cMOF Evidence Base
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Ni₃(HITP)₂ / Ni–HITP

This family merges chemical shorthand and formula variants only after verification against source articles. Per-paper composition and phase details remain separate below.

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60primary papers
94material records
295linked samples
608linked measurements
2,254linked results
2015–2026publication span

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  • Several formulas or formula descriptions are reported
  • More than one known dimensionality is reported
  • Pristine, composite, derived or model contexts are mixed
  • Model-system or unresolved records are present

Evidence coverage

Paper counts are material-linked through samples and measurements; technique groups are not value rankings.

Diffraction Structure39 papers52 measurements · 158 resultsMicroscopy Morphology39 papers82 measurements · 216 resultsElectrical Transport35 papers73 measurements · 179 resultsSpectroscopy31 papers75 measurements · 288 resultsElectrochemistry Application26 papers152 measurements · 614 resultsComputational Modelling24 papers56 measurements · 435 resultsPorosity23 papers26 measurements · 68 resultsOther20 papers34 measurements · 77 resultsSensing Application11 papers45 measurements · 164 resultsThermoelectric5 papers13 measurements · 55 results

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Primary papers

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60 papers

Primary study2024

Solid-State Electrochemical Carbon Dioxide Capture by Conductive Metal-Organic Framework Incorporating Nickel Bis(diimine) Units

Liu J., Yang M., Zhou X. et al. · Journal of the American Chemical Society · 2024

Reported here: Ni3(HITP)2 conductive metal-organic framework · Ni3(HITP)2 reduced/adduct DFT model systems

Computational Modelling · 18Diffraction Structure · 1Electrical Transport · 1Electrochemistry Application · 25Microscopy Morphology · 1Other · 2Porosity · 2Spectroscopy · 7
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Primary study2022

Adjustable Synthesis of Ni-Based Metal-Organic Framework Membranes and Their Field-Effect Transistor Sensors for Mercury Detection

Shen S., Tan P., Tang Y. et al. · ACS Applied Electronic Materials · 2022

Reported here: Ni3(HITP)2 membrane · Ni3(HITP)2-DNA FET sensor control · Ni3(HITP)2-GA FET sensor control · Ni3(HITP)2-GA-DNA FET sensor

Diffraction Structure · 8Electrical Transport · 11Microscopy Morphology · 7Other · 3Sensing Application · 16Spectroscopy · 6
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Primary study2022

Mutually Noninterfering Flexible Pressure-Temperature Dual-Modal Sensors Based on Conductive Metal-Organic Framework for Electronic Skin

Li Y., Wang R., Wang G.-E. et al. · ACS Nano · 2022

Reported here: Ni3(HiTP)2 computational model · Ni3(HiTP)2 conductive metal-organic framework · Ni3(HiTP)2-on-microstructured mixed cellulose composite film · Ni3(HiTP)2-on-polypropylene composite film

Computational Modelling · 15Diffraction Structure · 1Electrical Transport · 8Microscopy Morphology · 14Other · 3Sensing Application · 38Thermoelectric · 11
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Primary study2021

Solar-driven ionic power generation: Via a film of nanocellulose @ conductive metal-organic framework

Zhou S., Qiu Z., Stromme M. et al. · Energy and Environmental Science · 2021

Reported here: Cladophora cellulose nanofibre @ Ni-HITP conductive MOF film (CCM) · Direct-blended cellulose/Ni-HITP nanopaper · Ni-HITP conductive metal-organic framework · Wood nanocellulose @ Ni-HITP film

Computational Modelling · 2Diffraction Structure · 9Electrical Transport · 5Electrochemistry Application · 16Microscopy Morphology · 5Porosity · 4Thermoelectric · 13
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Primary study2018

Selective reduction of CO2 by conductive MOF nanosheets as an efficient co-catalyst under visible light illumination

Zhu W., Zhang C., Li Q. et al. · Applied Catalysis B: Environmental · 2018

Reported here: Ni3(HITP)2 conductive two-dimensional metal-organic framework · Ni3(HITP)2/[Ru(bpy)3]2+ hybrid photocatalytic CO2-reduction system

Diffraction Structure · 1Electrical Transport · 3Electrochemistry Application · 27Microscopy Morphology · 2Other · 6Porosity · 1Spectroscopy · 19
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Per-paper identity records

Raw names, formulas and structural assignments remain separate; no consensus value is inferred.

Show 94 material identity records
Paper and reported nameFormula and componentsStructure contextSource
Ni-HITP2026 · In-situ growth of high-crystallinity M3(hexaaminotriphenylene)2 (M = Co, Ni) thin film for field-effect transistor-based glucose biosensorNi3(HITP)2Ni2+ centres · HITP2D · PristineMonometallic Ni-HITP conductive MOF control with characteristic XRD peaks at 4.8, 9.2 and 27.1 deg.2 · Results · Fig. 1d
Ni-HITP2025 · Micro-sized conductive metal–organic framework nanosheets for the electrochemical hydrogen evolution reaction in acidic mediaNi-HITP (nickel 2,3,6,7,10,11-hexaaminotriphenylene framework)Ni · 2,3,6,7,10,11-hexaaminotriphenylene (HITP)2D · PristineConductive HITP-based MOF; crystalline Cu/Co/Ni-HITP show XRD peaks assigned to (100), (200), (210), (220) in the ab plane and a c-axis peak at 27.8 degrees.p002 / 42274 · Results and discussion · Fig. S1
Ni3(2,3,6,7,10,11-hexaiminotriphenylene)22025 · Overscreening-Driven Modulation of Ion Adsorption and Desorption in Conductive MOF Electrodes by Charging RatesNi3(HITP)2Ni · 2,3,6,7,10,11-hexaiminotriphenylene (HITP)2D · PristineConductive metal-organic framework electrode with monodispersed nanopores; atomistic electrode structure used for MD was obtained from experimental measurements reported in prior work.2582 · Introduction
Ni3(HITP)22025 · A conductive MOF with bimetallic spontaneously recycled systems as a signal enhancer for the ultrasensitive detection of T-2 toxin using an electrochemical aptasensorNi3(HITP)2Ni ions · HITP = 2,3,6,7,10,11-hexaiminotriphenylene2D · PristineConductive triphenylene-based MOF used as the pristine Ni-only control in the NixCo3-x(HITP)2 series.2 · Introduction
Ni3(HITP)22025 · Catalysis-Assisted Synthesis of Two-Dimensional Conductive Metal–Organic Framework Films with Controllable OrientationNi3(HITP)2Ni ions from Ni(OAc)2 · HITP derived from HATP.6HCl2D · PristineDiamine-based conductive 2D MOF; face-on orientation verified by out-of-plane (002) peak; edge-on analogue in SI.17061 · Results and Discussion · Figure 4
Ni3(HITP)22025 · Highly Porous, Electrically Conductive Two-Dimensional Nickel–Hexaaminodehydrobenzoannulene FrameworksNi3(HITP)2Ni2+ coordinated by o-phenylenediamine/hexaiminotriphenylene nodes · HATP/HITP ligand2D · PristineTriphenylene-based 2D conductive MOF; eclipsed/slipped-AA stacked hexagonal framework, P6/mmm AA refinement.31942 · Preparation and Structure of MOFs · Scheme 1b
Ni3(HITP)22025 · Conductive metal-organic framework synthesis from metal nanoparticle precursorsNi3(HITP)2Ni nodes; Ni 2p3/2 binding energies above 855.5 eV indicate oxidised Ni and no metallic Ni within the top 5 nm/6 nm sampling depth reported. · 2,3,6,7,10,11-hexaiminotriphenylene (HITP), formed from HATP.6HCl precursor2D · Pristine2D hexagonal sheets with slipped parallel stacking; TEM interlayer spacing measured as 3.3 A.p003 · Introduction · Figure 1
Ni3(HITP)22025 · Enhancing pancreatic cancer ablation efficiency: bipolar IRE with conductive MOFNi3(HITP)2Ni · HITP2D · PristineSheet-like conductive MOF; crystallinity retained after PDA coating according to XRD comparison.2019 · 2.1 Materials and chemicals
Ni3(HITP)2 conductive metal-organic framework2025 · Controlling the Spatiotemporal Self-Organization of Stimuli-Responsive Nanocrystals under Out-of-Equilibrium ConditionsNi3(HITP)2Ni-bisdiimine / Ni2+ coordination nodes · HITP = 2,3,6,7,10,11-hexaiminotriphenylene, generated from HATP.6HCl2D · PristineLayered 2D conductive MOF; simulated ABAB/slipped-parallel stacking; PXRD compared with simulated/bulk Ni3(HITP)2 patterns.1585 · Experimental Design · Figure 1a
Ni3(HITP)2 slipped-AA model2025 · Highly Porous, Electrically Conductive Two-Dimensional Nickel–Hexaaminodehydrobenzoannulene FrameworksNi3(HITP)2Ni in DFT+U model · HITP ligand2D · Model SystemLowest-energy slipped-AA model with 0.175 nm interlayer shift used for band calculations.S5 · S1-2 Computation
Ni3(HITP)2@PDA2025 · Enhancing pancreatic cancer ablation efficiency: bipolar IRE with conductive MOFNi3(HITP)2@PDANi · HITP plus polydopamine coating2D · CompositePDA-coated Ni3(HITP)2 nanoparticles; SEM/TEM showed conformal PDA coating and XRD retained crystallinity.2022-2023 · 3.3 Characterization of conductive MOF · Fig. 2
Ge@Ni3(HITP)2 anode2024 · Enhancement of the performance of Ge–air batteries under high temperatures using conductive MOF-modified Ge anodesGe@Ni3(HITP)2Ni centres in Ni3(HITP)2 film on Ge wafer · HITP framework film on Ge2D · CompositeComposite anode made by depositing a Ni3(HITP)2 film on a heavily doped p-type Ge(100) wafer.p003 · 2.2 · Figure 1A
Ni3(HITP)22024 · Conductive Ni3(HITP)2 nanofilm with asymmetrical morphology prepared by gas–liquid interface self-assembly for glucose sensingNi3(HITP)2Ni · HITP (2,3,6,7,10,11-hexaiminotriphenylene)2D · Pristine2D graphene-like honeycomb/kagome conductive MOF; XRD peaks assigned to (100), (200), and (002) planes.p001 / 2375 · Abstract and Introduction
Ni3(HITP)22024 · Enhancement of the performance of Ge–air batteries under high temperatures using conductive MOF-modified Ge anodesNi3(HITP)2Ni coordination centres; Ni-N first shell · HITP = 2,3,6,7,10,11-hexaiminotriphenylene; precursor HATP.6HCl2D · Pristine2D honeycomb hexagonal conductive MOF with ordered one-dimensional channel structure and layered stacking.p003 · Introduction
Ni3(HITP)22024 · High-Performance H2S Sensors to Detect SF6 LeakageNi3(HITP)2Ni nodes · HITP2D · Pristine2D layered conductive HITP framework with M-N coordination; used as a monometallic comparison material.3 · 2.1. Sample Preparation and Characterization · Figures 2, S8
Ni3(HITP)2 c-MOF supercapacitor model systems2024 · Organic Solvent Boosts Charge Storage and Charging Dynamics of Conductive MOF SupercapacitorsNi3(HITP)2 electrodes with [Bmim][PF6] or [Bmim][PF6]/ACN electrolyteNi in modelled Ni3(HITP)2 electrodes · HITP-derived framework in modelled Ni3(HITP)2 electrodes2D · Model SystemTwo identical symmetric conductive MOF electrodes, each a stack of 18 conductive MOF layers, separated by electrolyte in constant-potential MD.9 · Experimental Section - Molecular Dynamics Simulations
Ni3(HITP)2 conductive metal-organic framework2024 · Solid-State Electrochemical Carbon Dioxide Capture by Conductive Metal-Organic Framework Incorporating Nickel Bis(diimine) UnitsNi3(2,3,6,7,10,11-hexaiminotriphenylene)2; Ni3(HITP)2Ni(II) centres linked into nickel bis(diimine) / Ni-BDI units. · 2,3,6,7,10,11-hexaiminotriphenylene / HITP from HATP precursor.2D · PristineLayered infinite honeycomb porous network with eclipsed packing model; PXRD consistent with simulated pattern.33094 · Introduction · Figure 1
Ni3(HITP)2 conductive MOF2024 · Organic Solvent Boosts Charge Storage and Charging Dynamics of Conductive MOF SupercapacitorsNi3(2,3,6,7,10,11-hexaiminotriphenylene)2Ni nodes in a conductive metal-organic framework · 2,3,6,7,10,11-hexaiminotriphenylene / HATP-derived hexaaminotriphenylene linker2D · PristineCrystalline conductive MOF with hexagonal pores; PXRD matches simulated and reported Ni3(HITP)2 structure.1 · Introduction
Ni3(HITP)2 conductive MOF film2024 · Electrodeposition of Ni/Cu Bimetallic Conductive Metal–Organic Frameworks Electrocatalysts with Boosted Oxygen Reduction Activity for Zinc–Air BatteriesNi3(HITP)2Ni coordinated to N sites in square-planar Ni-N4 motifs · 2,3,6,7,10,11-hexaiminotriphenylene (HITP)2D · PristineLayered 2D planar conductive framework with vertical pi-pi stacking; XRD peaks assigned to stacked cellular construction.2 · 2.1 Material Design and Structural Characterization · Figure 1a,b
Ni3(HITP)2 reduced/adduct DFT model systems2024 · Solid-State Electrochemical Carbon Dioxide Capture by Conductive Metal-Organic Framework Incorporating Nickel Bis(diimine) UnitsNi3(HITP)2, [Ni3(HITP)2]3-, [Ni3(HITP)2-3CO2]3-Model Ni-BDI units in the Ni3(HITP)2 framework. · HITP framework linker in periodic/modelled structure.2D · Model SystemDFT model used for charges, electrostatic potential and CO2 adduct energetics.S34 · 12.4 Computation Details · Figures S43-S47
Ni3(HITP)2 slab model2024 · Conductive Ni3(HITP)2 nanofilm with asymmetrical morphology prepared by gas–liquid interface self-assembly for glucose sensingNi3(HITP)2Ni · HITP2D · Model SystemPeriodic slab model with saturated Ni, unsaturated defective Ni, and carbon adsorption sites.p003 / 2377 · Computational methods
Ni3(HITP)2 two-dimensional MOF model2024 · Benchmark Investigation of SCC-DFTB against Standard and Hybrid DFT to Model Electronic Properties in Two-Dimensional MOFs for Thermoelectric ApplicationsNi3(HITP)2Ni nodes coordinated by imino nitrogen donors. · HITP = 2,3,6,7,10,11-hexaiminotriphenylene.2D · Model SystemModelled as flat and wavy monolayers plus flat and wavy AA-stacked geometries.main p.2, article p.3977 · Introduction
Ni3(HITP)2, nickel 2,3,6,7,10,11-hexaiminotriphenylene MOF2024 · Direct Electrodeposition of Electrically Conducting Ni3(HITP)2 MOF Nanostructures for Micro-Supercapacitor IntegrationNi3(2,3,6,7,10,11-hexaiminotriphenylene)2; abbreviated Ni3(HITP)2Ni2+ centres coordinated by oxidised HATP/HITP units; text describes diiminobenzosemiquinoate submoieties. · 2,3,6,7,10,11-hexaiminotriphenylene (HATP/HITP; HATP.6HCl precursor).2D · PristineElectrodeposited films assigned by PXRD to simulated and bulk chemically synthesised Ni3(HITP)2 phase; no extra diffraction peaks identified for optimised potentiostatic/pulsed deposits.1 · Abstract
Ni3HITP22024 · Humidity-Mediated Dual Ionic-Electronic Conductivity Enables High Sensitivity in MOF ChemiresistorsNi3(HITP)2Ni nodes in a triphenylene-based 2D conductive MOF · HITP2D · PristineTriphenylene-based cMOF control; PXRD and SEM shown in SI.p002 / article p.20214 · Results and Discussion · Figures S4 and S5
Pt@Ni3(HITP)2 core-shell nanowire network2024 · Direct Electrodeposition of Electrically Conducting Ni3(HITP)2 MOF Nanostructures for Micro-Supercapacitor IntegrationPt core nanowires with Ni3(HITP)2 shellNi2+ centres in Ni3(HITP)2 shell; metallic Pt core scaffold. · HITP/HATP-derived linker in Ni3(HITP)2 shell.unknown · CompositeCore-shell morphology confirmed by SEM/TEM; Ni3(HITP)2 shell assigned by the same electrodeposited MOF characterisation.6 · Results and Discussion · Figure 5A
HITP-Ni-NS2023 · Air/liquid interfacial formation process of conductive metal–organic framework nanosheetsNi3(HITP)2Ni2+ · 2,3,6,7,10,11-hexaiminotriphenylene (HITP), generated from HATP2D · PristineLayered, metrically hexagonal 2D conductive MOF nanosheet with pi-pi stacked sheets; a = b about 21.36 Angstrom and interlayer distance about 3.22 Angstrom.3 (journal p. 771) · Figure 1 caption · Fig. 1
HITP-Ni_subphase2023 · Air/liquid interfacial formation process of conductive metal–organic framework nanosheetsNi3(HITP)2Ni2+ · HITP, generated from dissolved HATP2D · PristineNi3(HITP)2 crystals formed in the aqueous subphase and floating to the air/liquid interface; optical and IR spectra indicate the same HITP-Ni coordination as HITP-Ni-NS.11 (journal p. 779) · 3.2 Discussion on formation process · Fig. 9
Hydrogen-defective Ni3(HITP)2 model systems2023 · Ligand-Mediated Hydrogenic Defects in Two-Dimensional Electrically Conductive Metal-Organic FrameworksNi3(HITP)2Hx, x = vacancy/interstitial modelNickel nodes retained from the Ni3(HITP)2 kagome framework. · HITP linkers with hydrogen vacancy, H+, H-, H* or 2H* interstitial configurations.2D · Model SystemHydrogenic defect models in monolayer and vdW-stacked bulk Ni3(HITP)2; 2H* interstitial model forms Ni3(HITP)2H2.main p.3 / article p.11389 · Results and Discussion · Figure 5
Ni3(HITP)22023 · Two-Dimensional Conjugated Metal-Organic Frameworks with Large Pore Apertures and High Surface Areas for NO2 Selective Chemiresistive SensingNi3(HITP)2Ni coordination sites · HITP ligand, as represented in Figure S322D · PristinePreviously known 2D c-MOF control with smaller pore aperture than HIOTP-Ni; PXRD shown against simulated pattern.p004 · Sensing comparison · Figure S32
Ni3(HITP)22023 · Ruthenium(II) complex-grafted conductive metal-organic frameworks with conductivity- and confinement-enhanced electrochemiluminescence for ultrasensitive biosensing applicationNi3(HITP)2Ni centres in a HITP-based conductive framework · HITP from 2,3,6,7,10,11-hexaiminotriphenylene / HATP.6HCl precursor2D · PristineConductive MOF with simulated Ni3(HITP)2 PXRD match; reported positively charged framework with large channels.p002 · Introduction; 2.1; 3.1 · Fig. 1A
Ni3(HITP)22023 · A Novel Electrocatalyst Pd(II)@Ni3(HITP)2 for Ultrasensitive Detection of Chloramphenicol: Experimental and Computational InvestigationNi3(HITP)2Ni · HITP from 2,3,6,7,10,11-hexaaminotriphenylene (HATP)2D · PristineHighly conductive MOF with XRD peaks assigned to (100), (200), and (001) planes.2 · Results and Discussion · Figure 1
Ni3(HITP)2 bulk powder2023 · Air/liquid interfacial formation process of conductive metal–organic framework nanosheetsNi3(HITP)2Ni · HITP2D · PristineBulk polycrystalline reference material for IR comparison.S6 · Synthesis of Ni3(HITP)2 bulk powder
Ni3(HITP)2 conductive 2D metal-organic framework2023 · Ligand-Mediated Hydrogenic Defects in Two-Dimensional Electrically Conductive Metal-Organic FrameworksNi3(HITP)2Nickel nodes in a charge-neutral 2D kagome lattice. · HITP = 2,3,6,7,10,11-hexaiminotriphenylene, modelled as deprotonated/oxidised HITP3- linkers.2D · Model SystemCharge-neutral kagome lattice; predicted bulk through-space pi-stacking metal and in-plane semiconductor before hydrogenic defects.main p.2 / article p.11388 · Introduction · Figure 1
Pd(II)@Ni3(HITP)22023 · A Novel Electrocatalyst Pd(II)@Ni3(HITP)2 for Ultrasensitive Detection of Chloramphenicol: Experimental and Computational InvestigationPdCl2@Ni3(HITP)2 (reported as Pd(II)@Ni3(HITP)2)Ni framework nodes with adsorbed Pd(II)/PdCl2 · HITP framework; PdCl2 guest/electrocatalyst2D · CompositePdCl2 nanocrystals/adsorbates on Ni3(HITP)2; MOF structure largely retained after loading.2 · Results and Discussion · Scheme 1
Ru@Ni3(HITP)22023 · Ruthenium(II) complex-grafted conductive metal-organic frameworks with conductivity- and confinement-enhanced electrochemiluminescence for ultrasensitive biosensing applicationRu(bpydc)3 grafted in Ni3(HITP)2Ni framework nodes plus grafted Ru(II) bpydc complex · HITP framework; Ru(bpydc)3 guest from tris(4,4'-dicarboxylicacid-2,2'-bipyridyl) ruthenium(II) dichloride2D · CompositeRu complex grafted into Ni3(HITP)2 channels by electrostatic attraction and coordination; PXRD shows framework retained.p001-p002 · Abstract; Introduction · Scheme 1A
ITO/Ni3(HITP)2/perovskite/PC61BM/Ag inverted perovskite solar cell stack2022 · High-Hole-Mobility Metal–Organic Framework as Dopant-Free Hole Transport Layer for Perovskite Solar CellsITO/Ni3(HITP)2/CH3NH3PbI3/PC61BM/AgNi nodes in the Ni3(HITP)2 HTL component. · HITP linker in Ni3(HITP)2; PC61BM electron-transport layer in the device.unknown · CompositeApplication device stack containing a pristine Ni3(HITP)2 film as the hole transport layer.main p.6 · Results and Discussion · Figure 5a
Ni-HITP / Ni3HITP22022 · Operando Elucidation of Electrocatalytic and Redox Mechanisms on a 2D Metal Organic Framework Catalyst for Efficient Electrosynthesis of Hydrogen Peroxide in Neutral MediaNi3HITP2 (HITP = hexaiminotriphenylene)Ni-N4 nodes · 2,3,6,7,10,11-hexaaminotriphenylene-derived HITP/HATP linker2D · PristineConductive 2D MOF with a similar Ni-N4 motif to Ni-HAB, used as comparison catalyst.15847 · Results · Figure S8
Ni-HITP conductive MOF2022 · Dissecting π-conjugated covalent-coupling over conductive MOFs toward efficient two-electron oxygen reductionNot specifiedNi sites; expected Ni1-N4 moieties · 2,3,6,7,10,11-hexaiminotriphenylene (HITP)2D · PristineLayered honeycomb-like hexagonal conductive MOF with pi-conjugated metal-ligand centres; XRD peaks assigned to [100], [200], [210], and [001] planes.2 · 3.1 Morphology and structure characterization · Fig. 1a; Fig. S1
Ni-HITP metal-organic framework2022 · Synthesis of Tostadas-Shaped Metal-Organic Frameworks for Remitting Capacity Fading of Li-Ion BatteriesNi3(2,3,6,7,10,11-hexaiminotriphenylene)2; Ni3(HITP)2Ni centers coordinated by N atoms · 2,3,6,7,10,11-hexaiminotriphenylene (HITP)2D · PristineLayered conductive Ni-HITP framework with (100), (200), and (001) reflections; nanosheet, particle, and mechanically assembled morphologies reported.p001 · Introduction
Ni3(2,3,6,7,10,11-hexaiminotriphenylene)22022 · Catalysing the performance of Li-sulfur batteries with two-dimensional conductive metal organic frameworksNi3(HITP)2Ni · 2,3,6,7,10,11-hexaiminotriphenylene (HITP), nitrogen-based linker2D · Model SystemTriphenylene-based 2D honeycomb MOF monolayer; non-magnetic ground state.PDF p2-p3 / article p12401-p12402 · Introduction; 3.1 Structural and electronic properties · Figure 1; Table 1
Ni3(HITP)22022 · Redox-Active Ni(II) Nodes Induced Electrochromism in a Two-Dimensional Conductive Metal-Organic FrameworkNi3(2,3,6,7,10,11-hexaiminotriphenylene)2Ni ions/Ni nodes; redox-active Ni(II)/Ni(I) centres during electrochromism · Hexadentate HITP ligands derived from HATP.6HCl2D · PristineTwo-dimensional graphene-like layered honeycomb framework with pi-stacked layers and one-dimensional cylindrical channels of about 2 nm.p002 · Results and Discussion · Figure 1a
Ni3(HITP)22022 · Thousand-fold increase in O2electroreduction rates with conductive MOFsNi3(HITP)2; HITP = 2,3,6,7,10,11-hexaiminotriphenyleneNickel nodes in a triphenylene-based conductive MOF framework. · HITP derived from HATP/HATP hydrochloride precursor.2D · PristineMonophasic, highly crystalline 2D conductive MOF, isostructural M3(HITP)2 family.main article p.976 · Results and Discussion · Figure 1A
Ni3(HiTP)2 computational model2022 · Mutually Noninterfering Flexible Pressure-Temperature Dual-Modal Sensors Based on Conductive Metal-Organic Framework for Electronic SkinNi3(HiTP)2Ni · HiTP-derived linker2D · Model SystemFirst-principles model for band structures under 0 and 300 kPa.480 · Analysis of the Mutual Noninterference Mechanism · Figure 4g-i
Ni3(HITP)2 conductive metal-organic framework2022 · Large-Area Synthesis of Ultrathin, Flexible, and Transparent Conductive Metal–Organic Framework Thin Films via a Microfluidic-Based Solution Shearing ProcessNi3(hexaiminotriphenylene)2; Ni3(HITP)2Ni2+ nodes coordinated to imino/semiquinone HITP-derived ligands. · HITP derived from 2,3,6,7,10,11-hexaaminotriphenylene hexahydrochloride (HATP.6HCl).2D · PristineLayered 2D conductive MOF with in-plane (100), (200), (210), (220) PXRD peaks and an oriented (001) stacking feature in GIXD.1 · Abstract
Ni3(HiTP)2 conductive metal-organic framework2022 · Mutually Noninterfering Flexible Pressure-Temperature Dual-Modal Sensors Based on Conductive Metal-Organic Framework for Electronic SkinNi3(HiTP)2Ni(II) · HiTP / 2,3,6,7,10,11-hexaaminotriphenylene-derived ligand2D · PristineConductive MOF film assigned by XRD and literature-prepared Ni3(HiTP)2; band-structure model shown for Ni3(HiTP)2.476 · Results and Discussion · Figure 1; Figure S1
Ni3(HITP)2 layered MOF model2022 · Modeling energy transfer and absorption spectra in layered metal-organic frameworks based on a Frenkel-Holstein HamiltonianNi3(HITP)2; HITP = 2,3,6,7,10,11-hexaiminotriphenyleneNi square-planar nodes in secondary building units · HITP (2,3,6,7,10,11-hexaiminotriphenylene)2D · Model SystemArchetypal layered pi-stacked conductive MOF used as the basis for SBU monomer, dimer, and 1D stack computational models.article page 2 (rendered p003) · I. Introduction · Fig. 1
Ni3(HITP)2 membrane2022 · Adjustable Synthesis of Ni-Based Metal-Organic Framework Membranes and Their Field-Effect Transistor Sensors for Mercury DetectionNi3(HITP)2; Ni3(2,3,6,7,10,11-hexaiminotriphenylene)2Ni coordinated to imino/amino N sites · HITP generated from HATP.6HCl (2,3,6,7,10,11-hexaaminotriphenylene hexahydrochloride) under alkaline conditions2D · PristineConductive layered two-dimensional stacked honeycomb Ni-HITP framework; PXRD reflections assigned to (100), (200) and (001) planes.623 · 2.3. In Situ Synthesis of Ni3(HITP)2 Membranes
Ni3(HITP)2 metal-organic framework2022 · High-Hole-Mobility Metal–Organic Framework as Dopant-Free Hole Transport Layer for Perovskite Solar CellsNi3(2,3,6,7,10,11-hexaiminotriphenylene)2Nickel nodes in a Ni-HITP conductive framework. · 2,3,6,7,10,11-hexaiminotriphenylene, generated from the hexaaminotriphenylene hexahydrochloride precursor under basic conditions.2D · PristineLayered conductive MOF; XRD peaks at 4.7, 9.5, 12.6 and 16.5 degrees are assigned to (100)-family reflections and 27.3 degrees to the (001) reflection.main p.2 · Results and Discussion · Figure 1a
Ni3(HITP)2-DNA FET sensor control2022 · Adjustable Synthesis of Ni-Based Metal-Organic Framework Membranes and Their Field-Effect Transistor Sensors for Mercury DetectionNi3(HITP)2 membrane physically/chemically associated with DNA probe without GA cross-linkerNi centres in Ni3(HITP)2 · HITP framework plus DNA probe2D · CompositeDNA-modified Ni3(HITP)2 membrane control used to test the GA cross-linker contribution.627 · 3.2. Hg2+ Sensing Performance · Figure S9
Ni3(HITP)2-GA FET sensor control2022 · Adjustable Synthesis of Ni-Based Metal-Organic Framework Membranes and Their Field-Effect Transistor Sensors for Mercury DetectionNi3(HITP)2 membrane modified with glutaraldehydeNi centres in Ni3(HITP)2 · HITP framework plus glutaraldehyde2D · CompositeGA-functionalised Ni3(HITP)2 membrane control used to test whether DNA is required for Hg2+ response.627 · 3.2. Hg2+ Sensing Performance · Figure S9
Ni3(HITP)2-GA-DNA FET sensor2022 · Adjustable Synthesis of Ni-Based Metal-Organic Framework Membranes and Their Field-Effect Transistor Sensors for Mercury DetectionNi3(HITP)2 membrane modified with glutaraldehyde and amino-terminated DNA probeNi centres in Ni3(HITP)2 · HITP framework plus GA cross-linker and 5'-NH2-TTG-TTG-TTT-CCT-TTC-GTT-TT-3' DNA probe2D · CompositeFunctionalised conductive MOF membrane; XRD/FT-IR after GA/DNA modification remains similar to pristine S4 and SEM morphology remains nanosheet-like.627 · 3.2. Hg2+ Sensing Performance · Figures S7 and S8
Ni3(HiTP)2-on-microstructured mixed cellulose composite film2022 · Mutually Noninterfering Flexible Pressure-Temperature Dual-Modal Sensors Based on Conductive Metal-Organic Framework for Electronic SkinNi3(HiTP)2/MSMCNi(II) · HiTP-derived linker2D · CompositeNi3(HiTP)2 conformal film wrapped around MSMC fibres; liquid-solid interfacial growth.476 · Fabrication, Sensing Mechanisms and Characterizations · Figure 1
Ni3(HiTP)2-on-polypropylene composite film2022 · Mutually Noninterfering Flexible Pressure-Temperature Dual-Modal Sensors Based on Conductive Metal-Organic Framework for Electronic SkinNi3(HiTP)2/PPNi(II) · HiTP-derived linker2D · CompositeControl substrate composite fabricated using PP membrane instead of MSMC membrane.477 · Pressure-Sensing Properties · Figure S5; Figure S6
Ni3HITP2 conductive MOF2022 · Wet-Adhesive On-Skin Sensors Based on Metal–Organic Frameworks for Wireless Monitoring of Metabolites in SweatNi3HITP2Nickel nodes / Ni sites in a HITP-based conductive MOF. · HITP = 2,3,6,7,10,11-hexaiminotriphenylene or hexaiminotriphenylenesemiquinonate as written in SI.2D · PristineStructurally analogous Ni-cMOF comparator; PXRD compared with Cu3HHTP2 and Ni3HHTP2.3 · Results and Discussions · Figure S8
Pt-atom-immobilised Ni3(HITP)2 thin film2022 · Large-Area Synthesis of Ultrathin, Flexible, and Transparent Conductive Metal–Organic Framework Thin Films via a Microfluidic-Based Solution Shearing ProcessNi3(HITP)2@Pt / Ni3(HITP)2 with atomically dispersed Pt atomsNi nodes with Pt atoms introduced from PtCl2 in the metal-source solution. · HITP derived from HATP.6HCl.2D · CompositeHAADF-STEM image shows atomically dispersed Pt atoms in Ni3(HITP)2.5 · 2.2 Characterizations of Ni3(HITP)2 Thin Film · Figure S21
Br-Ni MOF2021 · Self-Nanocavity-Confined Halogen Anions Boosting the High Selectivity of the Two-Electron Oxygen Reduction Pathway over Ni-Based MOFsBr-confined Ni-HITP-type MOFPlanar Ni nodes interacting with confined bromide anions. · HITP.2D · PristineHalogen-anion-confined conductive Ni MOF showing lattice contraction and contracted nanocavity relative to pristine Ni MOF.main p.4, article p.8709 · Results and discussion · Figure 3d
Cl-Ni MOF2021 · Self-Nanocavity-Confined Halogen Anions Boosting the High Selectivity of the Two-Electron Oxygen Reduction Pathway over Ni-Based MOFsCl-confined Ni-HITP-type MOFPlanar Ni nodes interacting with confined chloride anions. · HITP.2D · PristineHalogen-anion-confined conductive Ni MOF showing lattice contraction relative to pristine Ni MOF.main p.2, article p.8707 · Results and discussion · Figure 1
Cladophora cellulose nanofibre @ Ni-HITP conductive MOF film (CCM)2021 · Solar-driven ionic power generation: Via a film of nanocellulose @ conductive metal-organic frameworkNi-HITP/cellulose compositeNi(II) in Ni-HITP nanolayers · HITP; Cladophora cellulose nanofibres as substrate2D · CompositeCore-shell nanofibres with Ni-HITP coating Cladophora cellulose; stacked/interwoven fibres form a freestanding hierarchical porous film.p002 · Preparation and characterization of the CCM film · Fig. 1
Direct-blended cellulose/Ni-HITP nanopaper2021 · Solar-driven ionic power generation: Via a film of nanocellulose @ conductive metal-organic frameworkNi-HITP particles/cellulose compositeNi(II) in Ni-HITP particles · HITP; Cladophora cellulose2D · CompositeComposite nanopaper made by direct blending of cellulose with Ni-HITP particles; lacks continuous charged cMOF surfaces.p018 · Supplementary Results · Fig. S12
F-Ni MOF2021 · Self-Nanocavity-Confined Halogen Anions Boosting the High Selectivity of the Two-Electron Oxygen Reduction Pathway over Ni-Based MOFsF-confined Ni-HITP-type MOFPlanar Ni nodes interacting with confined fluoride anions. · HITP.2D · PristineHalogen-anion-confined conductive Ni MOF showing lattice contraction relative to pristine Ni MOF.main p.2, article p.8707 · Results and discussion · Figure 1
HITP-Ni-NS2021 · Uniaxially Oriented Electrically Conductive Metal-Organic Framework Nanosheets Assembled at Air/Liquid InterfacesNi3(HITP)2-like nanosheetNi(II) · HITP (deprotonated 2,3,6,7,10,11-hexaaminotriphenylene)2D · PristinePlanar honeycomb Ni2+-HITP network with pi-pi stacked layers; metrically hexagonal in-plane cell.54571 / p002 · Introduction · Figure 1
I-Ni MOF2021 · Self-Nanocavity-Confined Halogen Anions Boosting the High Selectivity of the Two-Electron Oxygen Reduction Pathway over Ni-Based MOFsI-confined Ni-HITP-type MOFPlanar Ni nodes interacting with confined iodide anions. · HITP.2D · PristineHalogen-anion-confined conductive Ni MOF showing lattice contraction relative to pristine Ni MOF.main p.2, article p.8707 · Results and discussion · Figure 1
Ni-HITP2021 · From n- To p-Type Material: Effect of Metal Ion on Charge Transport in Metal-Organic MaterialsNi3(HITP)2; reported analytical approximation Ni3(C18H12N6)1.8Cl0.6*4(H2O)Nickel ions in a metal-organic graphene analogue coordination environment. · HITP = 2,3,6,7,10,11-hexaiminotriphenylene.2D · PristineCrystalline layered metal-organic graphene analogue; used as the Ni control for metal substitution.p001 · Abstract
Ni-HITP conductive metal-organic framework2021 · Solar-driven ionic power generation: Via a film of nanocellulose @ conductive metal-organic frameworkNi3(2,3,6,7,10,11-hexaiminotriphenylene)2Ni(II) · 2,3,6,7,10,11-hexaiminotriphenylene (HITP)2D · PristineLayered conductive MOF with ordered approximately 2 nm nanopores in a hexagonal arrangement; assigned by TEM/HRTEM and XRD reflections.p002 · Preparation and characterization of the CCM film · Fig. 1
Ni3(HITP)22021 · Why conductivity is not always king-physical properties governing the capacitance of 2D metal-organic framework-based EDLC supercapacitor electrodes: A Ni3(HITP)2case studyNi3(HITP)2Square-planar Ni2+ ions bound through imine/iminosemiquinonate linkages. · HITP = 2,3,6,7,10,11-hexaiminotriphenylene, generated from HATP.6HCl precursor.2D · PristineGraphene-like two-dimensional sheets with slipped parallel stacking and tubular channels about 1.6 nm in diameter.main p.2, article p.299 · Main text
Ni3(HITP)22021 · Two-Dimensional Conductive Metal-Organic Frameworks as Highly Efficient Electrocatalysts for Lithium-Sulfur BatteriesNi3(HITP)2Ni transition-metal nodes coordinated by N/O/S donor atoms in the 2D framework · HITP (2,3,6,7,10,11-hexaiminotriphenylene; C18H12N6)2D · Model SystemN-coordinated TM3(HITP)2 kagome 2D MOF; periodic monolayer slab model with kagome sublattice where applicable.PDF p2 / article p.61206 · Introduction
Ni3(HITP)2 bulk powder2021 · Uniaxially Oriented Electrically Conductive Metal-Organic Framework Nanosheets Assembled at Air/Liquid InterfacesNi3(HITP)2Ni(II) · HITP2D · PristineBulk polycrystalline layered 2D conductive MOF reference.S4 / p004 · Synthesis of Ni3(HITP)2 bulk powder
Ni3(HITP)2 electrode composite2021 · Spindle-like Ni3(HITP)2 MOFs: Synthesis and Li+ storage mechanismNi3(HITP)2 powder/conductive carbon/CMC-SBR binder, 60:20:20 by weightNi sites from Ni3(HITP)2 component · HITP in Ni3(HITP)2 component; CMC/SBR polymer binder2D · CompositeComposite electrode film on Cu foil; framework structure retained before/after charge according to XRD.2 · 2.3 Electrochemical characterization
Pristine Ni MOF2021 · Self-Nanocavity-Confined Halogen Anions Boosting the High Selectivity of the Two-Electron Oxygen Reduction Pathway over Ni-Based MOFsNi-HITP-type MOF; exact empirical formula not directly reported in this paperPlanar Ni nodes; Ni2+ features observed by Ni 2p XPS. · 2,3,6,7,10,11-hexaiminotriphenylene (HITP).2D · PristineConductive Ni-based MOF with periodic nanocavity array within the a-b plane; (100) diffraction peak at 2theta = 4.5 degrees and d spacing approx 1.8 nm.main p.2, article p.8707 · Results and discussion · Figure 1
spindle-like Ni3(HITP)2 MOFs2021 · Spindle-like Ni3(HITP)2 MOFs: Synthesis and Li+ storage mechanismNi3(HITP)2Ni2+ coordinated by imine/amino N sites · 2,3,6,7,10,11-hexaiminotriphenylene (HITP), generated from HATP.6HCl2D · PristineD4h-coordination honeycomb 2D lattice; slipped-parallel AB stacking inferred from pore-size mismatch; spindle-like morphology assembled from nanofibres.2 · Results and discussion · Fig. 1a
Wood nanocellulose @ Ni-HITP film2021 · Solar-driven ionic power generation: Via a film of nanocellulose @ conductive metal-organic frameworkNi-HITP/wood nanocellulose compositeNi(II) in Ni-HITP · HITP; wood nanocellulose substrate2D · CompositeNi-HITP grown or deposited on wood nanocellulose; XRD and N2 sorption were reported in SI.p020 · Supplementary Results · Fig. S15
La0.6Sr0.4Co0.8Fe0.2O3@Ni3(HITP)22020 · Conductive metal–Organic frameworks endow high-efficient oxygen evolution of La0·6Sr0·4Co0·8Fe0·2O3 perovskite oxide nanofibersLa0.6Sr0.4Co0.8Fe0.2O3@Ni3(HITP)2La/Sr/Co/Fe perovskite oxide with Ni nodes in the MOF shell · HITP linker in the Ni3(HITP)2 component1D · CompositeComposite hollow nanofibres with a thin amorphous Ni3(HITP)2 layer uniformly bonded to LSCF nanofibres.3 · Results and discussion · Fig. 2c-e
Ni-HITP comparison model2020 · Two-Dimensional Conductive Ni-HAB as a Catalyst for the Electrochemical Oxygen Reduction ReactionNi-HITP 2D MOF model; empirical formula not statedNi(II) nodes · hexaiminotriphenylene (HITP)2D · Model SystemClosely related conductive 2D MOF with larger nanopores and honeycomb structure, included as a computational comparison.39078 · Theoretical Activity of M-HAB · Figure 4
Ni3(HITP)22020 · Continuous Electrical Conductivity Variation in M3(Hexaiminotriphenylene)2(M = Co, Ni, Cu) MOF AlloysNi3(HITP)2Ni(II) · HITP = 2,3,6,7,10,11-hexaiminotriphenylene2D · PristineLayered electrically conducting MOF; synchrotron PXRD Pawley refinements fit orthorhombic Cmcm for pure M3(HITP)2; alloys are isostructural solid solutions following Vegard-type trends.12368-12369 · Results and Discussion · Figures 2-3; Table S1
Ni3(HITP)22020 · Conductive metal–Organic frameworks endow high-efficient oxygen evolution of La0·6Sr0·4Co0·8Fe0·2O3 perovskite oxide nanofibersNi3(HITP)2Ni nodes · HITP from HATP.6HCl, described in reagents as 2,3,6,7,10,11-hexaiminotriphenyleneunknown · PristineConductive metal-organic framework; in this paper the deposited Ni3(HITP)2 phase is described as amorphous or below the XRD detection limit.2 · Introduction
Ni3(HITP)2 conductive MOF2020 · Conductive Metal–Organic Frameworks with Extra Metallic Sites as an Efficient Electrocatalyst for the Hydrogen Evolution ReactionNi3(HITP)2Ni-N4 linkages · HITP, hexaiminotriphenylene2D · PristineTraditional conductive HITP-based MOF control with Ni-N4 linkages and no extra M-N2 sites.main p.8, article p.2000012-8 · Experimental Section
CNF-Ni-HITP direct-mixed paper2019 · Cellulose Nanofiber @ Conductive Metal-Organic Frameworks for High-Performance Flexible SupercapacitorsCNF plus Ni-HITP powder, 85:15 CNF:c-MOF by weightNi(II) in Ni-HITP particles · HITP2D · CompositePhysical mixture control paper made by direct mixing c-MOF powders and CNFs rather than interfacial nanolayer growth.rendered page 4 / article p.9581 · Results and Discussion · Figure 2b and Figure 3e,f
CNF@Ni-HITP hybrid nanofibers / nanopaper2019 · Cellulose Nanofiber @ Conductive Metal-Organic Frameworks for High-Performance Flexible SupercapacitorsCNF@Ni-HITP; c-MOF content about 15 wt % in nanopaper by TGANi(II) in Ni-HITP nanolayers · HITP2D · CompositeCore-shell composite nanofibers with continuous Ni-HITP nanolayers compactly wrapping cellulose nanofibers; assembled into freestanding conductive nanopaper.rendered page 3 / article p.9580 · Results and Discussion · Figure 1c
Ni-HITP conductive metal-organic framework2019 · Cellulose Nanofiber @ Conductive Metal-Organic Frameworks for High-Performance Flexible SupercapacitorsNi3(HITP)2Ni(II) · HITP (2,3,6,7,10,11-hexaaminotriphenylene)2D · PristinePorous honeycomb 2D framework with hexagonal unit cell; main text references Ni3(HITP)2 and reports XRD peaks consistent with Ni-HITP.rendered pages 2-3 / article pp.9579-9580 · Introduction; Results and Discussion · Figure 1b,c
Ni-MOF / Ni3(HITP)22019 · Field-Effect Transistor Based on an in Situ Grown Metal-Organic Framework Film as a Liquid-Gated Sensing DeviceNi3(HITP)2Ni centres, described as Ni-N4 active sites in a two-dimensional framework · HITP derived from 2,3,6,7,10,11-hexaaminotriphenylene hexahydrochloride (HATP*6HCl)2D · PristineTwo-dimensional stacked-sheet conductive MOF; PXRD peaks at 2theta = 4.7, 9.5, 12.5, and 16.5 degrees matched previously reported Ni-MOF structural features.p001 / article p.35935 · Abstract and Introduction
Ni3(hexaiminotriphenylene)2 / Ni3(HITP)22019 · Pressure-induced metallicity and piezoreductive transition of metal-centres in conductive 2-dimensional metal-organic frameworksNi3(C18H6N6)2 (abbreviated Ni3(HITP)2)Nickel centres coordinated to imino-nitrogen atoms in a 2D conductive MOF sheet · HITP = 2,3,6,7,10,11-hexaiminotriphenylene2D · Model System2D-connected conductive MOF; monolayer model studied under hydrostatic pressure.1 · Introduction · Fig. 1
Ni3(HITP)22019 · Single Crystals of Electrically Conductive Two-Dimensional Metal-Organic Frameworks: Structural and Electrical Transport PropertiesNi3(2,3,6,7,10,11-hexaiminotriphenylene)2Ni/NH coordination nodes in a honeycomb 2D framework. · HITP, formed from 2,3,6,7,10,11-hexaaminotriphenylene hexahydrochloride (HATP.6HCl).2D · PristineLayered honeycomb conductive 2D MOF; HRTEM/FFT and PXRD support an eclipsed or near-eclipsed stacking configuration with continuous pores.main p.1-4, article pp.1959-1962 · Abstract; Results and Discussion · Figures 1, 2 and 4a
Ni3(HITP)22019 · Conductive MOF-Modified Separator for Mitigating the Shuttle Effect of Lithium-Sulfur Battery through a Filtration MethodNi3(HITP)2Ni2+ nodes · HITP = 2,3,6,7,10,11-hexaiminotriphenylene; prepared from HATP.6HCl2D · PristineConductive two-dimensional layered MOF with hexagonal pores and one-dimensional channels.main p.2, article p.11460 · Introduction/Experimental Section · Scheme 1; Fig. S1
Ni3(HITP)2-modified polypropylene separator2019 · Conductive MOF-Modified Separator for Mitigating the Shuttle Effect of Lithium-Sulfur Battery through a Filtration MethodNi3(HITP)2/PVDF on PPNi2+ nodes in the Ni3(HITP)2 layer · HITP in Ni3(HITP)22D · CompositeComposite separator consisting of a Ni3(HITP)2-containing coating filtered onto a polypropylene separator.main p.2, article p.11460 · Preparation of the Ni3(HITP)2-Modified Separator · Scheme 1
Ni3(HITP)2 conductive two-dimensional metal-organic framework2018 · Selective reduction of CO2 by conductive MOF nanosheets as an efficient co-catalyst under visible light illuminationNi3(HITP)2Ni2+ centres in square-planar Ni-N4 coordination units. · HITP, 2,3,6,7,10,11-hexaaminotriphenylene.2D · PristineStacked honeycomb 2D conductive MOF; PXRD matches eclipsed or slipped-parallel stacked 2D sheets and XPS supports a single Ni-N4 four-coordinate structure.main p.2, article p.340 · Introduction · Fig. 1a
Ni3(HITP)2 hexagonal MOF2018 · Modular O2 electroreduction activity in triphenylene-based metal-organic frameworksNi3(HITP)2; HITP = 2,3,6,7,10,11-hexaiminotriphenyleneDivalent Ni coordinated by hexaaminotriphenylene-derived N donors in a 2D honeycomb lattice. · HITP / hexaaminotriphenylene-derived ligand.2D · PristineHexagonal crystal system; 2D honeycomb lattice stacked in a slipped parallel configuration along c.1 · Results and discussion · Fig. 1
Ni3(HITP)2/[Ru(bpy)3]2+ hybrid photocatalytic CO2-reduction system2018 · Selective reduction of CO2 by conductive MOF nanosheets as an efficient co-catalyst under visible light illuminationNot specifiedNi-N4 sites in Ni3(HITP)2 plus Ru polypyridyl photosensitiser. · HITP in Ni3(HITP)2; bpy ligands in [Ru(bpy)3]2+.unknown · CompositeApplication mixture, not a new crystalline MOF phase: Ni3(HITP)2 nanosheet co-catalyst, [Ru(bpy)3]Cl2.6H2O photosensitiser and TEOA electron donor in MeCN/H2O.main p.1, article p.339 · Abstract
Ni3(HITP)22017 · Porous field-effect transistors based on a semiconductive metal-organic frameworkNi3(HITP)2Square-planar Ni2+ centres · HITP, 2,3,6,7,10,11-hexaiminotriphenylenesemiquinonate, generated from HATP2D · PristineLayered graphene-like honeycomb porous framework with sixfold symmetry, AB stacking, 1D channels and ca. 1.4 nm open windows.main p.2 / article p.1361 · Results and discussion · Figure 1a
Ni3(HITP)22017 · A Microporous and Naturally Nanostructured Thermoelectric Metal-Organic Framework with Ultralow Thermal ConductivityNi3(2,3,6,7,10,11-hexaiminotriphenylene)2; precise analysed formula reported as Ni3(HITP)1.8Cl0.6·2(acetone)·4H2ONi2+ ions in a layered two-dimensional lattice · HITP3- = 2,3,6,7,10,11-hexaiminotriphenylene2D · PristineLayered honeycomb lattice with stacked 2D sheets and approximately 1.5 nm tubular pores parallel to the c direction; TEM/FFT gave hexagonal cell parameters a = b = 20.1 A and c = 6.6 A.p003 / article p.169 · Introduction · Figure 1A
Ni3(HITP)22017 · Mechanistic Evidence for Ligand-Centered Electrocatalytic Oxygen Reduction with the Conductive MOF Ni3(hexaiminotriphenylene)2Ni3(HITP)2; crystal-structure formula cited as Ni3(C18H12N6)2Ni, square-planar divalent Ni-N coordination · HITP = 2,3,6,7,10,11-hexaiminotriphenylene / hexaaminotriphenylene-derived ligand2D · PristineElectrically conductive 2D MOF with slipped-parallel layer model; interlayer distance 3.33 Angstrom from previously reported crystal structure.7726 · Introduction · Figure 1
Ni3(HITP)2 two-dimensional metal-organic framework model2017 · Two-dimensional metal-organic frameworks with high thermoelectric efficiency through metal ion selectionNi3(HITP)2Ni square-planar d8 metal sites in X3(HITP)2. · HITP = 2,3,6,7,10,11-hexaiminotriphenylene.2D · Model SystemHexagonal monolayer X3(HITP)2 structure based on experimental Ni3(HITP)2; multilayer model considered separately and calculated to be metallic.main p.2 / article p.19462 · Results and discussion
Ni3(hexaiminotriphenylene)22016 · Electrochemical oxygen reduction catalysed by Ni3 (hexaiminotriphenylene)2Ni3(HITP)2; HITP = 2,3,6,7,10,11-hexaiminotriphenyleneSquare-planar Ni-N4 sites in a nickel bis(iminosemiquinone/diimine-type) two-dimensional network. · 2,3,6,7,10,11-hexaiminotriphenylene (HITP), prepared from HATP.6HCl precursor.2D · PristineTwo-dimensionally layered conductive MOF, structurally reminiscent of M-Nx ORR electrocatalysts; long-range ab-plane order retained after ORR.main p.2 · Introduction · Fig. 1
Ni3(HITP)22015 · Cu3(hexaiminotriphenylene)2: An electrically conductive 2D metal-organic framework for chemiresistive sensingNi3(HITP)2Nickel sites in the isostructural M3(HITP)2 framework. · HITP = 2,3,6,7,10,11-hexaiminotriphenylene.2D · PristinePreviously reported isostructural 2D MOF comparator for Cu3(HITP)2.main p.1, article p.4349 · Introduction
Ni3(HITP)2 (MOF 3)2015 · Chemiresistive Sensor Arrays from Conductive 2D Metal-Organic FrameworksNi3(HITP)2Ni square-planar metal centres · HITP (2,3,6,7,10,11-hexaiminotriphenylene)2D · PristineConductive layered hexagonal 2D MOF; sheets stack in eclipsed or slipped-parallel conformations with extended 1D pores.main p002 / article page 13781 · Results · Figure 1