This family merges chemical shorthand and formula variants only after verification against source articles. Per-paper composition and phase details remain separate below.
Guest-loaded, defect-engineered, exchanged, composite and commercial-grade samples remain visible as variants; conflicting source formulas are not silently corrected.
Paper counts are material-linked through samples and measurements; technique groups are not value rankings.
Distinct primary papers in this browse group by publication year.
Filter the material-linked paper set while keeping every result in its original dossier.
30 papers
Zhang F., Jiao C., Shang Y. et al. · ACS Sensors · 2024
Reported here: Cu2O@Cu3(BTC)2
Tien Dat N., Ngoc Tien N., Ngan N.T.T. et al. · Analyst · 2023
Reported here: Cu-BTC
Dong P., Zhang X., Hiscox W. et al. · Advanced Materials · 2023
Reported here: HKUST-1 nanoparticles
Chen X., Zhang K., Hassan Z.M. et al. · Journal of Physics Condensed Matter · 2022
Reported here: HKUST-1 SURMOF thin film · TCNQ-loaded HKUST-1 SURMOF thin film
Kang M.S., Heo I., Cho K.G. et al. · Energy Storage Materials · 2022
Reported here: Monodisperse HKUST-1 MOF crystals (mMOF) · polymer@MOF
Gaikwad S., Kim Y., Gaikwad R. et al. · Journal of Environmental Chemical Engineering · 2022
Reported here: HKUST-1 / Basolite C300
Thong C.-H., Priyanga N., Ng F.-L. et al. · Catalysis Today · 2022
Reported here: Cu-MOF
Hsieh P.-F., Law Z.X., Lin C.-H. et al. · Langmuir · 2022
Reported here: Cu-MOF / HKUST-1 / Cu-BTC colloids
Wen X., Huang Q., Nie D. et al. · Molecules · 2021
Reported here: N-doped Cu-MOF (N-Cu-MOF)
Jung S., Huelsenbeck L., Hu Q. et al. · ACS Applied Materials and Interfaces · 2021
Reported here: HKUST-1 · TCNQ@HKUST-1
He Y., Yang S., Fu Y. et al. · Small Structures · 2021
Reported here: BQ@Cu3(BTC)2 thin film · Cu3(BTC)2 and acceptor-loaded Cu3(BTC)2 DFT model systems · Cu3(BTC)2 thin film (HKUST-1-type Cu-BTC MOF) · PMDI@Cu3(BTC)2 thin film · TCNQ@Cu3(BTC)2 thin film
Okada K., Mori K., Fukatsu A. et al. · Journal of Materials Chemistry A · 2021
Reported here: Oriented Cu3(BTC)2 thin film · Oriented TCNQ@Cu3(BTC)2 thin film
Sun Z., Peng Y., Wang M. et al. · Analytical Chemistry · 2020
Reported here: electrodeposited Cu-MOF thin film
Kanj A.B., Verma R., Liu M. et al. · Nano Letters · 2019
Reported here: [BMIM][NTf2]@HKUST-1 SURMOF · Atomistic [BMIM][NTf2] in HKUST-1 model · HKUST-1 SURMOF
Li X.-F., Lu M.-Y., Yu H.-Y. et al. · ChemElectroChem · 2019
Reported here: HKUST-1 · HKUST-1@carbon paper hybrid
Bodkhe G.A., Deshmukh M.A., Patil H.K. et al. · Journal of Physics D: Applied Physics · 2019
Reported here: CuBTC (HKUST-1)
Wu F., Fang W., Yang X. et al. · Journal of the Chinese Chemical Society · 2019
Reported here: HKUST-1
Zhang M., Zhang A.-M., Wang X.-X. et al. · Journal of Materials Chemistry A · 2018
Reported here: PMo10V2-ILs@HKUST-1 · PMo10V2@HKUST-1
Schneider C., Ukaj D., Koerver R. et al. · Chemical Science · 2018
Reported here: Cu3BTC2 (HKUST-1) · CuTCNQ/Cu3BTC2 physical mixture · TCNQ@Cu3BTC2 from liquid phase infiltration · xTCNQ@Cu3BTC2
Zhang B., Li C., Yang G. et al. · ACS Applied Materials and Interfaces · 2018
Reported here: HKUST-1 Cu-MOF-coated Cu/Cu2O nanodendrites
Thurmer K., Schneider C., Stavila V. et al. · ACS Applied Materials and Interfaces · 2018
Reported here: Cu3BTC2 (HKUST-1)
Muller K., Fink K., Schottner L. et al. · ACS Applied Materials and Interfaces · 2017
Reported here: Defective HKUST-1 with Cu+ paddle-wheel defects · HKUST-1 / Cu2(BTC)3
Zhang F., Zhang T., Zou X. et al. · Solid State Ionics · 2017
Reported here: NENU-3 film · PTA-free HKUST-1 control
Gu Z.-G., Chen S.-C., Fu W.-Q. et al. · ACS Applied Materials and Interfaces · 2017
Reported here: PTB7-Th/HKUST-1/SiO2/Si OFET stack · SURMOF HKUST-1 thin film
Bhardwaj S.K., Sharma A.L., Bhardwaj N. et al. · Sensors and Actuators, B: Chemical · 2017
Reported here: anti-PSA antibody immobilised TCNQ-Cu3(BTC)2 · Cu3(BTC)2 copper metal-organic framework · TCNQ-doped Cu3(BTC)2
Liu T.-Z., Hu R., Zhang X. et al. · Analytical Chemistry · 2016
Reported here: Ab2-modified Au-MOF signal probe · Au-MOFs · Cd2+-exchanged HKUST-1 MOFs · HKUST-1 MOFs
Neumann T., Liu J., Wachter T. et al. · ACS Nano · 2016
Reported here: F4-TCNQ-loaded HKUST-1 SURMOF · F4-TCNQ/HKUST-1 model system · HKUST-1 SURMOF · TCNQ-loaded HKUST-1 SURMOF · TCNQ/HKUST-1 model system
Erickson K.J., Leonard F., Stavila V. et al. · Advanced Materials · 2015
Reported here: Cu3(BTC)2; HKUST-1 · TCNQ@Cu3(BTC)2
Talin A.A., Centrone A., Ford A.C. et al. · Science · 2014
Reported here: Cu3(BTC)2 (HKUST-1) · F4-TCNQ@Cu3(BTC)2 · Guest@Cu3(BTC)2 computational model systems · H4-TCNQ@Cu3(BTC)2 · TCNQ@Cu3(BTC)2
Jeremias F., Henninger S.K., Janiak C. · Chemical Communications · 2012
Reported here: Commercial copper trimesate Basolite C-300 · HKUST-1 / copper trimesate · HKUST-1 coating on copper sheet
No linked paper matches these filters.
Raw names, formulas and structural assignments remain separate; no consensus value is inferred.
| Paper and reported name | Formula and components | Structure context | Source |
|---|---|---|---|
| Cu2O@Cu3(BTC)22024 · In Situ Growth of Conductive Metal-Organic Framework onto Cu2O for Highly Selective and Humidity-Independent Hydrogen Sulfide Detection in Food Quality Assessment | Cu2O@Cu3(BTC)2Cu2O core plus Cu nodes in Cu3(BTC)2 · 1,3,5-benzenetricarboxylate (BTC) | 3D · CompositeMOF-coated Cu2O comparison material; XRD pattern shown in SI Figure S11. | p007 / 1316 · Results and Discussion · Figure S11 |
| Cu-BTC2023 · Sensing interface based on electrodeposited Cu-BTC microporous film for electrochemical detection of the painkiller paracetamol | Cu3(BTC)2 / Cu3(TMA)2(H2O)3 framework assignmentdimeric copper(II) carboxylate units; copper ion centres · benzene-1,3,5-tricarboxylate (BTC, trimesate) | 2D · PristineTwo-dimensional Cu-BTC film; octahedral Cu-BTC crystals observed by SEM; coordination confirmed by Raman/FTIR. | p001 / 1777 · Abstract and Introduction |
| HKUST-1 nanoparticles2023 · Toward High-Performance Metal–Organic-Framework-Based Quasi-Solid-State Electrolytes: Tunable Structures and Electrochemical Properties | Cu3(BTC)2; BTC = benzene-1,3,5-tricarboxylateCu2 paddle-wheel units; open Cu2+ sites exposed only toward pore 2. · H3BTC-derived BTC linker | 3D · Pristine3D-channel multimodal pores; pore 1 about 11 A without open Cu2+ sites and pore 2 about 13.5 A with open Cu2+ sites; ion-conducting aperture reported as 6.9 A. | article p.3 · Figure 1 caption · Figure 1 |
| Cu-MOF2022 · Metal organic frameworks (MOFs) as potential anode materials for improving power generation from algal biophotovoltaic (BPV) platforms | Cu3(BTC)2-type copper trimesate frameworkCu2+ paddlewheel/dimeric Cu(II) units · BTC / benzene-1,3,5-tricarboxylate | 3D · PristineCu-BTC-type crystalline MOF; text reports Cu3(BTC)2 units and XRD indexed to JCPDS no. 00-62-1183 cubic crystalline structure, while the abstract calls it monoclinic. | p003 / journal page 421 · 3.1 Morphological Analysis |
| Cu-MOF / HKUST-1 / Cu-BTC colloids2022 · Understanding Solvothermal Growth of Metal-Organic Framework Colloids for CO2Capture Applications | HKUST-1 Cu-BTC framework, commonly Cu3(BTC)2; exact empirical formula not printed for samplesCu(II) centres from copper(II) nitrate trihydrate · 1,3,5-benzenetricarboxylic acid (H3BTC; trimesic acid/BTC) | 3D · PristineHKUST-1; XRD peaks at 6.7, 9.5, 11.6 and 13.5 deg 2theta assigned to (200), (220), (222) and (400) planes. | 4416 · Introduction |
| HKUST-1 / Basolite C3002022 · Enhanced VOC adsorption capacity on MOF thin layer with reduced particle size by cryogrinding and microwave method | commonly Cu3(BTC)2; formula not stated in main textCu paddlewheel framework implied by HKUST-1 identity · benzene-1,3,5-tricarboxylate (BTC), implied by HKUST-1 identity | 3D · PristineCommercial HKUST-1; characteristic XRD peaks at 9.5, 11.5 and 13.5 deg retained after cryogrinding. | 3 · 2.1 Materials |
| HKUST-1 SURMOF thin film2022 · Charge. transport, conductivity and Seebeck coefficient in pristine and TCNQ loaded preferentially grown metal-organic framework films | HKUST-1, commonly Cu3(BTC)2; BTC = benzenetricarboxylateCu(II) paddlewheel dimers · benzene-tricarboxylate (BTC) | 3D · PristineCrystalline 3D porous HKUST-1 framework grown as surface-anchored MOF thin films; random polycrystalline or preferentially (001)-oriented depending on substrate/interface. | article page 2 · Introduction |
| Monodisperse HKUST-1 MOF crystals (mMOF)2022 · Coarsening-induced hierarchically interconnected porous carbon polyhedrons for stretchable ionogel-based supercapacitors | HKUST-1, [Cu3(btc)2] as written in main textCu nodes / open Cu metal sites · btc (benzene-1,3,5-tricarboxylate; named only as btc in main text) | 3D · PristineMonodisperse octahedral HKUST-1 crystals prepared by modified hydrothermal synthesis with PVP modulator; Figure S2 reportedly shows same crystalline and textural features as conventional HKUST-1. | p002 / journal page 381 · Results and discussion · Figure 2a |
| polymer@MOF2022 · Coarsening-induced hierarchically interconnected porous carbon polyhedrons for stretchable ionogel-based supercapacitors | phenol-formaldehyde polymer infiltrated in HKUST-1Cu sites from HKUST-1 · btc plus phenol-formaldehyde polymer precursor | 3D · CompositeOctahedral polymer-infiltrated HKUST-1 composite retaining characteristic HKUST-1 XRD peaks after vapour-phase polymerisation. | p002 / journal page 381 · Results and discussion · Figure 2b |
| TCNQ-loaded HKUST-1 SURMOF thin film2022 · Charge. transport, conductivity and Seebeck coefficient in pristine and TCNQ loaded preferentially grown metal-organic framework films | HKUST-1@TCNQCu(II) paddlewheel dimers · benzene-tricarboxylate (BTC); TCNQ guest in pores | 3D · CompositeHKUST-1 framework with tetracyanoquinodimethane guest molecules infiltrated into the pores; XRD and Raman indicate guest loading without framework deterioration. | article page 3 · Figure 1 and text · Figure 1 |
| BQ@Cu3(BTC)2 thin film2021 · Electronic Doping of Metal-Organic Frameworks for High-Performance Flexible Micro-Supercapacitors | BQ guest-loaded/doped Cu3(BTC)2; BQ = benzoquinoneCu2+ sites in Cu3(BTC)2 framework interacting with BQ acceptor molecules. · BTC framework linker plus BQ guest/acceptor molecule. | 3D · CompositeDoped Cu3(BTC)2 thin film; XRD (333) peak shifts to lower degree versus undoped Cu3(BTC)2. | 2 · Results and Discussion · Figure 1 |
| Cu3(BTC)2 and acceptor-loaded Cu3(BTC)2 DFT model systems2021 · Electronic Doping of Metal-Organic Frameworks for High-Performance Flexible Micro-Supercapacitors | Model geometries of H2O@Cu3(BTC)2, TCNQ@Cu3(BTC)2, BQ@Cu3(BTC)2, and PMDI@Cu3(BTC)2Cu-based Cu3(BTC)2 model cluster/framework fragment. · BTC framework linker, with TCNQ, BQ, or PMDI guest molecules for doped model systems. | unknown · Model SystemCalculated geometries and orbitals used to rationalise LUMO lowering after doping. | Theoretical calculation and Figure captions · Figures S12-S15 |
| Cu3(BTC)2 thin film (HKUST-1-type Cu-BTC MOF)2021 · Electronic Doping of Metal-Organic Frameworks for High-Performance Flexible Micro-Supercapacitors | Cu3(BTC)2; BTC = benzene-1,3,5-tricarboxylateCu2+ centres generated in situ from Cu foil during Ag+-mediated reaction. · BTC / benzene-1,3,5-tricarboxylate from H3BTC. | 3D · PristinePolycrystalline Cu3(BTC)2 thin film; XRD compared with literature Cu3(BTC)2 and doped films. | 2 · Results and Discussion · Figure 1a |
| HKUST-12021 · Conductive, Large-Area, and Continuous 7,7,8,8-Tetracyanoquinodimethane@HKUST-1 Thin Films Fabricated Using Solution Shearing | Cu3(BTC)2Cu(II) dimers · 1,3,5-benzenetricarboxylate (BTC; trimesic acid-derived) | 3D · PristineHKUST-1 copper(II)-benzene-1,3,5-tricarboxylate framework; simple cubic structure reported in introduction. | 10203 · Introduction |
| N-doped Cu-MOF (N-Cu-MOF)2021 · A multifunctional n-doped cu–mofs (N–cu–mof) nanomaterial-driven electrochemical aptasensor for sensitive detection of deoxynivalenol | Cu-BTC/PVP-derived N-doped HKUST-1-type Cu-MOFCu-based MOF nodes; Cu variable valence states Cu(0), Cu+, Cu2+ discussed in electrochemical response · 1,3,5-benzenetricarboxylate from H3BTC; PVP used as nitrogen source/additive | 3D · PristineHKUST-1-type Cu-based MOF crystals with characteristic XRD peaks and regular octahedral morphology; nitrogen incorporation confirmed by elemental mapping. | p003 · 2.1 Characterization of the N-Cu-MOF · Figure 2 |
| Oriented Cu3(BTC)2 thin film2021 · Oriented growth of semiconducting TCNQ@Cu3(BTC)2MOF on Cu(OH)2: crystallographic orientation and pattern formation toward semiconducting thin-film devices | Cu3(BTC)2Cu paddlewheel nodes · BTC = 1,3,5-benzenetricarboxylate from H3BTC | 3D · PristineHKUST-1-type Cu3(BTC)2 grown epitaxially on aligned Cu(OH)2 nanobelts; two orientation relationships reported: [111bar](112)Cu3(BTC)2//[001](010)Cu(OH)2 and [001](110)Cu3(BTC)2//[001](010)Cu(OH)2. | 19614-19615 · 2.1 Oriented growth of Cu3(BTC)2 on Cu(OH)2 · Figures 1 and 2 |
| Oriented TCNQ@Cu3(BTC)2 thin film2021 · Oriented growth of semiconducting TCNQ@Cu3(BTC)2MOF on Cu(OH)2: crystallographic orientation and pattern formation toward semiconducting thin-film devices | TCNQ@Cu3(BTC)2Cu paddlewheel nodes · BTC framework linker; TCNQ guest = 7,7,8,8-tetracyanoquinodimethane | 3D · PristineGuest-loaded oriented Cu3(BTC)2 film where the {111} lattice plane/conducting path is present parallel and perpendicular to the substrate. | 19616 · 2.3 Anisotropic conductivity of the oriented TCNQ@Cu3(BTC)2 film · Figure 4 |
| PMDI@Cu3(BTC)2 thin film2021 · Electronic Doping of Metal-Organic Frameworks for High-Performance Flexible Micro-Supercapacitors | PMDI guest-loaded/doped Cu3(BTC)2; PMDI = pyromellitic diimideCu2+ sites in Cu3(BTC)2 framework interacting with PMDI acceptor molecules. · BTC framework linker plus PMDI guest/acceptor molecule. | 3D · CompositeDoped Cu3(BTC)2 thin film; XRD (333) peak shifts to lower degree versus undoped Cu3(BTC)2. | 2 · Results and Discussion · Figure 1 |
| TCNQ@Cu3(BTC)2 thin film2021 · Electronic Doping of Metal-Organic Frameworks for High-Performance Flexible Micro-Supercapacitors | TCNQ guest-loaded/doped Cu3(BTC)2; TCNQ = 7,7,8,8-tetracyanoquinododimethaneCu2+ sites in Cu3(BTC)2 framework interacting with TCNQ acceptor molecules. · BTC framework linker plus TCNQ guest/acceptor molecule. | 3D · CompositeDoped Cu3(BTC)2 thin film; XRD (333) peak shifts to lower degree and spectroscopy supports guest incorporation. | 2 · Results and Discussion · Figure 1 |
| TCNQ@HKUST-12021 · Conductive, Large-Area, and Continuous 7,7,8,8-Tetracyanoquinodimethane@HKUST-1 Thin Films Fabricated Using Solution Shearing | TCNQ@Cu3(BTC)2Cu(II) dimers / open metal sites in HKUST-1 · BTC framework linkers plus 7,7,8,8-tetracyanoquinodimethane guest | 3D · CompositeGuest-loaded HKUST-1 in which TCNQ binds to open metal sites while XRD indicates the HKUST-1 crystal structure is retained. | 10202 · Abstract |
| electrodeposited Cu-MOF thin film2020 · Electrochemical deposition of Cu metal-organic framework films for the dual analysis of pathogens | Cu-BTC framework, commonly Cu3(BTC)2; exact formula not explicitly statedCopper paddle-wheel nodes with Cu2+/Cu+ redox-active sites. · H3BTC / 1,3,5-benzenetricarboxylate | 3D · PristineCrystalline Cu-MOF with paddle-wheel-shaped metal corners connected by BTC linkers; XRD pattern of synthesized film is consistent with simulated Cu-MOF. | main p.3, article p.8997 · Characterization of MOF Films · Figure 1 |
| [BMIM][NTf2]@HKUST-1 SURMOF2019 · Bunching and Immobilization of Ionic Liquids in Nanoporous Metal-Organic Framework | [BMIM][NTf2] guest-loaded Cu3(BTC)2Cu paddle-wheel nodes · BTC framework linker with [BMIM][NTf2] ionic liquid guest | 3D · Composite[BMIM][NTf2] ionic liquid confined in regular HKUST-1 nanopores of dense SURMOF thin films. | 2115 · Results and Discussion · Figure 1 |
| Atomistic [BMIM][NTf2] in HKUST-1 model2019 · Bunching and Immobilization of Ionic Liquids in Nanoporous Metal-Organic Framework | 3 x 3 x 3 HKUST-1 supercell loaded with [BMIM][NTf2]Cu paddle-wheel nodes in HKUST-1 model · BTC framework linker; [BMIM][NTf2] cation/anion force-field model | 3D · Model SystemFully atomistic MD model using UFF4MOF for HKUST-1 and a literature IL force field. | 2119 · Methods - Molecular Dynamic Simulations |
| CuBTC (HKUST-1)2019 · Field effect transistor based on proton conductive metal organic framework (CuBTC) | Cu3(BTC)2 framework; article names copper benzene tricarboxylate (CuBTC)Cu(II) paddlewheel/copper metal centres · benzene-1,3,5-tricarboxylate (BTC) | 3D · PristineHKUST-1/CuBTC; XRD matched ICDD PDF 00-065-1028 and literature HKUST-1. | rendered page 3 / article p. 2 · Introduction |
| HKUST-12019 · Two-dimensional π-conjugated metal-organic framework with high electrical conductivity for electrochemical sensing | Not specified | 3D · UnknownComparator MOF electrode modifier; synthesis and composition not described in this paper. | p004 (journal p.525) · 3.2 Electrochemical sensing of DA · Figure S2 referenced |
| HKUST-12019 · Copper-Metal Organic Frameworks Electrodeposited on Carbon Paper as an Enhanced Cathode for the Hydrogen Evolution Reaction | Cu-BTC / Cu3(BTC)2 framework; exact formula not printedCopper centres; XPS assigns Cu2+ in HKUST-1 · H3BTC / 1,3,5-trimesic acid (benzene-1,3,5-tricarboxylate after coordination) | 3D · PristineHKUST-1 octahedral crystals; hydrothermal XRD matches simulated HKUST-1 and Raman patterns for ED and HT indicate the same crystal structure. | SI p002 · Experimental Section |
| HKUST-1 SURMOF2019 · Bunching and Immobilization of Ionic Liquids in Nanoporous Metal-Organic Framework | Cu3(BTC)2; exact formula not printed in articleCopper acetate-derived Cu paddle-wheel nodes · BTC / benzene-1,3,5-tricarboxylate | 3D · PristineRelatively rigid face-centred cubic HKUST-1 with 3D pores; SURMOF films grown in (100) orientation on interdigitated electrode substrates. | 2115 · Results and Discussion · Figure 1 and SI1 |
| HKUST-1@carbon paper hybrid2019 · Copper-Metal Organic Frameworks Electrodeposited on Carbon Paper as an Enhanced Cathode for the Hydrogen Evolution Reaction | HKUST-1 nanoparticles on carbon paperCu2+ centres in HKUST-1 with residual/predeposited copper species possible · H3BTC-derived BTC linker | 3D · CompositeElectrodeposited HKUST-1 nanoparticles directly anchored on conductive carbon paper/current collector. | 4507 · Abstract |
| Cu3BTC2 (HKUST-1)2018 · High electrical conductivity and high porosity in a Guest@MOF material: Evidence of TCNQ ordering within Cu3BTC2 micropores | Cu3BTC2Cu paddlewheel units with open Cu sites · BTC = 1,3,5-benzenetricarboxylate | 3D · PristineParent porous MOF framework, also known as HKUST-1; face-centred cubic parent structure referenced in PXRD discussion. | 7405 · Abstract/Introduction |
| Cu3BTC2 (HKUST-1)2018 · Surface Morphology and Electrical Properties of Cu3BTC2 Thin Films before and after Reaction with TCNQ | Cu3BTC2Cu paddlewheel units / open metal sites after desolvation · BTC = 1,3,5-benzenetricarboxylate | 3D · PristineParent porous MOF thin film; GIXRD before TCNQ treatment matches the Cu3BTC2 reference structure. | p001 / 39400 · Abstract |
| CuTCNQ/Cu3BTC2 physical mixture2018 · High electrical conductivity and high porosity in a Guest@MOF material: Evidence of TCNQ ordering within Cu3BTC2 micropores | CuTCNQ + Cu3BTC2Cu in Cu(TCNQ) and Cu3BTC2 · TCNQ and BTC | 3D · CompositePressed physical mixtures of CuTCNQ with pristine Cu3BTC2, used to test whether surface CuTCNQ impurity alone accounts for conductivity. | 7409 · Results and discussion · Figure S12 |
| HKUST-1 Cu-MOF-coated Cu/Cu2O nanodendrites2018 · Nanostructured CuO/C Hollow Shell@3D Copper Dendrites as a Highly Efficient Electrocatalyst for Oxygen Evolution Reaction | HKUST-1/Cu2O/CuCu ions in HKUST-1 plus Cu/Cu2O nanodendrite core · benzene-1,3,5-tricarboxylic acid / trimesic acid (BTC) | 3D · CompositeCu-MOF HKUST-1 thin layer uniformly coated on Cu/Cu2O nanodendrites; XRD shows HKUST-1, Cu2O, and Cu. | p002 / 23808 · Results and Discussion · Figure 1d-f |
| PMo10V2-ILs@HKUST-12018 · Encapsulating ionic liquids into POM-based MOFs to improve their conductivity for superior lithium storage | {Cu2[C6H3(CO2)3]4/3}6[PMo10V2O40]0.9516[C6H11N2]4.875 (speculated from ICP/elemental analysis)Cu nodes with PMo10V2 and imidazolium IL guests · BTC | 3D · CompositeHKUST-1 analogue with the same internal PMo10V2-ILs material but different external structure. | 14 · Calculation of the theoretical capacities |
| PMo10V2@HKUST-12018 · Encapsulating ionic liquids into POM-based MOFs to improve their conductivity for superior lithium storage | PMo10V2 encapsulated in Cu-BTC HKUST-1Cu nodes with PMo10V2 guest · BTC | 3D · CompositePOMOF control based on HKUST-1 external framework. | 2 (journal p. 8736) · Experimental |
| TCNQ@Cu3BTC2 from liquid phase infiltration2018 · High electrical conductivity and high porosity in a Guest@MOF material: Evidence of TCNQ ordering within Cu3BTC2 micropores | approximately 0.4TCNQ@Cu3BTC2 + n H2OCu paddlewheel units in Cu3BTC2 · BTC framework linker with TCNQ guest molecules; residual water/solvent present | 3D · PristineLiquid-infiltrated comparison sample retaining the Cu3BTC2 crystal structure but without pronounced (111) TCNQ ordering. | S15-S17 · Liquid phase infiltration · Figures S21-S24; Table S3 |
| xTCNQ@Cu3BTC22018 · High electrical conductivity and high porosity in a Guest@MOF material: Evidence of TCNQ ordering within Cu3BTC2 micropores | xTCNQ@Cu3BTC2, 0 <= x <= 1.0Cu paddlewheel units in Cu3BTC2 · BTC framework linker with TCNQ guest molecules | 3D · PristineGuest-loaded Cu3BTC2 with TCNQ preferentially ordered along the (111) lattice plane; Pawley fit suggests reduced symmetry/possible supercell at high loading. | 7405-7407 · Abstract/Results and discussion · Figures 1-3 |
| anti-PSA antibody immobilised TCNQ-Cu3(BTC)22017 · TCNQ-doped Cu-metal organic framework as a novel conductometric immunosensing platform for the quantification of prostate cancer antigen | antibody-TCNQ-Cu3(BTC)2Cu nodes of TCNQ-doped Cu3(BTC)2 · BTC, TCNQ, physically adsorbed anti-PSA antibody | 3D · CompositeBiofunctionalised TCNQ-Cu3(BTC)2 thin-film electrode, with antibody immobilisation evidenced by UV-vis, FTIR and Raman signatures. | 2 · 2.3 Immobilization of anti-PSA antibodies on TCNQ-Cu3(BTC)2 |
| Cu3(BTC)2 copper metal-organic framework2017 · TCNQ-doped Cu-metal organic framework as a novel conductometric immunosensing platform for the quantification of prostate cancer antigen | Cu3(BTC)2Cu(II) paddlewheel/open copper sites · BTC; trimesic acid/H3BTC | 3D · PristineCu-BTC/HKUST-1-type crystalline porous MOF; crystallinity agrees with literature XRD. | 2 · 2.1 Materials and equipment |
| Defective HKUST-1 with Cu+ paddle-wheel defects2017 · Defects as Color Centers: The Apparent Color of Metal-Organic Frameworks Containing Cu2+-Based Paddle-Wheel Units | HKUST-1 framework containing reduced Cu+ defect sites; exact defect stoichiometry not reportedCu paddle-wheel units with one Cu2+ reduced to Cu+ and loss of one carboxylate ligand in the model description · BTC framework with missing/removed linker coordination at defect sites | 3D · PristineDefect-bearing HKUST-1/SURMOF; defects are described as prevailing HKUST-1 defects that reduce symmetry and act as colour centres. | 2 · Results and Discussions · Figure 3 discussion |
| HKUST-1 / Cu2(BTC)32017 · Defects as Color Centers: The Apparent Color of Metal-Organic Frameworks Containing Cu2+-Based Paddle-Wheel Units | Cu2(BTC)3; BTC = benzene-1,3,5-tricarboxylateCu2+ paddle-wheel dimers connected by carboxylate groups · benzene-1,3,5-tricarboxylic acid / trimesic acid (BTC) | 3D · PristineCrystalline HKUST-1 framework; out-of-plane XRD patterns verify the HKUST-1 MOF structure of the thin-film samples. | 2 · Results and Discussions · Figure 1 |
| NENU-3 film2017 · Electrochemical synthesis of metal organic framework films with proton conductive property | PTA integrated in Cu3(BTC)2 cavities; paper also writes Cu2(BTC)3 in conclusionsCu paddlewheel/HKUST-type copper nodes · 1,3,5-benzenetricarboxylate (BTC3-) | 3D · PristineHost-guest MOF film containing Keggin-type phosphotungstic acid clusters occluded in the Cu3(BTC)2/HKUST-1 framework; PXRD matches simulated NENU-3 single-crystal pattern. | 1 · Abstract |
| PTA-free HKUST-1 control2017 · Electrochemical synthesis of metal organic framework films with proton conductive property | Cu3(BTC)2 / HKUST-1Cu paddlewheel nodes · 1,3,5-benzenetricarboxylate (BTC3-) | 3D · PristinePTA-free HKUST-1 comparison material used for water-stability and proton-conductivity control measurements. | 5-7 · Stability; Proton conduction · Fig. 6B; Fig. 8d; Fig. 9b |
| PTB7-Th/HKUST-1/SiO2/Si OFET stack2017 · Epitaxial Growth of MOF Thin Film for Modifying the Dielectric Layer in Organic Field-Effect Transistors | PTB7-Th on HKUST-1/SiO2/Si with Au source/drain electrodesCu nodes within HKUST-1 dielectric interlayer · BTC in HKUST-1; PTB7-Th semiconducting polymer active layer | unknown · CompositeTop-contact, bottom-gate OFET with HKUST-1 SURMOF modifying the SiO2 dielectric layer and PTB7-Th as the semiconductor. | 2 / 7260 · Figure caption and discussion · Figure 1 |
| SURMOF HKUST-1 thin film2017 · Epitaxial Growth of MOF Thin Film for Modifying the Dielectric Layer in Organic Field-Effect Transistors | Cu3(BTC)2Cu paddlewheel nodes from Cu(OAc)2 precursor · BTC = 1,3,5-benzenetricarboxylate | 3D · PristineHKUST-1 SURMOF thin film; XRD weak (222) and (333) peaks assigned to [111]-oriented HKUST-1. | 1 / 7259 · Abstract |
| TCNQ-doped Cu3(BTC)22017 · TCNQ-doped Cu-metal organic framework as a novel conductometric immunosensing platform for the quantification of prostate cancer antigen | TCNQ-Cu3(BTC)2Cu(II)/Cu(I)-accessible Cu nodes with TCNQ coordination at open metal sites · BTC plus infiltrated 7,7,8,8-tetracyanoquinodimethane (TCNQ) | 3D · CompositeTCNQ-infiltrated Cu3(BTC)2 charge-transfer adduct retaining MOF crystallinity. | 4 · 3.1 Mechanism of TCNQ doping in Cu3(BTC)2 |
| Ab2-modified Au-MOF signal probe2016 · Metal-organic framework nanomaterials as novel signal probes for electron transfer mediated ultrasensitive electrochemical immunoassay | CRP antibody/BSA functionalised Au-HKUST-1Cu2+ HKUST-1 nodes plus Au nanoparticles · 1,3,5-benzenetricarboxylic acid | 3D · CompositeAntibody-functionalised Au-MOF nanoprobe used as the electrochemical metal-ion label. | 3 · Preparation of Signal-MOFs-Metal Ion Probes · Scheme 1 |
| Au-MOFs2016 · Metal-organic framework nanomaterials as novel signal probes for electron transfer mediated ultrasensitive electrochemical immunoassay | Au nanoparticles incorporated into HKUST-1Cu2+ HKUST-1 nodes plus Au nanoparticles · 1,3,5-benzenetricarboxylic acid | 3D · CompositeComposite Au-MOF nanoparticles; EDS used to confirm Au presence. | 5 · Characterization · Figure 2c,d; Figure S13 |
| Cd2+-exchanged HKUST-1 MOFs2016 · Metal-organic framework nanomaterials as novel signal probes for electron transfer mediated ultrasensitive electrochemical immunoassay | Cd2+-exchanged Cu-BTC / HKUST-1Cu2+ HKUST-1 coordination sites partly exchanged with Cd2+ · 1,3,5-benzenetricarboxylic acid | 3D · PristineIon-exchanged MOF confirmed by chromogenic test, TEM morphology change, XPS Cd 3d peaks, and DPV Cd2+ response. | 4 · Immunoassay Using MOF-Metal-Ion Probes · Figures S3-S6 |
| F4-TCNQ-loaded HKUST-1 SURMOF2016 · Superexchange Charge Transport in Loaded Metal Organic Frameworks | F4-TCNQ@HKUST-1 / F4-TCNQ-loaded Cu-BTC SURMOFCu paddle-wheel / Cu2+ sites bridged by F4-TCNQ nitrile groups · BTC framework linker plus 2,3,5,6-tetrafluoro-7,7,8,8-tetracyanoquinodimethane guest | 3D · CompositeGuest-loaded HKUST-1 SURMOF; XRD indicates framework crystallinity retained and IRRAS/Raman indicate F4-TCNQ interaction with Cu2+ sites. | 7089 · Results and Discussion · Figure 4b,d |
| F4-TCNQ/HKUST-1 model system2016 · Superexchange Charge Transport in Loaded Metal Organic Frameworks | F4-TCNQ plus HKUST-1 fragment modelCu-containing MOF sites in model fragment · BTC-derived saturated linker fragments plus F4-TCNQ | unknown · Model SystemDFT/KMC model with F4-TCNQ guest and four MOF-sites used for electronic coupling and superexchange calculations. | S13 · 3.2 Marcus theory of hopping · Figure S10 |
| HKUST-1 MOFs2016 · Metal-organic framework nanomaterials as novel signal probes for electron transfer mediated ultrasensitive electrochemical immunoassay | Cu-BTC / HKUST-1Cu2+ ions · 1,3,5-benzenetricarboxylic acid | 3D · PristineHKUST-1 identified by synthesis from CuSO4 and 1,3,5-benzenetricarboxylic acid and an XRD peak at 12 degrees. | 3 · Preparation of MOFs · Figure 2 |
| HKUST-1 SURMOF2016 · Superexchange Charge Transport in Loaded Metal Organic Frameworks | Cu-BTC framework; HKUST-1 conventionally Cu3(BTC)2Cu paddle-wheel / Cu2+ sites · 1,3,5-benzenetricarboxylate (BTC) | 3D · PristineSurface-anchored HKUST-1 film with crystalline [111] orientation perpendicular to the substrate; XRD shows characteristic (111), (222) and (333) peaks. | 7089 · Results and Discussion · Figure 4 |
| TCNQ-loaded HKUST-1 SURMOF2016 · Superexchange Charge Transport in Loaded Metal Organic Frameworks | TCNQ@HKUST-1 / TCNQ-loaded Cu-BTC SURMOFCu paddle-wheel / Cu2+ sites bridged by TCNQ nitrile groups · BTC framework linker plus 7,7,8,8-tetracyanoquinodimethane guest | 3D · CompositeGuest-loaded HKUST-1 SURMOF; XRD indicates framework crystallinity retained and IRRAS/Raman indicate TCNQ interaction with Cu2+ sites. | 7089 · Results and Discussion · Figure 4a,c |
| TCNQ/HKUST-1 model system2016 · Superexchange Charge Transport in Loaded Metal Organic Frameworks | TCNQ plus HKUST-1 fragment modelCu-containing MOF sites in model fragment · BTC-derived saturated linker fragments plus TCNQ | unknown · Model SystemDFT/KMC model with TCNQ guest and four MOF-sites used for electronic coupling and superexchange calculations. | S13 · 3.2 Marcus theory of hopping · Figure S10 |
| Cu3(BTC)2; HKUST-12015 · Thin film thermoelectric metal-organic framework with high seebeck coefficient and low thermal conductivity | Cu3(BTC)2, where BTC = benzene-1,3,5-tricarboxylateCu(II) paddlewheel/dimer units in HKUST-1. · Benzene tricarboxylate (BTC). | 3D · PristinePolycrystalline HKUST-1 thin film with preferred (111) orientation; parent framework is insulating before TCNQ infiltration. | main p.1, article p.3453 · Introduction |
| TCNQ@Cu3(BTC)22015 · Thin film thermoelectric metal-organic framework with high seebeck coefficient and low thermal conductivity | TCNQ guest molecules in Cu3(BTC)2; experimentally observed average concentration described as about one TCNQ per poreCu(II) dimers in the Cu3(BTC)2 framework, bridged/interacting with TCNQ guest molecules. · BTC framework linkers plus tetracyanoquinodimethane (TCNQ) guest molecules. | 3D · CompositeGuest-loaded HKUST-1 thin film; TCNQ infiltration gives blue-green regions, C=N Raman features and electrically conducting behaviour. | main p.2, article p.3454 · Results · Figure 1 |
| Cu3(BTC)2 (HKUST-1)2014 · Tunable electrical conductivity in metal-organic framework thin-film devices | Cu3(BTC)2; hydrated as Cu3(BTC)2.xH2OBinuclear Cu(II) paddlewheel units · BTC, benzene-1,3,5-tricarboxylate | 3D · PristineFace-centred cubic Fm3m HKUST-1; preferred (111) orientation in thin films. | 1 · main text · Fig. 1C |
| F4-TCNQ@Cu3(BTC)22014 · Tunable electrical conductivity in metal-organic framework thin-film devices | F4-TCNQ@Cu3(BTC)2Cu(II) paddlewheel units · BTC plus infiltrated 2,3,5,6-tetrafluoro-7,7,8,8-tetracyanoquinodimethane | 3D · CompositeGuest-loaded HKUST-1 comparison material. | 3 · main text · Fig. 2A |
| Guest@Cu3(BTC)2 computational model systems2014 · Tunable electrical conductivity in metal-organic framework thin-film devices | H2O@CuBTC, TCNQ@Cu3(BTC)2, F4-TCNQ@Cu3(BTC)2, H4-TCNQ@Cu3(BTC)2 clusters and periodic TCNQ@Cu3(BTC)2Cu paddlewheel cluster or fixed periodic Cu3(BTC)2 framework · BTC and model guest molecules | unknown · Model SystemMolecular clusters optimised with NWChem; periodic model optimised with VASP/PBEsol. | 5 · Computational Methods · Figs. S5-S7 |
| H4-TCNQ@Cu3(BTC)22014 · Tunable electrical conductivity in metal-organic framework thin-film devices | H4-TCNQ@Cu3(BTC)2; elemental analysis model includes residual CH2Cl2Cu(II) paddlewheel units · BTC plus infiltrated H4-TCNQ | 3D · CompositeGuest-loaded HKUST-1 comparison material. | 3 · main text · Fig. 2A; Fig. 3A |
| TCNQ@Cu3(BTC)22014 · Tunable electrical conductivity in metal-organic framework thin-film devices | TCNQ@Cu3(BTC)2; elemental analysis consistent with 1 TCNQ:2 Cu3(BTC)2Cu(II) paddlewheel units bridged by TCNQ at open metal sites · BTC plus infiltrated 7,7,8,8-tetracyanoquinodimethane (TCNQ) | 3D · CompositeHKUST-1 framework retained after TCNQ infiltration; slight lattice expansion. | 1 · abstract |
| Commercial copper trimesate Basolite C-3002012 · High performance metal–organic-framework coatings obtained via thermal gradient synthesis | commercial copper trimesate / HKUST-1-type materialCu centres · trimesate | 3D · Model SystemCommercial copper trimesate used only for heat-capacity regression supporting coating thermal-conductivity calculations. | 5 · Heat capacity measurements · Figure S6 |
| HKUST-1 / copper trimesate2012 · High performance metal–organic-framework coatings obtained via thermal gradient synthesis | Cu3(btc)2Cu centres from copper nitrate precursor; HKUST-1 copper paddlewheel framework implied by copper trimesate assignment · benzene-1,3,5-tricarboxylate / trimesate (btc) from trimesic acid H3btc | 3D · PristineMajor crystalline phase assigned as HKUST-1 by PXRD against HKUST-1 simulation; top layer separated from copper surface is treated as crystalline HKUST-1. | 9708 · Abstract/Introduction |
| HKUST-1 coating on copper sheet2012 · High performance metal–organic-framework coatings obtained via thermal gradient synthesis | HKUST-1 top layer plus carbon-rich bottom layer on Cu supportCu centres in HKUST-1 coating; Cu substrate; bottom layer contains Cu species including Cu2O/rouaite by PXRD · trimesate in HKUST-1 top layer; bottom layer contains carbon-rich amorphous/polymeric organic material | 3D · CompositeTwo-layer coating: thicker HKUST-1 top layer and thin carbon-rich bottom layer; whole coating was modelled as layer 2 in laser-flash analysis. | 9709 · Results · Figure 4e,f |