metal–Organic Framework, Copper Benzenehexathiol | Cu-BHT; unit-cell composition reported as Cu3S6C6Cu, predominantly Cu(I) · benzenehexathiol / benzenehexathiolate (BHT) | 2D · PristineElectrically conductive 2D MOF with hexagonal crystal structure, nanopores, and layered structure; HR-TEM/FFT show a 0.76 nm lattice spacing/constant in the thin flakes. | rendered page 2 / article p.2000437-2 · Characterization and Experiments · Figure 1a-d |
| Copper benzenehexathiol conductive metal-organic framework (Cu-BHT)2020 · Ultrafast in Situ Synthesis of Large-Area Conductive Metal-Organic Frameworks on Substrates for Flexible Chemiresistive Sensing | Cu3C6S6 (reported computational unit cell); Cu-BHTCu ions/Cu nodes; surface environments assigned as four-coordinated Cu4c and two-coordinated Cu2c sites. · Benzenehexathiol (BHT). | 2D · Pristine2D kagome lattice in the ab plane with AA layer stacking; XRD pattern matches simulated Cu-BHT pattern. | p004; article page 57238 · 3.1 Strategy · Figure 1f |
| Cu-BHT2020 · Highly Conductive Two-Dimensional Metal-Organic Frameworks for Resilient Lithium Storage with Superb Rate Capability | [Cu3(C6S6)]nCu(II) centres; Cu-S coordination network · benzenehexathiolate (BHT, C6S6H6 precursor) | 2D · Pristine2D hexagonal unit cell, space group P6/mmm; AA stacking; kagome lattice. | p003 / 12018 · Introduction; Results and Discussion · Scheme 1; Figure 1 |
| Cu3C6S6 surface model for NH3 adsorption2020 · Ultrafast in Situ Synthesis of Large-Area Conductive Metal-Organic Frameworks on Substrates for Flexible Chemiresistive Sensing | Cu3C6S6 slab modelCu atoms in Cu4c and edge Cu2c surface coordination environments. · BHT-derived C6S6 framework in the computational slab. | 2D · Model SystemHexagonal Cu3C6S6 unit cell; (001) surface with p(3 x 2) periodicity and an edge row removed to expose two-coordinated Cu atoms. | p004; article page 57238 · 2.6 Computational Method |
| Li-loaded Cu-BHT model2020 · Highly Conductive Two-Dimensional Metal-Organic Frameworks for Resilient Lithium Storage with Superb Rate Capability | Li_x[Cu3(C6S6)]nCu(II) centres retained during lithiation/delithiation · benzenehexathiolate ligand redox centres, especially sulfur atoms | 2D · Model SystemDFT model of Li adsorption in benzene, five-membered and six-membered cyclic sites of Cu-BHT monolayer. | p006-p007 / 12021-12022 · DFT Theoretical Analysis · Figure 4 |
| Cu-BHT copper bis(dithiolene) two-dimensional coordination polymer2015 · A two-dimensional π-d conjugated coordination polymer with extremely high electrical conductivity and ambipolar transport behaviour | [Cu3(C6S6)]n; also written [Cu3C6S6]nCu atoms coordinated by four sulfur atoms in square-planar CuS4 environments; Cu(II) precursor reduced toward Cu(I)-like Cu 2p binding energy during formation. · Benzenehexathiol (BHT, C6H6S6 before deprotonation; C6S6 in the framework) | 2D · PristinePlanar pi-d conjugated dense 2D Cu-S network; stacked nanosheets with AA/AB stacking mixture possible; hexagonal in-plane lattice assigned by GIXRD/PXRD and DFT. | main p.2-3 · Introduction/Structural resolution · Fig. 2c |
| Cu3C6S6 computational model structures2015 · A two-dimensional π-d conjugated coordination polymer with extremely high electrical conductivity and ambipolar transport behaviour | Cu3C6S6Model Cu-S coordination networks with candidate AA, AB and single-layer structures. · BHT-derived C6S6 units | 2D · Model SystemDFT/PBE-D2 and CALYPSO-derived candidate structures used to rationalise GIXRD/PXRD and electronic bands. | SI p.6 · Supplementary Note 1 · Supplementary Fig. 9; Supplementary Table 3 |