cMOF Evidence Base
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Ni₃(HHTP)₂ / Ni–HHTP

This family merges chemical shorthand and formula variants only after verification against source articles. Per-paper composition and phase details remain separate below.

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49primary papers
73material records
199linked samples
466linked measurements
1,383linked results
2017–2026publication span

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  • Several formulas or formula descriptions are reported
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  • Pristine, composite, derived or model contexts are mixed
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Paper counts are material-linked through samples and measurements; technique groups are not value rankings.

Microscopy Morphology28 papers71 measurements · 156 resultsDiffraction Structure27 papers43 measurements · 113 resultsSpectroscopy26 papers79 measurements · 233 resultsElectrochemistry Application24 papers117 measurements · 424 resultsElectrical Transport18 papers41 measurements · 91 resultsPorosity17 papers25 measurements · 43 resultsOther13 papers25 measurements · 58 resultsSensing Application11 papers56 measurements · 231 resultsComputational Modelling6 papers9 measurements · 34 results

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Primary papers

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49 papers

Primary study2021

Soft Electrochemical Actuators with a Two-Dimensional Conductive Metal-Organic Framework Nanowire Array

Shi Y.-X., Wu Y., Wang S.-Q. et al. · Journal of the American Chemical Society · 2021

Reported here: core-shell Ni-CAT NWAs/CNF hybrid electrode · Ni-CAT conductive metal-organic framework · Ni-CAT NWAs/CNF based ionic IPMC actuator

Diffraction Structure · 4Electrical Transport · 1Electrochemistry Application · 25Microscopy Morphology · 4Other · 1Porosity · 2Spectroscopy · 5
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Primary study2020

Conductive MOFs as bifunctional oxygen electrocatalysts for all-solid-state Zn-air batteries

Pan N., Zhang H., Yang B. et al. · Chemical Communications · 2020

Reported here: Ni-HHTP conductive MOF · Ru-doped Ni-HHTP conductive MOF, high Ru · Ru-doped Ni-HHTP conductive MOF, intermediate Ru · Ru-doped Ni-HHTP conductive MOF, low Ru · Ru-doped Ni-HHTP conductive MOF, optimised composition

Diffraction Structure · 4Electrical Transport · 2Electrochemistry Application · 38Microscopy Morphology · 2Spectroscopy · 12
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Per-paper identity records

Raw names, formulas and structural assignments remain separate; no consensus value is inferred.

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Paper and reported nameFormula and componentsStructure contextSource
Ni-HHTP2026 · Structure and Electrical Transport Properties of Metal Cate-Cholate Frameworks: The Metal Center Matters†M-HHTP; HHTP = 2,3,6,7,10,11-hexahydroxytriphenyleneNi2+ nickel nodes coordinated to HHTP catecholate/semiquinone ligands · HHTP (2,3,6,7,10,11-hexahydroxytriphenylene), partially deprotonated/oxidised catecholate-semiquinone units after coordination2D · Pristine2D honeycomb-like HHTP framework with transition-metal catecholate coordination; Ni2+ inferred hexacoordinated octahedral.main p.1, article p.311 · Comprehensive Summary
Ni-HHTP2025 · In situ construction of a dual-metal 2D conjugated metal-organic framework on carbon paper for asymmetric supercapacitorsNi-HHTPNi sites · HHTP2D · PristineSingle-metal HHTP MOF shown by SEM in the SI; synthesis details not reported in the provided text layer.Figure captions · Figure S2
Ni-HHTP2025 · Dual-metal sites enable conductive metal-organic frameworks with extraordinary high capacitance for transparent energy storage devicesNi-HHTPNi · HHTP2D · PristineSingle-metal layered HHTP c-MOF control with rod-like morphology.p003 / 9278 · Results and discussion · Fig. 2
Ni-HHTP2025 · Mitigating lipid biofouling in wearable sweat sensors: A study on conductive MOF-based electrodes with tuned hydrophilicityNi3(HHTP)2(H2O)12Ni nodes · HHTP (2,3,6,7,10,11-hexahydroxytriphenylene)2D · Pristine2D conductive MOF; PXRD peaks consistent with simulated Ni-HHTP pattern4 · Fig. 2 caption · Fig. 2b
Ni-HHTP coordination complex in solution2025 · Mechanistic Insight into the Formation and Deposition of Conductive, Layered Metal-Organic Framework Nanocrystalssolution-phase Ni2+-HHTP coordination complex; exact formula not isolatedNi2+ from nickel(II) acetate · HHTP0D · Model SystemTransient coordination complex/oligomer formed before oxidant-driven MOF crystallite growth.p008 / journal page 1390 · Observations of the Initial Phase · Figure 5
Ni-HHTP electrically conductive MOF2025 · Stacking growth of ionically conductive MOF on biofabrics enables reliable NH3 sensor for hepatic encephalopathy diagnosisNi-HHTPNi2+ coordinated with HHTP ligands · HHTP2D · PristineM-HHTP EC-MOF analogue prepared by LBL-LPE.p003 · Performance comparison of M-HHTP and M-TCPP · Figure 3a
Ni-MOF / Ni3(HHTP)2 conductive metal-organic framework2025 · Flexible 8 V planar supercapacitors: Unleashing ionic liquid transport via Co/Ni/Mn-MOFs nanorod pore-channel modulationNi3(HHTP)2Ni cations; Ni2+ assigned by XPS · 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP)2D · PristineIsomorphous conductive metal-catecholate c-MOF with hexagonal planar macrocycles aligned along the c-axis and pi-pi corrugated stacking into honeycomb nanorods.3 · 3.1 Physical and chemical characteristics · Fig. 1a
Ni3(HHTP)22025 · Employing Triphenylene-Based, Layered, Conductive Metal-Organic Framework Materials as Electrochemical Sensors for Nitric Oxide in Aqueous MediaNi3(HHTP)2Ni2+ · 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP)2D · PristineLayered conductive HHTP MOF; ABAB stacking with intercalated layers.554-555 · Characterization of HHTP MOFs · Figure 1
Ni3(HHTP)22025 · Mechanistic Insight into the Formation and Deposition of Conductive, Layered Metal-Organic Framework NanocrystalsNi3(HHTP)2 used as a connectivity descriptor for the 2D coordinated layer; cobalt/nickel HHTP analogues also contain an intercalated layer and edge/defect/solvent sites not captured by the formulaNi2+ dominant redox state; nickel-catecholate/bis-dioxolene coordination nodes · 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP)2D · PristineLayered conductive MOF; ABAB packing with conjugated and intercalated HHTP-metal layers, isostructural to Co3(HHTP)2 simulation used for PXRD assignment.p003 / journal page 1385 · Experimental Design - Naming conventions
Ni3(HHTP)2 model2025 · Dirac-cone induced metallic conductivity in Cu3(HHTP)2: high-quality MOF thin films fabricated via ML-driven robotic synthesisNi3(HHTP)2Ni nodes in 2D HHTP framework · HHTP2D · Model SystemFully relaxed 2D high-spin computational model used for band-structure comparison.p008 / SI page 8 · Band Structure Calculations · Figure 8
Ni3HHTP22025 · Photoactivated conductive MOF thin film arrays on micro-LEDs for chemiresistive gas sensingNi3(HHTP)2Ni · HHTP; H6HHTP2D · PristineCu3HHTP2 analogue used as an overlayer; described as sharing a similar hexagonal structure but too resistive as a standalone thin-film chemiresistor.2 · Introduction
AgNPs/Ni3(HHTP)22024 · A highly sensitive AgNPs/Ni3(HHTP)2 SERS substrate for the detection of food additives and pesticide residuesAgNPs/Ni3(HHTP)2Ni2+ in Ni3(HHTP)2 plus metallic Ag nanoparticles · HHTP in Ni3(HHTP)22D · CompositeComposite SERS substrate formed by loading a monolayer AgNP film on rod-shaped Ni3(HHTP)2.2 · Introduction
luminol@Ni-HHTP2024 · Triggering Anodic Luminol Electrochemiluminescence through Electrostatic Interactions: An Innovative Approach Utilizing Conductive Metal-Organic Framework Co-HHTPluminol-loaded Ni-HHTP host-guest constructNi nodes in Ni-HHTP host framework. · HHTP framework linker plus luminol guest molecules.2D · CompositeGuest-loaded Ni-HHTP comparator, synthesised by the same luminol@M-HHTP route and used in ECL/EIS comparison.4 · Figure caption · Figure 3H-I
Ni-HHTP2024 · Metal-organic frameworks with fine-tuned interlayer spacing for microwave absorptionNi3(HHTP)2Ni2+ centres · HHTP2D · PristineLayered HHTP cMOF analogue used in the ZnNi-HHTP extension.7 · Materials and Methods · Fig. S15
Ni-HHTP2024 · Conductive Metal−Organic Frameworks for Rechargeable LiOH-Based Li−O2 BatteriesM-HHTP, M = NiNi centres; XPS assigns Ni2+/Ni3+ · 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP)2D · PristineMonometallic conductive 2D M-HHTP framework with hexagonal rod morphology and XRD peaks matching the M-HHTP family.12027 (p001) · Abstract
Ni-HHTP2024 · Successful In Situ Growth of Conductive MOFs on 2D Cobalt-Based Compounds and Their Electrochemical PerformanceM-HHTP, M = Ni; HHTP ligandNi2+ nodes · HHTP = 2,3,6,7,10,11-hexahydroxytriphenylene2D · PristineConductive HHTP framework; Ni-HHTP shows nanorod clusters and 1D channels along [001].article p. 10324 · Abstract
Ni-HHTP2024 · A novel pencil graphite electrode modified with an iron-based conductive metal-organic framework exhibited good ability in simultaneous sensing bisphenol A and bisphenol SNi-HHTP; exact stoichiometry not reportedNi · HHTPunknown · PristineMetal-HHTP control MOF used in sensing comparison.2,7 · 2.2.1; 3.3 · Fig. 3F
Ni-HHTP conductive metal-organic framework2024 · Triggering Anodic Luminol Electrochemiluminescence through Electrostatic Interactions: An Innovative Approach Utilizing Conductive Metal-Organic Framework Co-HHTPNi-HHTP; HHTP = 2,3,6,7,10,11-hexahydroxytriphenyleneNi nodes from Ni(OAc)2 precursor coordinated to HHTP. · 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP)2D · PristinePrepared by the same M-HHTP hydrothermal route; used as structurally similar comparator to Co-HHTP.3 · Materials and Methods
Ni-HHTP nickel hexahydroxytriphenylene conductive MOF2024 · Electrosynthesis of a Nickel-Based Conductive Metal-Organic Framework with Controlled Morphology for Enhanced CapacitanceNi-HHTP; HHTP = 2,3,6,7,10,11-hexahydroxytriphenyleneNi nodes, supplied either by Ni(OAc)2 in solvothermal synthesis or by anodic dissolution of nickel foam in electrosynthesis. · 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP).2D · PristineTwo-dimensional electrically conductive metal-organic framework; electrosynthesised flower and disc morphologies match solvothermal bulk Ni-HHTP by PXRD, FTIR, XPS and EDS.50 · Introduction / Results · Figure 1
Ni-HHTP@Co(OH)22024 · Successful In Situ Growth of Conductive MOFs on 2D Cobalt-Based Compounds and Their Electrochemical PerformanceNi-HHTP@Co(OH)2 compositeNi2+ HHTP framework grown on Co(OH)2 · HHTP = 2,3,6,7,10,11-hexahydroxytriphenylene2D · CompositeIn situ grown conductive M-HHTP nanoarrays/nanorods on a 2D cobalt-based compound substrate.article p. 10326 · Results and Discussion · Figure 1
Ni-HHTP@Co(OH)2//AC asymmetric supercapacitor2024 · Successful In Situ Growth of Conductive MOFs on 2D Cobalt-Based Compounds and Their Electrochemical PerformanceNi-HHTP@Co(OH)2 positive electrode // activated carbon negative electrodeNi-HHTP@Co(OH)2 and AC electrodes · HHTP = 2,3,6,7,10,11-hexahydroxytriphenyleneunknown · CompositeAqueous asymmetric supercapacitor assembled in 3 M KOH.article p. 10331 · Results and Discussion · Figure 6d-h
Ni-HHTP@Co3O42024 · Successful In Situ Growth of Conductive MOFs on 2D Cobalt-Based Compounds and Their Electrochemical PerformanceNi-HHTP@Co3O4 compositeNi2+ HHTP framework grown on Co3O4 · HHTP = 2,3,6,7,10,11-hexahydroxytriphenylene2D · CompositeIn situ grown conductive M-HHTP nanoarrays/nanorods on a 2D cobalt-based compound substrate.article p. 10326 · Results and Discussion · Figure 1
Ni-HHTP@CoP2024 · Successful In Situ Growth of Conductive MOFs on 2D Cobalt-Based Compounds and Their Electrochemical PerformanceNi-HHTP@CoP compositeNi2+ HHTP framework grown on CoP · HHTP = 2,3,6,7,10,11-hexahydroxytriphenylene2D · CompositeIn situ grown conductive M-HHTP nanoarrays/nanorods on a 2D cobalt-based compound substrate.article p. 10326 · Results and Discussion · Figure 1
Ni-HHTP@CoP//AC asymmetric supercapacitor2024 · Successful In Situ Growth of Conductive MOFs on 2D Cobalt-Based Compounds and Their Electrochemical PerformanceNi-HHTP@CoP positive electrode // activated carbon negative electrodeNi-HHTP@CoP and AC electrodes · HHTP = 2,3,6,7,10,11-hexahydroxytriphenyleneunknown · CompositeAqueous asymmetric supercapacitor used for cycling comparison.article p. 10332 · Results and Discussion · Figure S25
Ni3(HHTP)22024 · High-Performance Ni3(HHTP)2 Film-Based Flexible Field-Effect Transistor Gas SensorsNi3(HHTP)2Nickel nodes; XPS indicates Ni is present as Ni2+ coordinated with the HHTP ligand. · HHTP, hexahydroxytriphenylene.2D · PristineConductive metal-organic framework with characteristic XRD peaks assigned to (100), (200), (210), (220), (221), and (004) planes; hexagonal crystal system inferred from 1.75 nm (100) lattice spacing.p001 · Abstract
Ni3(HHTP)22024 · A highly sensitive AgNPs/Ni3(HHTP)2 SERS substrate for the detection of food additives and pesticide residuesNi3(HHTP)2Ni2+ from nickel acetate · 2,3,6,7,10,11-triphenylenehexol (HHTP)2D · PristineTwo-dimensional pi-MOF; XRD peaks assigned to (100), (200), (210), and (001) planes.2 · Introduction
Ni3(HHTP)2 DFT model2024 · High-Performance Ni3(HHTP)2 Film-Based Flexible Field-Effect Transistor Gas SensorsNi3(HHTP)2Ni sites in the simulated framework. · HHTP framework model with OH and benzene adsorption sites.2D · Model SystemComputational model used to compare NO2 adsorption at Ni-, OH-, and benzene-sites.p008 · Results and Discussion · Figure 8
Ni3HHTP22024 · Humidity-Mediated Dual Ionic-Electronic Conductivity Enables High Sensitivity in MOF ChemiresistorsNi3(HHTP)2Ni nodes in a triphenylene-based 2D conductive MOF · HHTP2D · PristineTriphenylene-based cMOF control; PXRD and SEM shown in SI.p002 / article p.20214 · Results and Discussion · Figures S4 and S5
NiCAT2024 · In-situ growth of electrically conductive MOFs in wood cellulose scaffold for flexible, robust and hydrophobic membranes with improved electrochemical performanceNi-HHTP catecholate frameworkNi(II) · 2,3,6,7,10,11-hexahydroxytriphenylene hydrate (HHTP)2D · Pristine2D hexagonal nickel catecholate layers packed along the c-axis in an ABAB arrangement, with 1D channels along the c-axis.p005 / journal page 5 · 3.1 Preparation of EC-MOF@TOW membrane · Fig. 2d
NiCAT@TOW composite membrane2024 · In-situ growth of electrically conductive MOFs in wood cellulose scaffold for flexible, robust and hydrophobic membranes with improved electrochemical performanceNiCAT on TEMPO-oxidised wood cellulose scaffoldNi(II) in NiCAT; Ni(II) bridge sites at the TOW interface · HHTP in NiCAT; carboxylated cellulose in TOW scaffold2D · CompositeComposite membrane containing continuous NiCAT nanolayers/nanowires grown on porous TEMPO-oxidised balsa wood scaffold.p004 / journal page 4 · 3.1 Preparation of EC-MOF@TOW membrane
Ni-CAT conductive nickel catecholate MOF2023 · Microwave discharge for rapid introduction of bimetallic-synergistic configuration to conductive catecholate toward long-term supercapacitorNi-CAT; nickel 2,3,6,7,10,11-hexahydroxy triphenyl catecholate frameworkNi ions in a conductive catecholate MOF lattice. · 2,3,6,7,10,11-hexahydroxy triphenyl (HHTP).2D · PristineParent conductive Ni-CAT phase supported on carbon cloth; XRD peaks used as pristine reference and HRTEM lattice spacing for (100) is reported as 1.77 nm.2 · 2.2. Synthesis of Ni-CAT
Ni-MOF/CPE modified carbon paste electrode2023 · Controllable Construction of Two-Dimensional Conductive M3(HHTP)2 Nanorods for Electrochemical Sensing of Malachite Green in FishNi3(HHTP)2 + graphite powder + paraffin oilNi3(HHTP)2 nanorod component. · HHTP in the Ni3(HHTP)2 component.unknown · CompositeComposite carbon-paste comparison electrode containing 2 wt% Ni3(HHTP)2 nanorods.main p.3, article p.22918 · Preparation of the M3(HHTP)2 Nanorod Modified Electrode
Ni-MOF; Ni3(HHTP)22023 · Strategies to enhance electrochemical performance of isoreticular 2d conjugated metal correlated organic frameworks via transition metals intercalation for battery-supercapacitor hybridsNi3(HHTP)2Ni ions; text states nickel only exhibits +2 oxidation state · HHTP (2,3,6,7,10,11-hexahydroxytriphenylene)2D · Pristine2D conjugated c-MOF with hexagonal conjugated framework; described as eclipsed relative to Cu analogue.2 · Introduction
Ni3(HHTP)2 conductive MOF2023 · Elucidating d-π conjugated two-dimensional 2,3,6,7,10,11-hexahydroxytriphenylene based conductive metal-organic framework for hybrid supercapacitorsNi3(HHTP)2Ni2+ ions coordinated to catecholate oxygen atoms · 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP)2D · Pristine2D hexagonal lattice with d-pi conjugation; PXRD peaks assigned to (100), (200) and (220)1-2 · Abstract; Introduction · Figure 1
Ni3(HHTP)2 conductive MOF nanorods2023 · Controlled synthesis of Cu-/Ni-based 1D c-MOFs and their application in near-linear temperature sensingNi3(HHTP)2Ni nodes; Ni present as Ni2+ by Ni 2p XPS. · 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP)2D · PristineConjugated hexagonal M3(HHTP)2 lattice stacked along the c axis; synthesised as 1D nanorod-like MOF powder.main p.3 · 3.1 Synthesis and characterization · Fig. 1; Fig. 4; Fig. 5
Ni3(HHTP)2 nanorods2023 · Controllable Construction of Two-Dimensional Conductive M3(HHTP)2 Nanorods for Electrochemical Sensing of Malachite Green in FishNi3(HHTP)2Ni centres from nickel(II) acetate tetrahydrate. · HHTP2D · PristineNanorod-like p-d conjugated 2D conductive MOF.main p.3, article p.22918 · Preparation of M3(HHTP)2 Nanorod Materials · Figure 1B,B1
Ni3(HHTP)2//AC asymmetric hybrid supercapacitor2023 · Elucidating d-π conjugated two-dimensional 2,3,6,7,10,11-hexahydroxytriphenylene based conductive metal-organic framework for hybrid supercapacitorsNi3(HHTP)2//ACNi2+ in Ni3(HHTP)2 positive electrode · HHTP in Ni3(HHTP)2 positive electrode2D · CompositeAsymmetric two-electrode device combining Ni3(HHTP)2 positive electrode and activated carbon negative electrode5 · 3.3. Electrochemical evaluation of asymmetric device · Figure 5
Ni-CAT2022 · Conductive Metal-Organic Frameworks Bearing M−O4 Active Sites as Highly Active Biomass Valorization ElectrocatalystsNi metal-catecholate framework with Ni-O4 active sitesNi2+/Ni3+ centres coordinated by catecholate oxygens · 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP)2D · PristineConductive metal-catecholate framework consisting of 2D layers; XRD peaks at 9.2 and 13.9 degrees assigned to (200) and (3-11) planes and matching calculated pattern.2 · Introduction / Results and Discussion · Figures 1 and 2
Ni-CAT; Ni-catecholate2022 · Preparation of Bimetallic Conductive Metal-organic Framework Material Ni/Co-CAT for Electrocatalytic Oxygen Reduction 双金属导电金属有机框架材料 Ni/Co-CAT 的制备及其氧还原催化性能研究Not specifiedNi · 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP)2D · PristineConductive metal-catecholate MOF; Ni atoms coordinate with adjacent HHTP and water ligands, forming octahedral coordination units; figure references c-axis structure.748-750 · Abstract; 2.1 · Figure 1c
Ni-HHTP2022 · Iron-Based 2D Conductive Metal-Organic Framework Nanostructure with Enhanced PseudocapacitanceNot specifiedNi nodes in reported 2D M-HHTP honeycomb analogue · HHTP2D · Pristine2D honeycomb structure confirmed by PXRD for comparison with Fe-HHTP.main p.5 · Results and Discussion · Figure S12
Ni-HHTP analogous conductive MOF2022 · Large-Area Synthesis of Ultrathin, Flexible, and Transparent Conductive Metal–Organic Framework Thin Films via a Microfluidic-Based Solution Shearing ProcessNi-HHTP, analogous c-MOF to Ni3(HITP)2Ni nodes. · HHTP linker with hydroxyl groups instead of amine groups.2D · PristineAnalogous triphenylene-core conductive MOF used for ex situ H2S mechanism comparison.40 · Figure S26 Discussion · Figure S26
Ni-HHTP metal-organic framework2022 · Engineering the modulation of the active sites and pores of pristine metal-organic frameworks for high-performance sodium-ion storageNi-HHTP; HHTP = 2,3,6,7,10,11-hexahydroxytriphenyleneNi ions, reported as Ni2+ redox-active centres · 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP)2D · PristineConductive nickel-catecholate framework retaining characteristic ab-plane diffraction peaks at 4.7, 9.3 and 12.3 degrees after 250 C treatment; nanorod morphology forms a cross-linked network.396 · Abstract
Ni-HHTP monometallic metal-organic framework2022 · Conductive NiCo bimetal-organic framework nanorods with conductivity-enhanced electrochemiluminescence for constructing biosensing platformNot specifiedNi nodes · HHTP = 2,3,6,7,10,11-hexahydroxytriphenyleneunknown · PristineReported as isostructural monometallic control to NiCo-HHTP.5 · S-1.3 Synthesis of Ni-HHTP
Ni3(HHTP)22022 · Epitaxial Self-Assembly of Interfaces of 2D Metal-Organic Frameworks for Electroanalytical Detection of NeurotransmittersNot specified['Ni']unknown · Unknown1 · Abstract
Ni3(HHTP)2 two-dimensional conductive metal-organic framework2022 · Dense Conductive Metal-Organic Frameworks as Robust Electrocatalysts for BiosensingNi3(HHTP)2Square-planar coordinated Ni2+ nodes. · 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP).2D · PristineExpected 2D hexagonal conductive MOF; PXRD matched reported/simulated patterns and HRTEM showed ordered lattice fringes and hexagonal meshes.main p.2, article p.17178 · Introduction/Experimental overview · Figure 1
Ni3HHTP22022 · NiPd mediated by conductive metal organic frameworks with facilitated electron transfer for assaying of H2O2 released from living cellsNi3HHTP2Ni(II) · 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP)unknown · PristineConductive MOF with pXRD peaks at 2theta = 4.7, 9.2, 13.9 and 26.8 deg assigned to (100), (200), (3-10) and (004) planes.3 · 3.1. Characterization of hybrid nanomaterials · Fig. 1A-C
Ni3HHTP2 conductive MOF2022 · Wet-Adhesive On-Skin Sensors Based on Metal–Organic Frameworks for Wireless Monitoring of Metabolites in SweatNi3HHTP2Nickel nodes / Ni sites in a triphenylene-based conductive MOF. · HHTP = 2,3,6,7,10,11-hexahydroxytriphenylene.2D · PristineLayered conductive MOF; PXRD peaks at 2theta = 4.7, 9.6, and 12.6 deg indexed to (100), (200), and (210), respectively; randomly oriented nanorods observed on the working electrode.2-3 · Results and Discussions · Figure 1; Figure S8
Ni3HHTP2/Au/BNC wearable layered electrode sensor2022 · Wet-Adhesive On-Skin Sensors Based on Metal–Organic Frameworks for Wireless Monitoring of Metabolites in SweatNi3HHTP2 film on Cr/Au patterned bacterial nanocellulose with Ag/AgCl reference and Ecoflex insulationNi nodes in Ni3HHTP2; Au current collector; Ag/AgCl pseudo-reference electrode. · HHTP linker in Ni3HHTP2; bacterial nanocellulose substrate and Nafion binder.2D · CompositeComposite layered device with two Ni3HHTP2-modified working electrodes on a 15 um BNC substrate; Cr/Au electrode layer and Ecoflex insulation.2 · Results and Discussions · Figure 1a-b
NiPd@Ni3HHTP22022 · NiPd mediated by conductive metal organic frameworks with facilitated electron transfer for assaying of H2O2 released from living cellsNiPd@Ni3HHTP2Ni(II) framework nodes plus NiPd nanoparticles · HHTP in Ni3HHTP2 frameworkunknown · CompositeHybrid nanomaterial retaining Ni3HHTP2 structure with Ni-Pd peaks at 2theta = 40.3 and 46.9 deg.3 · 3.1. Characterization of hybrid nanomaterials · Fig. 1G-H; Fig. S2-S3
core-shell Ni-CAT NWAs/CNF hybrid electrode2021 · Soft Electrochemical Actuators with a Two-Dimensional Conductive Metal-Organic Framework Nanowire ArrayNi-CAT nanowire arrays grown on carbon nanofibersNi(II) catecholate framework on CNF · HHTP-derived catecholate framework on CNF2D · CompositeVertically oriented Ni-CAT nanowire arrays radially grown on CNF, forming a core-shell hierarchical porous electrode.p002 / article p.4018 · Synthesis and Characterization of Core-Shell Ni-CAT NWAs/CNF · Figure 1
Ni-CAT conductive metal-organic framework2021 · Soft Electrochemical Actuators with a Two-Dimensional Conductive Metal-Organic Framework Nanowire ArrayNi-CAT; nickel 2,3,6,7,10,11-hexahydroxytriphenylene catecholate frameworkSquare-planar coordinated Ni(II) · 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP)2D · Pristine2D honeycomb-layered pi-d conjugated framework with slipped-parallel AB stacking and 1D open cylindrical channels.p002 / article p.4018 · Synthesis and Characterization of Core-Shell Ni-CAT NWAs/CNF · Figure 1g
Ni-CAT NWAs/CNF based ionic IPMC actuator2021 · Soft Electrochemical Actuators with a Two-Dimensional Conductive Metal-Organic Framework Nanowire ArrayNi-CAT NWAs/CNF electrodes + EMImTFSI/PVDF gel electrolyteNi(II) catecholate framework in electrode layers · HHTP-derived catecholate framework; PVDF/EMImTFSI electrolyte matrix2D · CompositeSymmetrical bimorph actuator with a solid ionic-liquid gel electrolyte sandwiched between two Ni-CAT NWAs/CNF electrodes.p004 / article p.4020 · Construction and Performance Evaluation · Figure 4a
Ni-CAT-1 / Ni3(HHTP)2 two-dimensional pi-conjugated metal-organic framework2021 · Large Single Crystals of Two-Dimensional π-Conjugated Metal-Organic Frameworks via Biphasic Solution-Solid GrowthNi3(HHTP)2; Ni:C ratio reported as 1:12 for crystalsNi catecholate nodes / Ni(OAc)2-derived nickel ions coordinated to HHTP catecholates · 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP)2D · PristineLayered 2D pi-conjugated metal-catecholate MOF with hexagonal in-plane lattice; TEM/FFT lattice parameter 2.1 nm; stacking sequence left caveated by SI.p001 · Abstract
Ni-HHTP2021 · Conductive metal-organic frameworks promoting polysulfides transformation in lithium-sulfur batteriesNi-catecholate framework based on HHTP; commonly Ni3(HHTP)2 familyNi(II) nodes · 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP)2D · PristineConductive nickel-catecholate MOF with two distinct types of 2D layers stacked by pi-pi interactions and hydrogen bonding to form parallel 1D open channels.p003 / article p338 · Results and discussion · Fig. 2a; Fig. S2 referenced
Ni-HHTP@CP2021 · Conductive metal-organic frameworks promoting polysulfides transformation in lithium-sulfur batteriesNi-HHTP grown on carbon paperNi(II) nodes in Ni-HHTP · HHTP linker in Ni-HHTP2D · CompositeComposite electrode in which bush-like Ni-HHTP coats interconnected carbon fibres; XRD peaks of Ni-HHTP are retained on CP.p003 / article p338 · Results and discussion · Figs. 2b-d and 3a
Ni3(HHTP)22021 · Two-Dimensional Conductive Metal-Organic Frameworks as Highly Efficient Electrocatalysts for Lithium-Sulfur BatteriesNi3(HHTP)2Ni transition-metal nodes coordinated by N/O/S donor atoms in the 2D framework · HHTP (2,3,6,7,10,11-hexahydroxytriphenylene; C18H6O6)2D · Model SystemO-coordinated TM3(HHTP)2 kagome 2D MOF; periodic monolayer slab model with kagome sublattice where applicable.PDF p2 / article p.61206 · Introduction
Conductive Ni-MOF / Ni3(HHTP)22020 · High-performance non-enzymatic glucose detection: Using a conductive Ni-MOF as an electrocatalystNi3(HHTP)2Ni2+ nodes in square-planar coordination environments with ortho-disubstituted O donor atoms from HHTP. · 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP)3D · Pristine3D pi-conjugated conductive MOF; honeycomb lattices with long-range in-plane order and a 002 peak assigned to pi-pi layered stacking.main p.2, article p.5411 · Communication · Fig. 1a-b
Ni-CAT2020 · Trimetallic conductive metal-organic frameworks as precatalysts for the oxygen evolution reaction with enhanced activityNi3(HHTP)2 / M-CAT familyNi2+ nodes · HHTP2D · PristineConductive M-CAT isostructural with Co-CAT.2 · Synthesis of CoxNi1-x-CATs
Ni-HHTP conductive MOF2020 · Conductive MOFs as bifunctional oxygen electrocatalysts for all-solid-state Zn-air batteries[Ni6(HHTP)3(H2O)x]nNi2+ · HHTP = 2,3,6,7,10,11-hexhydroxyltriphenylene2D · PristineTrigonal P-3c1, 2D ABAB-stacked conductive framework with nanoscale channels.1-2 · main text · Fig. 1
Ni3HHTP2 MOF nanorods2020 · ChemFET Sensor: nanorods of nickel-substituted Metal–Organic framework for detection of SO2Ni3HHTP2nickel(II) · 2,3,6,7,10,11-hexahydroxytriphenylene hydrate (HHTP)2D · PristineSemiconducting HHTP-based nickel MOF; GIXRD matched reported Ni3HHTP2 data with (100) and (200) reflections.1 · Abstract
Ru-doped Ni-HHTP conductive MOF, high Ru2020 · Conductive MOFs as bifunctional oxygen electrocatalysts for all-solid-state Zn-air batteries[Ni5.4Ru0.6(HHTP)3(H2O)x]nNi2+/Ru3+ · HHTP2D · PristineRu-doped analogue of the Ni-HHTP conductive framework; high Ru loading was reported to damage crystallinity relative to lower Ru contents.3 · Synthesis method of conductive MOFs · Table S1
Ru-doped Ni-HHTP conductive MOF, intermediate Ru2020 · Conductive MOFs as bifunctional oxygen electrocatalysts for all-solid-state Zn-air batteries[Ni5.82Ru0.18(HHTP)3(H2O)x]nNi2+/Ru3+ · HHTP2D · PristineRu-doped analogue of the Ni-HHTP ABAB-stacked conductive framework.3 · Synthesis method of conductive MOFs · Table S1
Ru-doped Ni-HHTP conductive MOF, low Ru2020 · Conductive MOFs as bifunctional oxygen electrocatalysts for all-solid-state Zn-air batteries[Ni5.94Ru0.06(HHTP)3(H2O)x]nNi2+/Ru3+ · HHTP2D · PristineRu-doped analogue of the Ni-HHTP ABAB-stacked conductive framework.3 · Synthesis method of conductive MOFs · Table S1
Ru-doped Ni-HHTP conductive MOF, optimised composition2020 · Conductive MOFs as bifunctional oxygen electrocatalysts for all-solid-state Zn-air batteries[Ni5.7Ru0.3(HHTP)3(H2O)x]nNi2+/Ru3+ · HHTP2D · PristineTrigonal P-3c1-type ABAB-stacked framework similar to [Ni6(HHTP)3(H2O)x]n; A layers are extended [(NiRu)3(HHTP)2(H2O)x]n hexagons and B layers are 0D [(NiRu)3(HHTP)(H2O)x] fragments.2 · main text · Fig. 1, Fig. 2
1D conductive Ni-CAT nanorods2019 · Construction of 1D conductive Ni-MOF nanorods with fast Li+ kinetic diffusion and stable high-rate capacities as an anode for lithium ion batteriesNi-CAT; Ni(II)-HHTP conductive MOF, exact empirical formula not reportedNi(II) ions coordinated by catecholate oxygens · 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP)2D · PristineLayered M-CAT framework: extended 2D hexagonal honeycomb sheets with c-axis stacking; isolated as one-dimensional nanorods.1 · Introduction/Results
CNF-Ni-HHTP direct-mixed paper2019 · Cellulose Nanofiber @ Conductive Metal-Organic Frameworks for High-Performance Flexible SupercapacitorsCNF plus Ni-HHTP powder, 85:15 CNF:c-MOF by weightNi(II) in Ni-HHTP particles · HHTP2D · CompositePhysical mixture control paper made by direct mixing c-MOF powders and CNFs rather than interfacial nanolayer growth.rendered page 4 / article p.9581 · Results and Discussion · Figure 2b
CNF@Ni-HHTP hybrid nanofibers / nanopaper2019 · Cellulose Nanofiber @ Conductive Metal-Organic Frameworks for High-Performance Flexible SupercapacitorsCNF@Ni-HHTP; c-MOF content about 15 wt % in nanopaper by TGANi(II) in Ni-HHTP nanolayers · HHTP2D · CompositeComposite nanofibrillar material in which continuous conductive Ni-HHTP nanolayers are grown on cellulose nanofibers and assembled into freestanding nanopaper.rendered page 3 / article p.9580 · Results and Discussion · Figure 1a,b
Ni-CAT-12019 · Oriented Thin Films of Electroactive Triphenylene Catecholate-Based Two-Dimensional MetalOrganic FrameworksIdealised Ni3(HHTP)2 / Ni3(C18H6O6)2; exact empirical formula not reported in this paperSquare-planar Ni(II) catecholate nodes within extended 2D sheets. · 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP) tricatecholate linker.2D · PristineLayered triphenylene metal-catecholate M-CAT-1 framework with microporous channels and stacked 2D sheets; c-axis preferentially normal to oriented films.p001-p002 · Abstract and Introduction
Ni-HHTP conductive metal-organic framework2019 · Cellulose Nanofiber @ Conductive Metal-Organic Frameworks for High-Performance Flexible SupercapacitorsNi-HHTP; exact empirical formula not reported in this paperNi(II) · HHTP (2,3,6,7,10,11-hexahydroxytriphenylene)2D · PristineConductive MOF with typical low-angle (100)/(200) XRD peaks near 4.7 and 9.5 degrees and a broader (001) reflection near 27.3 degrees in powder form.rendered page 3 / article p.9580 · Results and Discussion · Figure 1b
Ni3(HHTP)2 trigonal MOF2018 · Modular O2 electroreduction activity in triphenylene-based metal-organic frameworksNi3(HHTP)2Ni-containing honeycomb sheets alternating with trinuclear M3(HHTP)(H2O)12 clusters. · HHTP / hexahydroxytriphenylene.2D · PristineTrigonal crystal system with alternating honeycomb layers and rotated trinuclear clusters.1 · Results and discussion · Fig. 1
Ni3HHTP2 MOF2018 · Conductive Metal-Organic Frameworks as Ion-to-Electron Transducers in Potentiometric SensorsNi3HHTP2Ni · HHTP2D · PristineLayered conductive metal-catecholate MOF; PXRD consistent with slipped parallel packing; XPS shows Ni2+ only.3 · Characterization of M3HHTP2 MOFs · Figures S2-S5
Ni3HHTP22017 · Drawing sensors with ball-milled blends of metal-organic frameworks and graphiteNi3(HHTP)2Ni acetate-derived Ni nodes · 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP)2D · Pristineisoreticular 2D M3HHTP2 metal-catecholate framework3 of 17 · Introduction / Results 3.1 · Figure 1A
Ni3HHTP2/graphite blend2017 · Drawing sensors with ball-milled blends of metal-organic frameworks and graphiteNi3(HHTP)2 + graphite, 9:1 MOF:graphite by massNi nodes in MOF component · HHTP in MOF component; graphite conductive additive2D · Compositeball-milled MOF/graphite composite retaining MOF component; graphite (002) peak retained6-7 of 17 · Results 3.2 · Figure 2 and Figure S8