Bimetallic conductive MOF single crystals designed as high-performance anodes for lithium-ion batteries
Xu T., Li S., Mi H. et al. · Journal of Power Sources · 2026
Reported here: Co-HHTP conductive MOF (CH)
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30 papers
Xu T., Li S., Mi H. et al. · Journal of Power Sources · 2026
Reported here: Co-HHTP conductive MOF (CH)
Yang M., Zhu R., Chen X. et al. · Chinese Journal of Chemistry · 2026
Reported here: Co-HHTP
Scheiger C., Pohls J.F., Mostaghimi M. et al. · Materials Horizons · 2025
Reported here: Co3(HHTP)2 model
Ambrogi E.K., Li Y., Chandra P. et al. · ACS Sensors · 2025
Reported here: Co3(HHTP)2
Xie X., Chen Y., Jing J. et al. · Journal of Alloys and Compounds · 2025
Reported here: Co-MOF / Co3(HHTP)2 conductive metal-organic framework
Qian L., Tong Z., Jia Y. et al. · Electrochemistry Communications · 2025
Reported here: Co-HHTP
Lee K., Jo Y.-M., Sohn M.S. et al. · Nature Communications · 2025
Reported here: Co3HHTP2
T P., Narayana M.L., N․K․ M. et al. · Electrochimica Acta · 2025
Reported here: Co-catecholate MOF (Co-CAT)
Chen J.-Y., Weng Y.-X., Han Y.-H. et al. · Ecotoxicology and Environmental Safety · 2024
Reported here: Co-HHTP
Wu Y., Zhang K., Wang H. et al. · ACS Applied Energy Materials · 2024
Reported here: Co-HHTP
Jo Y.-M., Kim D.-H., Wang J. et al. · Journal of the American Chemical Society · 2024
Reported here: Co3HHTP2
Liu L., Zhang Y., Song Y. et al. · Inorganic Chemistry · 2024
Reported here: Co-HHTP · Co-HHTP@Co(OH)2 · Co-HHTP@Co3O4 · Co-HHTP@CoP
Liu M., Wei J., Lin S.-J. et al. · ACS Applied Electronic Materials · 2024
Reported here: Co-HHTP conductive metal-organic framework · luminol@Co-HHTP
Li J., Huang Y., Zhou Y. et al. · ACS Applied Nano Materials · 2023
Reported here: Co-MOF/CPE modified carbon paste electrode · Co3(HHTP)2 nanorods
He Y., Yan F., Zhang X. et al. · Advanced Energy Materials · 2023
Reported here: Co-catecholate (Co-CAT) · Ir-doped Co-CAT (IrCo-CAT) · Rh-doped Co-CAT (RhCo-CAT) · Ru-doped Co-CAT (RuCo-CAT)
Liu P., Yan J., Huang H. et al. · Chemical Engineering Journal · 2023
Reported here: CoHHTP conductive MOF
Huang C., Shang X., Zhou X. et al. · Nature Communications · 2023
Reported here: Co-HHTP conductive metal-organic framework
Song M., Jia J., Li P. et al. · Journal of the American Chemical Society · 2023
Reported here: Co3(HHTP)2 cobalt catecholate conductive MOF
Keum C., Park S., Kim H. et al. · Chemical Engineering Journal · 2023
Reported here: Co3HHTP2 control MOF
Mao P., Fan H., Liu C. et al. · Sustainable Energy and Fuels · 2022
Reported here: Co-CAT MOF / Co3(HHTP)2 · Co-CAT//LiCoO2 full cell
Zhang Y., Kornienko N. · ChemSusChem · 2022
Reported here: Co-CAT
Stolz R.M., Kolln A.F., Rocha B.C. et al. · ACS Nano · 2022
Reported here: Co3(HHTP)2
Ha D.-G., Rezaee M., Han Y. et al. · ACS Central Science · 2021
Reported here: Co-CAT-1 two-dimensional metal-organic framework
Wang J., Li F., Liu Z. et al. · ACS Applied Materials and Interfaces · 2021
Reported here: Co3(HHTP)2
Shi X., Hua R., Xu Y. et al. · Sustainable Energy and Fuels · 2020
Reported here: Co-CAT
Gu S., Bai Z., Majumder S. et al. · Journal of Power Sources · 2019
Reported here: Co3(HHTP)2
Mahringer A., Jakowetz A.C., Rotter J.M. et al. · ACS Nano · 2019
Reported here: Co-CAT-1
Mendecki L., Mirica K.A. · ACS Applied Materials and Interfaces · 2018
Reported here: Co3HHTP2 MOF
Miner E.M., Wang L., Dinca M. · Chemical Science · 2018
Reported here: Co3(HHTP)2 trigonal MOF
Ko M., Aykanat A., Smith M.K. et al. · Sensors (Switzerland) · 2017
Reported here: Co3HHTP2 · Co3HHTP2/graphite blend
No linked paper matches these filters.
Raw names, formulas and structural assignments remain separate; no consensus value is inferred.
| Paper and reported name | Formula and components | Structure context | Source |
|---|---|---|---|
| Co-HHTP2026 · Structure and Electrical Transport Properties of Metal Cate-Cholate Frameworks: The Metal Center Matters† | M-HHTP; HHTP = 2,3,6,7,10,11-hexahydroxytriphenyleneCo2+ cobalt nodes coordinated to HHTP catecholate/semiquinone ligands · HHTP (2,3,6,7,10,11-hexahydroxytriphenylene), partially deprotonated/oxidised catecholate-semiquinone units after coordination | 2D · Pristine2D honeycomb-like HHTP framework with transition-metal catecholate coordination; Co2+ inferred high-spin. | main p.1, article p.311 · Comprehensive Summary |
| Co-HHTP conductive MOF (CH)2026 · Bimetallic conductive MOF single crystals designed as high-performance anodes for lithium-ion batteries | Co-HHTP; exact empirical formula not reportedCo centres from Co(CH3COO)2.4H2O. · HHTP | 2D · PristineSingle-metal Co-HHTP control framework; assigned as polycrystalline by SAED and compared with CNH by XRD, FTIR, sorption and electrochemistry. | p.3 · Synthesis of Co-HHTP · Fig. S3 |
| Co-catecholate MOF (Co-CAT)2025 · Tailoring of electrocatalytic oxygen evolution reaction performance of 2D conductive Co-catecholate metal-organic frameworks | Co3(HHTP)2(H2O)6 / Co3(HHTP)1(H2O)12 layered structural motifCo2+ · 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP) catecholate linker | 2D · PristineCrystalline 2D layered hexagonal Co-catecholate framework with honeycomb pores; trigonal P3c1 reported from prior structural assignment. | 2 · Introduction · Scheme 1 |
| Co-HHTP2025 · In situ construction of a dual-metal 2D conjugated metal-organic framework on carbon paper for asymmetric supercapacitors | Co-HHTPCo sites · HHTP | 2D · PristineSingle-metal HHTP MOF shown by SEM in the SI; synthesis details not reported in the provided text layer. | Figure captions · Figure S2 |
| Co-MOF / Co3(HHTP)2 conductive metal-organic framework2025 · Flexible 8 V planar supercapacitors: Unleashing ionic liquid transport via Co/Ni/Mn-MOFs nanorod pore-channel modulation | Co3(HHTP)2Co cations; Co2+ assigned by XPS · 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP) | 2D · PristineIsomorphous conductive metal-catecholate c-MOF with hexagonal planar macrocycles aligned along the c-axis and pi-pi corrugated stacking into honeycomb nanorods. | 3 · 3.1 Physical and chemical characteristics · Fig. 1a |
| Co3(HHTP)22025 · Employing Triphenylene-Based, Layered, Conductive Metal-Organic Framework Materials as Electrochemical Sensors for Nitric Oxide in Aqueous Media | Co3(HHTP)2Co2+ · 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP) | 2D · PristineLayered conductive HHTP MOF; ABAB stacking with intercalated layers. | 554-555 · Characterization of HHTP MOFs · Figure 1 |
| Co3(HHTP)2 model2025 · Dirac-cone induced metallic conductivity in Cu3(HHTP)2: high-quality MOF thin films fabricated via ML-driven robotic synthesis | Co3(HHTP)2Co nodes in 2D HHTP framework · HHTP | 2D · Model SystemFully relaxed 2D high-spin computational model used for band-structure comparison. | p008 / SI page 8 · Band Structure Calculations · Figure 9 |
| Co3HHTP22025 · Photoactivated conductive MOF thin film arrays on micro-LEDs for chemiresistive gas sensing | Co3(HHTP)2Co · HHTP; H6HHTP | 2D · PristineCu3HHTP2 analogue used as an overlayer; described as sharing a similar hexagonal structure but too resistive as a standalone thin-film chemiresistor. | 2 · Introduction |
| Co-HHTP2024 · Conductive Metal−Organic Frameworks for Rechargeable LiOH-Based Li−O2 Batteries | M-HHTP, M = CoCo centres; XPS assigns Co2+/Co3+ · 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP) | 2D · PristineMonometallic conductive 2D M-HHTP framework with hexagonal rod morphology and XRD peaks matching the M-HHTP family. | 12027 (p001) · Abstract |
| Co-HHTP2024 · Successful In Situ Growth of Conductive MOFs on 2D Cobalt-Based Compounds and Their Electrochemical Performance | M-HHTP, M = Co; HHTP ligandCo2+ nodes · HHTP = 2,3,6,7,10,11-hexahydroxytriphenylene | 2D · PristineConductive HHTP framework; SEM showed random nanorods. | article p. 10324 · Abstract |
| Co-HHTP2024 · A novel pencil graphite electrode modified with an iron-based conductive metal-organic framework exhibited good ability in simultaneous sensing bisphenol A and bisphenol S | Co-HHTP; exact stoichiometry not reportedCo · HHTP | unknown · PristineMetal-HHTP control MOF used in sensing comparison. | 2,7 · 2.2.1; 3.3 · Fig. 3F |
| Co-HHTP conductive metal-organic framework2024 · Triggering Anodic Luminol Electrochemiluminescence through Electrostatic Interactions: An Innovative Approach Utilizing Conductive Metal-Organic Framework Co-HHTP | Co-HHTP; HHTP = 2,3,6,7,10,11-hexahydroxytriphenyleneCo nodes coordinated by oxygen donor sites of HHTP; Co-O bond confirmed by FTIR/XPS. · 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP) | 2D · PristineLayered/lamellar conductive MOF with hexagonal honeycomb lattice; XRD peaks assigned to (200), (210), and (002) facets. | 1 · Abstract |
| Co-HHTP@Co(OH)22024 · Successful In Situ Growth of Conductive MOFs on 2D Cobalt-Based Compounds and Their Electrochemical Performance | Co-HHTP@Co(OH)2 compositeCo2+ HHTP framework grown on Co(OH)2 · HHTP = 2,3,6,7,10,11-hexahydroxytriphenylene | 2D · CompositeIn situ grown conductive M-HHTP nanoarrays/nanorods on a 2D cobalt-based compound substrate. | article p. 10326 · Results and Discussion · Figure 1 |
| Co-HHTP@Co3O42024 · Successful In Situ Growth of Conductive MOFs on 2D Cobalt-Based Compounds and Their Electrochemical Performance | Co-HHTP@Co3O4 compositeCo2+ HHTP framework grown on Co3O4 · HHTP = 2,3,6,7,10,11-hexahydroxytriphenylene | 2D · CompositeIn situ grown conductive M-HHTP nanoarrays/nanorods on a 2D cobalt-based compound substrate. | article p. 10326 · Results and Discussion · Figure 1 |
| Co-HHTP@CoP2024 · Successful In Situ Growth of Conductive MOFs on 2D Cobalt-Based Compounds and Their Electrochemical Performance | Co-HHTP@CoP compositeCo2+ HHTP framework grown on CoP · HHTP = 2,3,6,7,10,11-hexahydroxytriphenylene | 2D · CompositeIn situ grown conductive M-HHTP nanoarrays/nanorods on a 2D cobalt-based compound substrate. | article p. 10326 · Results and Discussion · Figure 1 |
| Co3HHTP22024 · Humidity-Mediated Dual Ionic-Electronic Conductivity Enables High Sensitivity in MOF Chemiresistors | Co3(HHTP)2Co nodes in a triphenylene-based 2D conductive MOF · HHTP | 2D · PristineTriphenylene-based cMOF control; PXRD and SEM shown in SI. | p002 / article p.20214 · Results and Discussion · Figures S4 and S5 |
| luminol@Co-HHTP2024 · Triggering Anodic Luminol Electrochemiluminescence through Electrostatic Interactions: An Innovative Approach Utilizing Conductive Metal-Organic Framework Co-HHTP | luminol-loaded Co-HHTP host-guest constructCo nodes in Co-HHTP host framework. · HHTP framework linker plus luminol guest molecules. | 2D · CompositeGuest-loaded Co-HHTP; main text reports retained lamellar structure and preserved diffraction peak positions after encapsulation based on SI figures. | 5 · Results and Discussion · Figure S5-S9 cited |
| Co-catecholate (Co-CAT)2023 · Creating Dual Active Sites in Conductive Metal-Organic Frameworks for Efficient Water Splitting | Co-CAT; cobalt coordinated to HHTP-derived catecholate linkerCo centres coordinated with O atoms · 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP) | 2D · PristineM-CAT framework with peaks assigned to (100), (200), (210), and c-direction stacking; trigonal space group P-3c1; two alternatively stacked A and B layers. | article p.2 · Results and Discussion · Figure 1b |
| Co-HHTP conductive metal-organic framework2023 · Hierarchical conductive metal-organic framework films enabling efficient interfacial mass transfer | Co-HHTPCo coordination nodes · 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP) | 2D · PristineCrystalline conductive HHTP-based c-MOF film; hollow and bulk variants compared. | 6 · Generality of the HSAID strategy · Fig. 6c,d |
| Co-MOF/CPE modified carbon paste electrode2023 · Controllable Construction of Two-Dimensional Conductive M3(HHTP)2 Nanorods for Electrochemical Sensing of Malachite Green in Fish | Co3(HHTP)2 + graphite powder + paraffin oilCo3(HHTP)2 nanorod component. · HHTP in the Co3(HHTP)2 component. | unknown · CompositeComposite carbon-paste comparison electrode containing 2 wt% Co3(HHTP)2 nanorods. | main p.3, article p.22918 · Preparation of the M3(HHTP)2 Nanorod Modified Electrode |
| Co3(HHTP)2 cobalt catecholate conductive MOF2023 · Ligand-Oxidation-Based Anodic Synthesis of Oriented Films of Conductive M-Catecholate Metal-Organic Frameworks with Controllable Thickness | Co3(HHTP)2Co ions coordinated by catecholate HHTP ligands. · HHTP | 2D · Pristine2D M-catecholate MOF film, assigned from EDX, XRD and FT-IR and reported as out-of-plane oriented. | main p.6, article p.25575 · Results and Discussion · Figures S27-S38 |
| Co3(HHTP)2 nanorods2023 · Controllable Construction of Two-Dimensional Conductive M3(HHTP)2 Nanorods for Electrochemical Sensing of Malachite Green in Fish | Co3(HHTP)2Co centres from cobalt(II) acetate tetrahydrate. · HHTP | 2D · PristineNanorod-like p-d conjugated 2D conductive MOF. | main p.3, article p.22918 · Preparation of M3(HHTP)2 Nanorod Materials · Figure 1C,C1 |
| Co3HHTP2 control MOF2023 · Modular conductive MOF-gated field-effect biosensor for sensitive discrimination on the small molecular scale | Co3HHTP2Cobalt nodes; SI XPS caption states presence of Co2+, C and O. · HHTP ligand. | 2D · PristineStructurally similar HHTP-based control film; SI caption reports characteristic XRD peaks and UV-vis absorptions near 360 and 630 nm associated with aromatic pi-pi* and ligand-to-metal charge-transfer transitions. | SI text · Supplementary Figures and Tables · Fig. S19 |
| CoHHTP conductive MOF2023 · Cu/Co bimetallic conductive MOFs: Electronic modulation for enhanced nitrate reduction to ammonia | CoHHTP nominalCo-O4 nodes · HHTP | 2D · PristineCoHHTP HHTP framework with sharp (100) peak at 4.82 degree | 2 · 3.1 · Fig. 1b |
| Ir-doped Co-CAT (IrCo-CAT)2023 · Creating Dual Active Sites in Conductive Metal-Organic Frameworks for Efficient Water Splitting | IrCo-CAT; Ir and Co in HHTP-derived catecholate frameworkCo centres with doped Ir atoms · HHTP-derived catecholate linker | 2D · PristineSame crystalline structure as RuCo-CAT and Co-CAT by XRD. | article p.5 · Results and Discussion · Figure S12 referenced |
| Rh-doped Co-CAT (RhCo-CAT)2023 · Creating Dual Active Sites in Conductive Metal-Organic Frameworks for Efficient Water Splitting | RhCo-CAT; Rh and Co in HHTP-derived catecholate frameworkCo centres with doped Rh atoms · HHTP-derived catecholate linker | 2D · PristineSame crystalline structure as RuCo-CAT and Co-CAT by XRD. | article p.5 · Results and Discussion · Figure S12 referenced |
| Ru-doped Co-CAT (RuCo-CAT)2023 · Creating Dual Active Sites in Conductive Metal-Organic Frameworks for Efficient Water Splitting | RuCo-CAT; Ru and Co coordinated to HHTP-derived catecholate linkerCo centres with doped Ru atoms; Ru-O and Co-O coordination · HHTP-derived catecholate linker | 2D · PristineRu-doped M-CAT retains Co-CAT crystalline structure and P-3c1 stacked-layer assignment. | article pp.2-3 · Results and Discussion · Figure 1 |
| Co-CAT2022 · Conductive Metal-Organic Frameworks Bearing M−O4 Active Sites as Highly Active Biomass Valorization Electrocatalysts | Co metal-catecholate framework with Co-O4 active sitesCo2+/Co3+ centres coordinated by catecholate oxygens · 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP) | 2D · PristineConductive metal-catecholate framework consisting of 2D layers; XRD peaks at 9.2 and 13.9 degrees assigned to (200) and (3-11) planes and matching calculated Co-CAT pattern. | 2 · Introduction / Results and Discussion · Figures 1 and 2 |
| Co-CAT MOF / Co3(HHTP)22022 · Conductive Co-based metal organic framework nanostructures for excellent potassium- and lithium-ion storage: kinetics and mechanism studies | Co3(HHTP)2Co ions coordinated by hydroxyl/oxygen donor groups; Co remains divalent by XPS · HHTP = 2,3,6,7,10,11-hexahydroxytriphenylene | 2D · PristineTwo-dimensional pi-conjugated honeycomb framework stacked along the c-axis; nanowire network morphology; XRD peaks at 4.65 and 9.34 degrees assigned to (100) and (200) planes. | 4076 · Results and discussion · Scheme S1; Fig. 2A |
| Co-CAT//LiCoO2 full cell2022 · Conductive Co-based metal organic framework nanostructures for excellent potassium- and lithium-ion storage: kinetics and mechanism studies | Co3(HHTP)2 anode paired with LiCoO2 cathodeCo nodes in Co-CAT MOF anode; Co in LiCoO2 cathode · HHTP linker in Co-CAT anode | unknown · CompositeComposite full cell assembled from Co3(HHTP)2 anode and commercial LiCoO2 cathode. | 4082 · Results and discussion · Fig. 8 |
| Co3(HHTP)22022 · Epitaxial Self-Assembly of Interfaces of 2D Metal-Organic Frameworks for Electroanalytical Detection of Neurotransmitters | Not specified['Co'] | unknown · Unknown | 1 · Abstract |
| Co-CAT-1 two-dimensional metal-organic framework2021 · Large Single Crystals of Two-Dimensional π-Conjugated Metal-Organic Frameworks via Biphasic Solution-Solid Growth | Co-catecholate HHTP framework; exact formula not restated in this paperCobalt catecholate nodes from cobalt acetate · HHTP | 2D · PristinePlanar Co-CAT-1 crystals grown by the same solution-solid route; EDS and FTIR support identity. | p004 · Results and Discussion · Figure S17 and Figure S18 |
| Co3(HHTP)22021 · Two-Dimensional Conductive Metal-Organic Frameworks as Highly Efficient Electrocatalysts for Lithium-Sulfur Batteries | Co3(HHTP)2Co transition-metal nodes coordinated by N/O/S donor atoms in the 2D framework · HHTP (2,3,6,7,10,11-hexahydroxytriphenylene; C18H6O6) | 2D · Model SystemO-coordinated TM3(HHTP)2 kagome 2D MOF; periodic monolayer slab model with kagome sublattice where applicable. | PDF p2 / article p.61206 · Introduction |
| Co-CAT2020 · Trimetallic conductive metal-organic frameworks as precatalysts for the oxygen evolution reaction with enhanced activity | Co3(HHTP)2 / M-CAT family, described as stacked Co3(HHTP)2(H2O)6 and Co3(HHTP)(H2O)12 layersCo2+ nodes · HHTP, 2,3,6,7,10,11-hexahydroxytriphenylene | 2D · PristineConductive M-CAT; alternating stacked 2D layers with hydrogen bonding and pi-pi interactions along [001]. | 1 · Introduction |
| Co-CAT-12019 · Oriented Thin Films of Electroactive Triphenylene Catecholate-Based Two-Dimensional MetalOrganic Frameworks | Idealised Co3(HHTP)2 / Co3(C18H6O6)2; exact empirical formula not reported in this paperSquare-planar Co(II) catecholate nodes within extended 2D sheets. · 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP) tricatecholate linker. | 2D · PristineLayered triphenylene metal-catecholate M-CAT-1 framework; GIWAXS and PXRD consistent with crystalline M-CAT-1 phase. | p002-p003 · Results and Discussion · Figure 2; Table S1 |
| Co3(HHTP)22019 · Conductive metal–organic framework with redox metal center as cathode for high rate performance lithium ion battery | Co3(HHTP)2Co cations · 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP) | 2D · PristineCobalt analogue of the HHTP framework, prepared under the same conditions for comparison. | 5 · 3.3. Lithium ion insertion-desertion discussion · Fig. S6 |
| Co3(HHTP)2 trigonal MOF2018 · Modular O2 electroreduction activity in triphenylene-based metal-organic frameworks | Co3(HHTP)2Co-containing honeycomb sheets alternating with trinuclear M3(HHTP)(H2O)12 clusters. · HHTP / hexahydroxytriphenylene. | 2D · PristineTrigonal crystal system with alternating honeycomb layers and rotated trinuclear clusters. | 1 · Results and discussion · Fig. 1 |
| Co3HHTP2 MOF2018 · Conductive Metal-Organic Frameworks as Ion-to-Electron Transducers in Potentiometric Sensors | Co3HHTP2Co · HHTP | 2D · PristineLayered conductive metal-catecholate MOF; PXRD consistent with slipped parallel packing; XPS shows mixed Co2+/Co3+ valency. | 3 · Characterization of M3HHTP2 MOFs · Figures S1-S5 |
| Co3HHTP22017 · Drawing sensors with ball-milled blends of metal-organic frameworks and graphite | Co3(HHTP)2Co acetate-derived Co nodes · 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP) | 2D · Pristineisoreticular 2D M3HHTP2 metal-catecholate framework | 3 of 17 · Introduction / Results 3.1 · Figure 1A |
| Co3HHTP2/graphite blend2017 · Drawing sensors with ball-milled blends of metal-organic frameworks and graphite | Co3(HHTP)2 + graphite, 9:1 MOF:graphite by massCo nodes in MOF component · HHTP in MOF component; graphite conductive additive | 2D · Compositeball-milled MOF/graphite composite retaining MOF component; graphite (002) peak retained | 6-7 of 17 · Results 3.2 · Figure 2 and Figure S8 |