cMOF Evidence Base
Source-verified familyIdentity or context cautions

Cu₃(HHTP)₂ / Cu–HHTP

This family merges chemical shorthand and formula variants only after verification against source articles. Per-paper composition and phase details remain separate below.

Compare coverageBack to material explorer
102primary papers
143material records
524linked samples
1139linked measurements
4,070linked results
2015–2026publication span

Read this group with context

  • Several formulas or formula descriptions are reported
  • More than one known dimensionality is reported
  • Pristine, composite, derived or model contexts are mixed
  • Model-system or unresolved records are present

Evidence coverage

Paper counts are material-linked through samples and measurements; technique groups are not value rankings.

Diffraction Structure76 papers133 measurements · 374 resultsMicroscopy Morphology68 papers162 measurements · 393 resultsElectrical Transport62 papers145 measurements · 375 resultsSpectroscopy58 papers146 measurements · 551 resultsElectrochemistry Application46 papers204 measurements · 848 resultsPorosity35 papers58 measurements · 171 resultsOther33 papers65 measurements · 256 resultsSensing Application29 papers148 measurements · 727 resultsComputational Modelling23 papers65 measurements · 325 resultsThermoelectric3 papers13 measurements · 50 results

Publication timeline

Distinct primary papers in this browse group by publication year.

Primary papers

Filter the material-linked paper set while keeping every result in its original dossier.

102 papers

Primary study2023

Growth mechanisms and anisotropic softness-dependent conductivity of orientation-controllable metal-organic framework nanofilms

Yao M.-S., Otake K.-I., Koganezawa T. et al. · Proceedings of the National Academy of Sciences of the United States of America · 2023

Reported here: Cu-HHTP conductive metal-organic framework · Cu-HHTP nanocrystals · Cu-HHTP-on-iMOF heterostructured thin films

Diffraction Structure · 20Electrical Transport · 22Microscopy Morphology · 21Spectroscopy · 4
Open dossier →
Primary study2023

Overcoming Diffusion Limitation of Faradaic Processes: Property-Performance Relationships of 2D Conductive Metal-Organic Framework Cu3(HHTP)2 for Reversible Lithium-Ion Storage

Wrogemann J.M., Luther M.J., Barmann P. et al. · Angewandte Chemie - International Edition · 2023

Reported here: Cu3(HHTP)2 composite battery electrode · Flake-like Cu3(HHTP)2 · Rod-like Cu3(HHTP)2

Diffraction Structure · 17Electrical Transport · 8Electrochemistry Application · 28Microscopy Morphology · 8Other · 4Porosity · 44Spectroscopy · 6
Open dossier →
Primary study2023

The rise of 2D conductive metal-organic framework: Cu3(HHTP)2 d-π MOF for integrated battery-supercapacitor hybrids

Iqbal M.Z., Shaheen M., Khan M.W. et al. · Materials Today Sustainability · 2023

Reported here: Cu3(HHTP)2 conductive copper MOF · Cu3(HHTP)2//activated carbon hybrid battery-supercapacitor device

Computational Modelling · 6Diffraction Structure · 2Electrical Transport · 4Electrochemistry Application · 16Microscopy Morphology · 2Other · 3Porosity · 4Spectroscopy · 3
Open dossier →
Primary study2019

Catalytic Metal Nanoparticles Embedded in Conductive Metal–Organic Frameworks for Chemiresistors: Highly Active and Conductive Porous Materials

Koo W.-T., Kim S.-J., Jang J.-S. et al. · Advanced Science · 2019

Reported here: Cu3(hexahydroxytriphenylene)2 · Pd nanoparticle-loaded Cu3(HHTP)2 · Pt nanoparticle-loaded Cu3(HHTP)2

Diffraction Structure · 4Electrical Transport · 4Microscopy Morphology · 6Other · 3Porosity · 3Sensing Application · 36Spectroscopy · 7
Open dossier →

Per-paper identity records

Raw names, formulas and structural assignments remain separate; no consensus value is inferred.

Show 143 material identity records
Paper and reported nameFormula and componentsStructure contextSource
Cu-HHTP2026 · Structure and Electrical Transport Properties of Metal Cate-Cholate Frameworks: The Metal Center Matters†M-HHTP; HHTP = 2,3,6,7,10,11-hexahydroxytriphenylene; Cu3HHTP2 (C36H12O12Cu3) reported for Cu-HHTP by ICP-AESCu2+/Cu+ copper nodes coordinated to HHTP catecholate/semiquinone ligands · HHTP (2,3,6,7,10,11-hexahydroxytriphenylene), partially deprotonated/oxidised catecholate-semiquinone units after coordination2D · PristineExtended honeycomb structure within each layer; inclined AA-prime stacking and planar [CuO4] coordination favoured by Jahn-Teller effect.main p.1, article p.311 · Comprehensive Summary
Cu-HHTP conductive metal-organic framework (cMOF)2026 · Microfluidic Printing-Induced Dynamic Splitting of Conductive MOF to Expose High-Density Active Sites for Boosted CO2 ElectroreductionCu3(HHTP)2-type; reported as Cu-HHTP/cMOFCu(II) sites from copper(II) acetate · 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP)2D · PristineLayered two-dimensional conductive Cu-HHTP framework with PXRD peaks assigned to (100), (200), (210), and (001) planes.3 · 2.1 Synthesis and Characterization of cMOF · Figures S4-S5
Cu3(HHTP)2 conductive metal-organic framework2026 · A conductive metal-organic framework-modified electrode for sensitive electrochemiluminescent detection of cardiac Troponin ICu3(HHTP)2Cu centres; discussion assigns mixed-valence Cu+/Cu2+ centres and Cu redox couples · 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP)2D · Pristine2D pi-d conjugated conductive MOF; XRD peaks at 9.45, 12.56, 16.36, and about 28 deg assigned to (200), (210), (220), and (002) planes and matched simulated Cu3(HHTP)2.p002-p003 · 2.3 Synthesis; 3.1 Characterization · Scheme 1; Figure 1A
Cu3(HHTP)2-modified screen-printed carbon electrode2026 · A conductive metal-organic framework-modified electrode for sensitive electrochemiluminescent detection of cardiac Troponin ICu3(HHTP)2 drop-cast on SPCECu centres in Cu3(HHTP)2 · HHTP-derived dioxolene/catechol-quinone linker2D · CompositeComposite electrode comprising a Cu3(HHTP)2 layer on a screen-printed carbon electrode.p002 · 2.4 Fabrication
Cu-CAT (Cu-based catecholate 2D conductive MOF)2025 · Radiation-Induced in Situ Construction of 2D Conductive Defect-Rich Metal-Organic Frameworks for High-Performance SupercapacitorCu-CAT / Cu-HHTP framework; exact empirical formula not reportedCu, mixed Cu2+/Cu+ centres reported by XPS/XAFS · 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP), oxidised/semquinonate catecholate units2D · PristineHexagonal P6/m; ordered 1D pore channels; PXRD indexed to 110, 200, 210 and 002 planes.1-2 · Abstract; Results and Discussion · Figure 1
Cu-HHTP2025 · In situ construction of a dual-metal 2D conjugated metal-organic framework on carbon paper for asymmetric supercapacitorsCu-HHTPCu sites · HHTP2D · PristineSingle-metal HHTP MOF shown by SEM in the SI; synthesis details not reported in the provided text layer.Figure captions · Figure S2
Cu-HHTP2025 · Dual-metal sites enable conductive metal-organic frameworks with extraordinary high capacitance for transparent energy storage devicesCu-HHTPCu · HHTP2D · PristineSingle-metal layered HHTP c-MOF; PXRD peaks indexed to layered structures.p003 / 9278 · Results and discussion · Fig. 2
Cu-HHTP2025 · Mitigating lipid biofouling in wearable sweat sensors: A study on conductive MOF-based electrodes with tuned hydrophilicityCu3(HHTP)2(H2O)6Cu nodes · HHTP (2,3,6,7,10,11-hexahydroxytriphenylene)2D · Pristine2D conductive MOF; PXRD peaks consistent with simulated Cu-HHTP pattern4 · Fig. 2 caption · Fig. 2b
Cu-HHTP 2D conductive MOF2025 · Copper-Based Two-Dimensional Conductive Metal-Organic Framework Thin Films for Ultrasensitive Detection of Perfluoroalkyls in Drinking WaterCu-HHTP; copper hexahydroxy triphenylene frameworkCopper nodes in CuO4 coordination; Cu present as Cu1+ and Cu2+ in the neutral framework · Hexahydroxytriphenylene / hexahydroxy triphenylene (HHTP)2D · Pristine2D conductive honeycomb Cu-HHTP thin film with diffraction indexed to (100), (200), (210), and broad (002) reflections.p002-p003 / article pp.6333-6334 · Results and Discussion - Materials Processing and Device Fabrication; MOF Structure Characterization · Figures 1-2
Cu-HHTP conductive metal-organic framework2025 · Conductive Metal–Organic Frameworks Anchoring on V3O7·H2O Nanobelts Toward High-Capacity and Long-Life Zinc-Ion BatteriesCu-HHTP; commonly Cu3(HHTP)2 but exact stoichiometry not specified in this paperCu ions from anhydrous copper acetate · HHTP = hexahydroxytriphenylene2D · Pristine2D conductive MOF with prominent diffraction peaks at 5.0, 9.6, and 12.6 degrees assigned to the (100), (200), and (210) planes.p002 · 2.1. Structural and Morphological Characterization · Figure 1a; Figure S1
Cu-HHTP conductive metal-organic framework2025 · Electro Fenton degradation of glyphosate by incrassated defect-free conductive Cu metal organic frameworkCu-HHTP (exact stoichiometry not explicitly reported in this paper)Cu centres coordinated by catecholate O atoms; described as CuO4 nodes with Cu2+/Cu+ redox cycling · HHTP = 2,3,6,7,10,11-hexahydroxytriphenylene2D · PristineLayered pi-pi conjugated conductive 2D MOF with AA-stacking Cu-HHTP powder peaks and film [001] stacking features.2 · Introduction
Cu-HHTP electrically conductive metal-organic framework2025 · From 0D to 2D: Microwave-assisted synthesis of electrically conductive metal-organic frameworks with controlled morphologiesCu-HHTP; idealised as Cu3(HHTP)2 in the conductive MOF literatureCopper nodes from Cu(NO3)2.2.5H2O. · HHTP, 2,3,6,7,10,11-hexahydroxytriphenylene.2D · PristineLayered eclipsed hexagonal Cu-HHTP framework; refined samples have P6/mmm symmetry. The paper controls particle morphology as 0D spheres, 1D rods and 2D sheets.main p.3168 · Abstract
Cu-HHTP electrically conductive MOF2025 · Stacking growth of ionically conductive MOF on biofabrics enables reliable NH3 sensor for hepatic encephalopathy diagnosisCu-HHTPCu2+ coordinated with HHTP ligands · HHTP2D · PristineM-HHTP EC-MOF analogue prepared by LBL-LPE.p003 · Performance comparison of M-HHTP and M-TCPP · Figure 3a
Cu-HHTP/OTS2025 · Mitigating lipid biofouling in wearable sweat sensors: A study on conductive MOF-based electrodes with tuned hydrophilicityCu-HHTP modified with OTSCu nodes · HHTP plus octadecyltrichlorosilane surface modification2D · CompositeHydrophobic OTS-modified Cu-HHTP; PXRD peaks consistent with simulated pattern4 · Fig. 2 caption · Fig. 2b
Cu-HHTP; Cu3(HHTP)22025 · Interconnected Lamellar 3D Semiconductive PCP for Rechargeable Aqueous Zinc Battery CathodesCu3(HHTP)2Cu nodes in HHTP conductive MOF framework. · HHTP2D · PristinePreviously reported HHTP-based conductive MOF used as structural/PDF comparison control.p.7 / article p.2411386-7 · Experimental Section · Materials
Cu-HHTP[001] oriented Cu3(HHTP)2 thin film2025 · Volatolomics in Fritillarias and Their Identification by Orientation Controlled cMOF Thin Film ChemiresistorsCu3(HHTP)2Cu2+ ions coordinated to HHTP ligands · HHTP2D · PristineAnisotropic Cu3(HHTP)2 thin film grown along the [001] orientation by layer-by-layer immersion in ethanolic Cu(OAc)2 and HHTP solutions.p002 · Results and Discussion · Figure 1
Cu-HHTP[100] oriented Cu3(HHTP)2 thin film2025 · Volatolomics in Fritillarias and Their Identification by Orientation Controlled cMOF Thin Film ChemiresistorsCu3(HHTP)2Cu2+ ions coordinated to HHTP ligands · HHTP2D · PristineAnisotropic Cu3(HHTP)2 thin film grown along the [100] orientation by layer-by-layer immersion in aqueous Cu(OAc)2 and HHTP solutions.p002 · Results and Discussion · Figure 1
Cu-O4 Cu3(HHTP)2 DFT surface model2025 · Fabrication of a Novel Cu Based Conjugated Coordination Polymer for Effective Electroreduction of Nitrate to Ammonia and Zn–Nitrate BatteriesCu3(HHTP)2 surface modelCu-O4 active site in a periodic Cu3(HHTP)2 surface. · HHTP-derived conjugated ligand in the model surface.2D · Model SystemDFT comparison model for NO3 adsorption, PDOS, d-band centre, Gibbs free-energy profiles and hydrogen adsorption.7-8 · Results and Discussions · Figure 5
Cu3(HHTP)22025 · Cu─X Bonds Regulated Conduction and Polarization Loss in Conductive Metal-Organic Framework Under Electromagnetic FieldCu3(HHTP)2; HHTP = 2,3,6,7,10,11-hexahydroxytriphenyleneCu-X4 square-planar units, X = O; mixed Cu(II)/Cu(I) detected · HHTP hydroxyl triphenylene linker2D · PristineIsoreticular hcb topology, layered 2D conductive MOF; Cu-O coordination; slip-parallel stacking with ca. 3.2 A interlayer spacing.2 · Section 2.1 · Figure 1a
Cu3(HHTP)22025 · Employing Triphenylene-Based, Layered, Conductive Metal-Organic Framework Materials as Electrochemical Sensors for Nitric Oxide in Aqueous MediaCu3(HHTP)2Cu2+ · 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP)2D · PristineLayered conductive HHTP MOF; AAAA/slipped-parallel stacking without intercalated layer.555 · Characterization of HHTP MOFs · Figure 1
Cu3(HHTP)22025 · Electrically Conducting Redox-Complementary Dual-Ligand 2D Graphitic MOF with Orthogonal Charge Transport PathwaysCu3(HHTP)2Copper nodes coordinated to catecholate HHTP ligands · Hexahydroxytriphenylene (HHTP; pi-donor)2D · PristineSingle-ligand parent hexagonal 2D MOF; PXRD pattern compared with CDL-MOF1.p003 / article p.3 · Results and Discussion · Figure 2; Figure 5
Cu3(HHTP)22025 · Dirac-cone induced metallic conductivity in Cu3(HHTP)2: high-quality MOF thin films fabricated via ML-driven robotic synthesisCu3(HHTP)2 / Cu3HHTP2Cu2+ secondary building units · 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP)2D · PristineConductive MOF composed of conjugated two-dimensional honeycomb monolayers; AB stacking in bilayer and ABAB stacking in bulk; channels along [001].p002 / 6190 · Introduction · Fig. 1
Cu3(HHTP)22025 · Catalysis-Assisted Synthesis of Two-Dimensional Conductive Metal–Organic Framework Films with Controllable OrientationCu3(HHTP)2Cu ions; Cu2+ and Cu+ by XPS · HHTP, partly oxidised catecholate/semiquinonate moieties2D · PristineLayered 2D conductive metal-catecholate MOF; face-on and edge-on films distinguished by XRD orientation.17060 · Results and Discussion · Figure 2
Cu3(HHTP)22025 · Flexible conductive metal-organic framework Cu3(HHTP)2 film with high thermoelectric performance for low-grade heat harvestingCu3(HHTP)2Cu ions coordinated by catecholate oxygen atoms; XPS discussion indicates coexistence of Cu+ and Cu2+ in the powder. · HHTP = 2,3,6,7,10,11-hexahydroxytriphenylene.2D · PristineTwo-dimensional extended conjugated hexagonal layered conductive MOF; layers stack along the c-axis to form honeycomb-like porous structure and one-dimensional channels.main p.3 · 3. Results and discussion · Figure 3a
Cu3(HHTP)22025 · Electrochemical Synthesis of Cu3(HHTP)2Metal–Organic Frameworks from Cu Nanoparticles for Chemiresistive Gas SensingCu3(HHTP)2Cu (square-planar Cu-O4 nodes; XPS shows mixed Cu+/Cu and Cu2+) · HHTP (2,3,6,7,10,11-hexahydroxytriphenylene), coordinated as semiquinone/catecholate2D · PristineHexagonal 2D layers that stack into 3D porous crystals with pore channels; PXRD indexed to hexagonal unit cell a=b=21.17 A, c=3.21 A.1,5 · Introduction; 3.1 Preparation and Characterization · Figure 1; Figure 3d
Cu3(HHTP)22025 · Advanced dual-signal point-of-care testing platform for sensitive T-2 toxin detection: Integrating copper-based conductive MOF with target-responsive DNA hydrogelCu3(HHTP)2copper ion clusters / Cu2+ sites · 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP)2D · PristineTwo-dimensional layered copper-based conductive MOF2 · Introduction
Cu3(HHTP)2 conductive metal-organic framework2025 · Volatolomics in Fritillarias and Their Identification by Orientation Controlled cMOF Thin Film ChemiresistorsCu3(HHTP)2; HHTP = 2,3,6,7,10,11-hexahydroxytriphenyleneCu2+ ions coordinated to HHTP ligands · 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP)2D · PristineHexagonal 2D honeycomb layered conductive MOF; HR-TEM lattice fringe assigned to the [100] crystal plane.p003 · Results and Discussion · Figure 2g-i
Cu3(HHTP)2 conjugated coordination polymer2025 · Fabrication of a Novel Cu Based Conjugated Coordination Polymer for Effective Electroreduction of Nitrate to Ammonia and Zn–Nitrate BatteriesCu3(HHTP)2Atomically dispersed Cu sites coordinated by four O atoms; Cu-O4 coordination. · HHTP ligand.2D · PristineHexagonal layered conjugated coordination polymer with layered stacking; XRD peaks assigned to (100), (200), (210) and (002) planes.3 · Results and Discussions · Figure 2
Cu3(HHTP)2 control 2D c-MOF2025 · Ligand-Insertion Strategy for Constructing 2D Conjugated Metal–Organic Framework with Large Pore Size for Electrochemical AnalyticsCu3(HHTP)2Cu catecholate coordination units · HHTP2D · PristineLiterature Cu3(HHTP)2 control used for coated-electrode and surface-area comparison.2 · Materials and Methods
Cu3(HHTP)2 monometallic MOF control2025 · Construction of a portable and sensitive electrochemical immunosensor for the rapid detection of erythromycin based on semiconductive bimetallic MOFCu3(HHTP)2Cu centres in an HHTP conductive MOF. · 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP).2D · PristinePreviously reported Cu3(HHTP)2 pattern used as a structural/electrochemical comparator.p.4 · Results and discussion - Basic characterizations · Fig. 1e; Fig. S4a
Cu3(HHTP)2 SURMOF / Cu-CAT-12025 · Impact of the Channel Length in Nanoporous Electric Double-Layer Capacitors on the Charge Transport Explored by Metal-Organic Framework FilmsCu3(HHTP)2Cu(II) ions / Cu-catecholate nodes · 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP)2D · PristineLayered two-dimensional conductive MOF with stacked pi-conjugated layers and one-dimensional cylindrical pores approximately 2 nm in diameter; oriented SURMOF films have layers parallel to the substrate and channels perpendicular to it.267 · Introduction · Figure 1a
Cu3(HHTP)2/Nylon hot-pressed film2025 · Flexible conductive metal-organic framework Cu3(HHTP)2 film with high thermoelectric performance for low-grade heat harvestingCu3(HHTP)2 on porous nylon membraneCu ions in Cu3(HHTP)2 nanorods. · HHTP linker in Cu3(HHTP)2; nylon membrane substrate is not part of the MOF framework.2D · CompositeComposite flexible film in which Cu3(HHTP)2 nanorods are vacuum-filtered onto porous nylon and densified by hot pressing; XRD peak positions remain largely consistent with powder.main p.2 · 2.3. Fabrication of Cu3(HHTP)2 hot-pressing films · Figure 1
Cu3HHTP22025 · Asymmetrical Substitution Manipulates Stacking Modes in 2D Conductive MOF CrystalsCu3HHTP2Cu catecholate nodes; square-planar CuO4 units · HHTP (2,3,6,7,10,11-hexahydroxytriphenylene)2D · Pristine2D honeycomb sheets with slipped parallel/4-fold interpenetrated stacking; orthorhombic Cmcm model from PXRD/Pawley and prior single-crystal report.4-5 · Results and Discussion · Figure 4 and Figure 5
Cu3HHTP22025 · Photoactivated conductive MOF thin film arrays on micro-LEDs for chemiresistive gas sensingCu3(HHTP)2Cu · HHTP; H6HHTP = 2,3,6,7,10,11-hexahydroxytriphenylene2D · Pristine2D conductive M3HHTP2 framework with hexagonal pores; phase matched to crystalline Cu3HHTP2 powder by Raman.2 · Introduction · Fig. 1a
Finite cluster model of Cu-HHTP2025 · Copper-Based Two-Dimensional Conductive Metal-Organic Framework Thin Films for Ultrasensitive Detection of Perfluoroalkyls in Drinking WaterCu-HHTP cluster extracted from periodic Cu-HHTPOne Cu node with truncated HHTP-linker environment · Two linker molecules from periodic Cu-HHTP, hydrogen-terminated at truncated bonds0D · Model SystemComputational finite cluster derived from the full periodic Cu-HHTP structure for PFAS binding and defluorination modelling.p007 / article p.6338 · Materials and Methods - Density Functional Theory (DFT) Calculations · Figure 4e; Figure S16-S17
T-2 toxin-responsive DNA hydrogel loaded with Cu3(HHTP)22025 · Advanced dual-signal point-of-care testing platform for sensitive T-2 toxin detection: Integrating copper-based conductive MOF with target-responsive DNA hydrogelNot specifiedCu3(HHTP)2 component provides copper active sites · HHTP in the MOF; DNA aptamer strands SA/SB/Apt, hyaluronic acid and PEI in hydrogel matrixunknown · CompositeTarget-responsive DNA hydrogel carrier containing Cu3(HHTP)25 · 3.3. Principle for T-2 toxin · Scheme 1
VO@Cu-HHTP composite2025 · Conductive Metal–Organic Frameworks Anchoring on V3O7·H2O Nanobelts Toward High-Capacity and Long-Life Zinc-Ion BatteriesV3O7.H2O@Cu-HHTPV-O nanobelt host plus Cu nodes in anchored Cu-HHTP · HHTP in anchored Cu-HHTPunknown · CompositeCu-HHTP anchored on V3O7.H2O nanobelts by pi-d conjugation; composite retains V3O7.H2O reflections with a Cu-HHTP peak near 8.4 degrees.p002 · 2.1. Structural and Morphological Characterization · Figure 1a
A-Cu-HHTP2024 · Toward Enhancing Performance of Electromagnetic Wave Absorption for Conductive Metal-Organic Frameworks: Nanostructure Engineering or Crystal Morphology ControllingCu-HHTP; commonly described as Cu3(HHTP)2, exact stoichiometric formula not explicitly restated in this paperCu ions coordinated by catecholate oxygen atoms; Cu+ and Cu2+ states observed by XPS · HHTP = 2,3,6,7,10,11-hexahydroxytriphenylene hydrate2D · PristineConductive Cu-HHTP MOF with nanosheet morphology; PXRD consistent with phase-1/eclipsed AA stacking.1,3 · Abstract; Results and Discussion · Figure 2a
B-Cu-HHTP2024 · Toward Enhancing Performance of Electromagnetic Wave Absorption for Conductive Metal-Organic Frameworks: Nanostructure Engineering or Crystal Morphology ControllingCu-HHTP; commonly described as Cu3(HHTP)2, exact stoichiometric formula not explicitly restated in this paperCu ions coordinated by catecholate oxygen atoms; Cu+ and Cu2+ states observed by XPS · HHTP = 2,3,6,7,10,11-hexahydroxytriphenylene hydrate2D · PristineConductive Cu-HHTP MOF with nanorod morphology; PXRD more consistent with near phase-1/tilted stacking.3 · Results and Discussion · Figure 2b
C-Cu-HHTP2024 · Toward Enhancing Performance of Electromagnetic Wave Absorption for Conductive Metal-Organic Frameworks: Nanostructure Engineering or Crystal Morphology ControllingCu-HHTP; commonly described as Cu3(HHTP)2, exact stoichiometric formula not explicitly restated in this paperCu ions coordinated by catecholate oxygen atoms; Cu+ and Cu2+ states observed by XPS · HHTP = 2,3,6,7,10,11-hexahydroxytriphenylene hydrate2D · PristineConductive Cu-HHTP MOF with nanoball/agglomerated morphology; PXRD highly consistent with phase-1/eclipsed AA stacking.3 · Results and Discussion · Figure 2c
Cu-HHTP2024 · Metal-organic frameworks with fine-tuned interlayer spacing for microwave absorptionCu3(HHTP)2Cu2+ centres · 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP)2D · PristineLayered 2D hexagonal cMOF with (100), (200), (210), and (001) PXRD reflections; ordered pi-stacked layers.2-3 · Results · Fig. 1; Fig. 2C
Cu-HHTP2024 · A novel pencil graphite electrode modified with an iron-based conductive metal-organic framework exhibited good ability in simultaneous sensing bisphenol A and bisphenol SCu-HHTP; exact stoichiometry not reportedCu · HHTPunknown · PristineMetal-HHTP control MOF used in sensing comparison.2,7 · 2.2.1; 3.3 · Fig. 3F
Cu-HHTP model2024 · Two-Dimensional Conjugated Metal–Organic Frameworks with a Ring-in-Ring Topology and High Electrical ConductanceCu HHTP framework modelCuO4 nodes · HHTP ligand model2D · Model SystemComparative computational model for band dispersion and DOS near the Fermi level.S19 · Computational Study of Electronic Properties · Figure S23
Cu2O@CuHHTP-n2024 · In Situ Growth of Conductive Metal-Organic Framework onto Cu2O for Highly Selective and Humidity-Independent Hydrogen Sulfide Detection in Food Quality AssessmentCu2O@CuHHTP-nCu2O core plus Cu ions in CuHHTP shell · HHTP in CuHHTP shell2D · CompositeComposite core-shell material; CuHHTP shell on Cu2O with 12-42 nm thickness depending on cycle number.p002 / 1311 · Introduction · Figure 1
Cu3(HHTP)22024 · Acid-Dependent Charge Transport in a Solution-Processed 2D Conductive Metal-Organic FrameworkCu3(HHTP)2CuO4 copper-catecholate nodes · HHTP = 2,3,6,7,10,11-hexahydroxytriphenylene2D · PristineParent isostructural copper-catecholate conductive MOF used as comparison/control.S4 · Materials
Cu3(HHTP)22024 · Molecular-Level Pore Tuning in 2D Conductive Metal-Organic Frameworks for Advanced Supercapacitor PerformanceCu3(HHTP)2Cu · HHTP = 2,3,6,7,10,11-hexahydroxytriphenylene2D · PristineParental conductive MOF control without pendant amines.S4 · Materials
Cu3(HHTP)22024 · Emerging class of SrZrS3 chalcogenide perovskite solar cells: Conductive MOFs as HTLs - A game changer?Cu3(HHTP)2Cu ions · HHTP = 2,3,6,7,10,11-hexahydroxytriphenylene2D · Model Systemtwo-dimensional hexagonal conductive MOF layer2 · 1. Introduction
Cu3(HHTP)22024 · Detection of Ascorbic Acid by Two-Dimensional Conductive Metal-Organic Framework-Based Electrochemical SensorsCu3(HHTP)2Cu · HHTP2D · PristineTwo-dimensional conductive MOF; XRD peaks assigned to (100), (200), (210), and (004) planes.2 · Introduction
Cu3(HHTP)2/SPE electrochemical sensor2024 · Detection of Ascorbic Acid by Two-Dimensional Conductive Metal-Organic Framework-Based Electrochemical SensorsCu3(HHTP)2/SPECu · HHTP2D · CompositeCu3(HHTP)2 deposited on a screen-printed electrode working surface.1 · Abstract
Cu3HHTP22024 · Humidity-Mediated Dual Ionic-Electronic Conductivity Enables High Sensitivity in MOF ChemiresistorsCu3(HHTP)2; HHTP = 2,3,6,7,10,11-hexahydroxytriphenyleneCu nodes in a triphenylene-based 2D conductive MOF · HHTP2D · PristineTriphenylene-based cMOF control; PXRD and SEM shown in SI.p002 / article p.20214 · Results and Discussion · Figures S4 and S5
CuCAT2024 · In-situ growth of electrically conductive MOFs in wood cellulose scaffold for flexible, robust and hydrophobic membranes with improved electrochemical performanceCu-HHTP catecholate frameworkCu(II) · 2,3,6,7,10,11-hexahydroxytriphenylene hydrate (HHTP)2D · PristineCopper catecholate EC-MOF analogue grown on TOW; bonding and properties are mainly discussed in missing SI.p004 / journal page 4 · 3.1 Preparation of EC-MOF@TOW membrane
CuHHTP2024 · In Situ Growth of Conductive Metal-Organic Framework onto Cu2O for Highly Selective and Humidity-Independent Hydrogen Sulfide Detection in Food Quality AssessmentCuHHTP; HHTP = 2,3,6,7,10,11-hexahydroxytriphenyleneCu ions · HHTP2D · PristineConductive MOF; XRD peaks assigned to CuHHTP (100) and (200) planes.p002 / 1311 · Introduction
MOF/PMMA/DTT-8 floating-gate optoelectronic memory transistor stack2024 · MOF-enabled high-density 2D molecular crystal optoelectronic memory transistor with floating gate architectureSi/SiO2/Cu3(HHTP)2/PMMA/DTT-8/Au device stackCu3(HHTP)2 MOF floating-gate layer; Au source-drain electrodes · HHTP in the MOF; DTT-8 organic semiconductor; PMMA blocking layer2D · CompositeLayer-by-layer bottom-gate top-contact OFET memory device with Cu3(HHTP)2 MOF as floating gate and DTT-8 2DMC as active layer.main p.4, article p.6946 · 2.3 2DMC optical memory transistors based on MOF floating gate · Fig. 3a
Two-dimensional Cu3(HHTP)2 metal-organic framework film2024 · MOF-enabled high-density 2D molecular crystal optoelectronic memory transistor with floating gate architectureCu3(HHTP)2Copper ions coordinated with HHTP ligands; Cu, C and O coordination confirmed by XPS. · 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP)2D · PristineHexagonal 2D MOF film with XRD peaks assigned to (100), (200), (210) and (002); used as the floating-gate charge-trapping layer.main p.2, article p.6944 · 2.1 Preparation and characterization of 2D MOF films · Fig. 1
AgNPs@Cu3(HHTP)22023 · Ag Nanoparticles-Induced Metallic Conductivity in Thin Films of 2D Metal-Organic Framework Cu3(HHTP)2Ag nanoparticles decorated Cu3(HHTP)2Cu nodes in Cu3(HHTP)2 plus zerovalent Ag nanoparticles · HHTP2D · CompositeComposite thin film of microcrystallite Cu3(HHTP)2 rods decorated with Ag nanoparticles; Cu3(HHTP)2 crystallinity retained by XRD and Ag fcc nanoparticle lattice observed by HRTEM.2 · Results · Figure 1
Cu-HHTP conductive metal-organic framework2023 · Self-Powered Disinfection Using Triboelectric, Conductive Wires of Metal-Organic FrameworksCu-HHTP; exact empirical formula not reportedCu(II) ions · 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP)2D · PristineCu(II) coordinates with HHTP ligands in the ab plane to form a 2D hexagonal lattice; layers pack along the c axis in parallel AB stacking, forming open cylindrical channels.3091 · Results overview · Figure 1e
Cu-HHTP conductive metal-organic framework2023 · Growth mechanisms and anisotropic softness-dependent conductivity of orientation-controllable metal-organic framework nanofilms[Cu3(HHTP)2]; HHTP = 2,3,6,7,10,11-hexahydrotriphenyleneCu2+ in [CuO4] planar units · 2,3,6,7,10,11-hexahydrotriphenylene (HHTP)2D · PristineHexagonal 2D pi-conjugated framework; P6mmm; 2D layers in the ab-plane and AB slipped-parallel pi-pi stacking along c.p002 · Syntheses and Structures · Fig. 1
Cu-HHTP control MOF2023 · 2D conjugated metal-organic framework as a proton-electron dual conductorCu-HHTP; exact empirical formula not reported in this paperCu nodes in an HHTP-based 2D MOF without axial ligands. · HHTP.2D · PristineIsostructural control to Zn-HHTP-H2O but without axial ligands.main p.6 / article p.148 · Results and discussion - Proton-electron dual conductivity of Zn-HHTP-H2O · Figure S14
Cu-HHTP MOF2023 · Dominant Role of Hole Transport Pathway in Achieving Record High Photoconductivity in Two-Dimensional Metal–Organic FrameworksCu3(HHTP)2Cu nodes / Cu2+ square-planar centres · 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP)2D · PristineConductive layered 2D M-HHTP framework; AA-like stacking gave the better PXRD simulation and the ab plane is stacked along c with about 3.2 Angstrom interlayer distance.p002 · Results and Discussion · Scheme 1 and Figure 1
Cu-HHTP nanocrystals2023 · Growth mechanisms and anisotropic softness-dependent conductivity of orientation-controllable metal-organic framework nanofilmsCu-HHTP nanocrystalsCu from copper acetate · HHTP2D · PristineFree Cu-HHTP nanocrystals used as a comparison for humidity-induced lattice expansion.SI p003 · Preparation of Cu-HHTP nanocrystals
Cu-HHTP-on-iMOF heterostructured thin films2023 · Growth mechanisms and anisotropic softness-dependent conductivity of orientation-controllable metal-organic framework nanofilmsCu-HHTP on Cu-BDC or Cu-BTCCu-HHTP cMOF layer on copper-carboxylate iMOF layer · HHTP in cMOF layer; BDC or BTC in bottom iMOF layer2D · CompositeMOF-on-MOF bilayers/trilayers; bottom iMOF affects quality but not the original Cu-HHTP orientation strongly.p004 · Synthesis and Structure of MOF-on-MOF Thin Films · SI Fig. S30-S36
Cu-MOF/CPE modified carbon paste electrode2023 · Controllable Construction of Two-Dimensional Conductive M3(HHTP)2 Nanorods for Electrochemical Sensing of Malachite Green in FishCu3(HHTP)2 + graphite powder + paraffin oilCu3(HHTP)2 nanorod component. · HHTP in the Cu3(HHTP)2 component.unknown · CompositeComposite carbon-paste sensing electrode containing 2 wt% Cu3(HHTP)2 nanorods.main p.3, article p.22918 · Preparation of the M3(HHTP)2 Nanorod Modified Electrode · Scheme 2
Cu-MOF; Cu3(HHTP)22023 · Strategies to enhance electrochemical performance of isoreticular 2d conjugated metal correlated organic frameworks via transition metals intercalation for battery-supercapacitor hybridsCu3(HHTP)2Cu ions; text discusses mixed oxidation states of metal and ligand · HHTP (2,3,6,7,10,11-hexahydroxytriphenylene)2D · Pristine2D conjugated c-MOF with hexagonal conjugated framework; described as slipped-parallel relative to Ni analogue.2 · Introduction
Cu3(HHTP)22023 · Ag Nanoparticles-Induced Metallic Conductivity in Thin Films of 2D Metal-Organic Framework Cu3(HHTP)2Cu3(C18H6O6)2 / Cu3(HHTP)2Cu nodes; mixed Cu(II)/minor Cu(I) detected by XPS · HHTP = 2,3,6,7,10,11-hexahydroxytriphenylene2D · PristineSemiconducting 2D pi-conjugated MOF thin film with characteristic out-of-plane XRD peaks at about 9.8 and 12.9 degrees 2theta assigned to (200) and (210) planes.1 · Abstract/Introduction
Cu3(HHTP)22023 · A Triptycene-Based 2D MOF with Vertically Extended Structure for Improving the Electrocatalytic Performance of CO2 to MethaneCu3(HHTP)2CuO4 units · 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP)2D · PristineRepresentative planarly extended 2D conductive MOF used as the comparison catalyst and DFT comparator.4 · The e-CO2RR Performance of 2D-vc-MOF(Cu) · Figure 4; Figures S36-S38
Cu3(HHTP)22023 · Microscopic Origin of Electrochemical Capacitance in Metal-Organic FrameworksCu3(HHTP)2Cu coordinated by catecholate O donors; Cu maintained as Cu2+ in modelling and XANES context · HHTP = 2,3,6,7,10,11-hexahydroxytriphenylene2D · Pristine2D layered conductive MOF; PXRD compared with a hexagonal eclipsed P6/mmm crystal structure; model uses cylindrical one-dimensional hexagonal pores.14530 · Results and Discussion · Figure 1
Cu3(HHTP)2 composite battery electrode2023 · Overcoming Diffusion Limitation of Faradaic Processes: Property-Performance Relationships of 2D Conductive Metal-Organic Framework Cu3(HHTP)2 for Reversible Lithium-Ion StorageCu3(HHTP)2/carbon black/PVDFCu centres in Cu3(HHTP)2 active material · HHTP framework in active material2D · CompositeComposite electrode retaining dominant Cu3(HHTP)2 morphology and crystal structure after processing.S-5 · 1.3 Electrode preparation · Figure S11; Figure S12
Cu3(HHTP)2 conductive copper MOF2023 · The rise of 2D conductive metal-organic framework: Cu3(HHTP)2 d-π MOF for integrated battery-supercapacitor hybridsCu3(HHTP)2; HHTP = 2,3,6,7,10,11-hexahydroxytriphenyleneCopper ions with reported Cu(II)/Cu(I) redox couple; copper-organic coordination in a 2D conductive framework. · 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP).2D · PristineHexagonal two-dimensional layered conductive MOF; PXRD peaks assigned to [100], [200], [210], [001], [220] and [112] phases and described as aligned with simulated results.main p.1 · Abstract
Cu3(HHTP)2 conductive metal-organic framework2023 · Orientation Control of a Two-Dimensional Conductive Metal-Organic Framework Thin Film by a Pyridine Vapor-Assisted Dry ProcessCu3(HHTP)2; HHTP = 2,3,6,7,10,11-hexahydroxytriphenyleneCu(II) ions / copper acetate-derived Cu nodes · HHTP (2,3,6,7,10,11-hexahydroxytriphenylene)2D · PristineLayer-structured two-dimensional conductive MOF; pyridine-vapour annealed film is assigned as (001)-oriented with Cu3(HHTP)2 layers parallel to alpha-Al2O3 (001).p001 · Abstract
Cu3(HHTP)2 conductive MOF nanorods2023 · Controlled synthesis of Cu-/Ni-based 1D c-MOFs and their application in near-linear temperature sensingCu3(HHTP)2Cu nodes; Cu 2p XPS assigned to Cu(I) and Cu(II) centres. · 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP)2D · PristineConjugated hexagonal M3(HHTP)2 lattice with slipped-parallel ab-plane stacking; synthesised as 1D nanorod-like MOF powder.main p.4 · 3.1 Synthesis and characterization · Fig. 4; Fig. 5
Cu3(HHTP)2 copper catecholate conductive MOF2023 · Ligand-Oxidation-Based Anodic Synthesis of Oriented Films of Conductive M-Catecholate Metal-Organic Frameworks with Controllable ThicknessCu3(HHTP)2; HHTP = 2,3,6,7,10,11-hexahydroxytriphenyleneSquare-planar Cu ions linking HHTP catecholate/semiquinonate units; XPS shows mixed Cu(II)/Cu(I) in films. · HHTP2D · PristineLayered 2D conductive metal-catecholate MOF; slipped-parallel AB stacking reported from literature; electrochemical films are [001]/out-of-plane oriented with layers parallel to substrate.main p.2, article p.25571 · Results and Discussion · Fig. 1
Cu3(HHTP)2 nanorods2023 · Controllable Construction of Two-Dimensional Conductive M3(HHTP)2 Nanorods for Electrochemical Sensing of Malachite Green in FishCu3(HHTP)2Cu centres from copper(II) acetate monohydrate. · HHTP2D · PristineRod-like p-d conjugated 2D conductive MOF with AA-stacked sheets and an extended pore network.main p.3, article p.22918 · Preparation of M3(HHTP)2 Nanorod Materials · Figure 1A,A1
Cu3(HHTP)2 two-dimensional conjugated metal-organic framework2023 · 2D metal-organic frameworks for ultraflexible electrochemical transistors with high transconductance and fast response speedsCu3(HHTP)2Copper nodes; XPS indicates coexisting Cu2+ and Cu+ states. · HHTP = 2,3,6,7,10,11-hexahydroxytriphenylene2D · PristineIn-plane hexagonal lattice; preferential [001]-oriented slipped-parallel AB stacking in thin films; vertical nanopores along the out-of-plane direction.main p.1 · Introduction
Cu3(HHTP)2//activated carbon hybrid battery-supercapacitor device2023 · The rise of 2D conductive metal-organic framework: Cu3(HHTP)2 d-π MOF for integrated battery-supercapacitor hybridsCu3(HHTP)2//ACCopper nodes in the Cu3(HHTP)2 positive-electrode component. · HHTP linker in the Cu3(HHTP)2 component; activated carbon negative electrode contains no organic linker.unknown · CompositeAsymmetric hybrid device combining battery-grade Cu3(HHTP)2 positive electrode with capacitive activated-carbon negative electrode.main p.5 · Fig. 4 caption and section 3.3 · Fig. 4
Cu3HHTP2 conductive MOF2023 · Modular conductive MOF-gated field-effect biosensor for sensitive discrimination on the small molecular scaleCu3HHTP2; HHTP = 2,3,6,7,11,12-hexahydroxytriphenyleneCopper nodes; Cu 2p XPS deconvoluted to Cu2+ and Cu+ components at 934.8 and 932.9 eV. · 2,3,6,7,10,11-hexahydroxytriphenylene / HHTP ligand (main text defines HHTP as 2,3,6,7,11,12-hexahydroxytriphenylene in one place).2D · PristineLayered 2D conductive MOF; GIXRD peaks assigned to (100), (200), and (210) ab-plane reflections, implying face-on orientation stacked perpendicular to the substrate in slipped-parallel AB mode.main p.4-5 · 3.1 Characterization of c-MOF thin film electrodes · Fig. 2
CuHHTP conductive MOF2023 · Cu/Co bimetallic conductive MOFs: Electronic modulation for enhanced nitrate reduction to ammoniaCu-HHTP framework; nominal CuHHTPCu-O4 nodes · 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP)2D · Pristine2D extended rigid plane, pi-d conjugated, AA-stacking CuHHTP2 · 3.1 · Fig. 1b
CuHHTP slab model2023 · Cu/Co bimetallic conductive MOFs: Electronic modulation for enhanced nitrate reduction to ammoniaCuHHTP slabCu sites · HHTP2D · Model SystemDFT slab model1.4
Flake-like Cu3(HHTP)22023 · Overcoming Diffusion Limitation of Faradaic Processes: Property-Performance Relationships of 2D Conductive Metal-Organic Framework Cu3(HHTP)2 for Reversible Lithium-Ion StorageCu3(HHTP)2Cu centres coordinated in a planar manner by oxygen atoms from HHTP linkers · 2,3,6,7,10,11-hexahydroxytriphenylene / HHTP2D · PristineLayered 2D conductive MOF; modelled as regular hexagonal sheets with eclipsed stacking and hexagonal P6/mmm refinement for the flake-like morphology.p004 · Results and Discussion · Figure 1; Table S3
monolayer Cu3(HHTP)2 DFT model2023 · A Triptycene-Based 2D MOF with Vertically Extended Structure for Improving the Electrocatalytic Performance of CO2 to Methanemodel of Cu3(HHTP)2CuO4 model sites · HHTP-derived framework model2D · Model SystemPlanarly extended 2D-c-MOF monolayer slab comparator for CO2RR DFT.4-5 · The e-CO2RR Mechanism of 2D-vc-MOF(Cu) · Figure 5; Figure S38
p-type amorphous Cu-HHTP film (p-a-Cu-HHTP)2023 · Self-Powered Infrared Photodetectors with Ultra-High Speed and Detectivity Based on Amorphous Cu-Based MOF FilmsCu-HHTP; nonstoichiometric film with O/Cu about 5/1 by XPSCu2+ coordinated by HHTP; Cu 2p XPS also deconvoluted into Cu(II) and Cu(I) components · 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP)2D · PristineAmorphous Cu-HHTP MOF film with graphite-like 2D layered local structure; broad SAED rings and no crystalline XRD peaks.p001 · Abstract
Rod-like Cu3(HHTP)22023 · Overcoming Diffusion Limitation of Faradaic Processes: Property-Performance Relationships of 2D Conductive Metal-Organic Framework Cu3(HHTP)2 for Reversible Lithium-Ion StorageCu3(HHTP)2Cu centres coordinated in a planar manner by oxygen atoms from HHTP linkers · 2,3,6,7,10,11-hexahydroxytriphenylene / HHTP2D · PristineLayered 2D conductive MOF; modelled as regular hexagonal sheets with tilted stacking and monoclinic C/2m refinement for the rod-like morphology.p004 · Results and Discussion · Figure 1; Table S3
Au-NPs/Cu-HHTP-NSs nanohybrid2022 · Dual nanozyme based on ultrathin 2D conductive MOF nanosheets intergraded with gold nanoparticles for electrochemical biosensing of H2O2 in cancer cellsAu nanoparticles on Cu-HHTP-NSs; approximately 6 wt% Au by ICP-MSCu-O4 nodes in Cu-HHTP plus metallic Au nanoparticles · HHTP linker in Cu-HHTP nanosheets2D · CompositeComposite of ultrathin conductive Cu-HHTP nanosheets decorated with high-density ultrafine Au nanoparticles; Au (111) and (200) peaks observed.1, 3-5 · Abstract; Characterization of Au-NPs/Cu-HHTP-NSs · Fig. 1g-i; Fig. 2a
Conductive Cu-MOF, Cu3(HHTP)22022 · Surface Structure Construction of Fibers in a Conductive Metal-Organic Framework/Metal/Cotton Electrode for Flexible Textile SupercapacitorsCu3(HHTP)2Cu centres in a conductive copper-catecholate framework. · 2,3,6,7,10,11-Hexahydroxytriphenylene (HHTP).2D · CompositeConductive Cu3(HHTP)2 layer assigned by low-angle XRD peaks at 4.8, 9.5, 12.6 and 27.7 degrees, consistent with a previous report.4598 · Results and Discussion · Figure 2b
Cotton/Au/Cu-MOF textile electrode (CPAMOF)2022 · Surface Structure Construction of Fibers in a Conductive Metal-Organic Framework/Metal/Cotton Electrode for Flexible Textile SupercapacitorsCu3(HHTP)2/Au/PDA/cotton compositeCu3(HHTP)2 conductive MOF layer plus Au nanoparticle current collector. · HHTP in Cu3(HHTP)2; polydopamine interlayer on cotton.unknown · CompositeHierarchically porous textile electrode with a thin Au nanoparticle layer and mulberry-like conductive Cu-MOF nanorod layer on primary cotton fibres.4595 · Abstract
Cu-HHTP2022 · Iron-Based 2D Conductive Metal-Organic Framework Nanostructure with Enhanced PseudocapacitanceNot specifiedCu nodes in reported 2D M-HHTP honeycomb analogue · HHTP2D · Pristine2D honeycomb structure confirmed by PXRD for comparison with Fe-HHTP.main p.5 · Results and Discussion · Figure S12
Cu-HHTP2022 · Imparting Functionality and Enhanced Surface Area to a 2D Electrically Conductive MOF via Macrocyclic LinkerCu-HHTPCopper catecholate nodes. · 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP).2D · PristineStructural analogue control with hexagonal pore but without the HHTC alkyne-based intrinsic pocket.main p.5, article p.10619 · Postsynthetic Metalation · Figure S30; Tables S8-S9
Cu-HHTP2022 · Electrically regulating nonlinear optical limiting of metal-organic framework filmCu-HHTP; HHTP = 2,3,6,7,10,11-hexahydroxytriphenyleneCu2+ / copper catecholate nodes · 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP)2D · PristineGraphene-like honeycomb porous layered Cu-HHTP; oriented [001] and [100] thin films assigned by out-of-plane and in-plane XRD.1-3 · Introduction; Characterization · Fig. 2
Cu-HHTP computational models2022 · Electrically regulating nonlinear optical limiting of metal-organic framework filmCu-HHTP model systems; Cu3L2 voltage modelCu centres · HHTP-derived ligand fragments2D · Model SystemDFT models for Cu-HHTP along [001] and [100] orientations plus Cu3L2 applied-voltage model.4, 6, 8 · The third-order NLO test; DFT calculations · Fig. 4e-g; Fig. 5f; Supplementary Figs. 10-14
Cu-HHTP conductive metal-organic framework2022 · Dual nanozyme based on ultrathin 2D conductive MOF nanosheets intergraded with gold nanoparticles for electrochemical biosensing of H2O2 in cancer cellsCu-HHTP; HHTP = 2,3,6,7,10,11-hexahydroxytriphenylene; exact empirical stoichiometry not statedCu-O4 square-planar coordination nodes · HHTP (2,3,6,7,10,11-hexahydroxytriphenylene)2D · PristineTwo-dimensional conductive MOF with layer-stacked nanosheet or bulk morphology; PXRD planes (100), (200), (210), (220) and (112) retained with SDS-assisted nanosheet synthesis.2-4 · Introduction; Results and discussion · Fig. 2a
Cu-HHTP conductive MOF2022 · Dissecting π-conjugated covalent-coupling over conductive MOFs toward efficient two-electron oxygen reductionNot specifiedCu sites; expected Cu1-O4 moieties · 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP)2D · PristineLayered honeycomb-like hexagonal conductive MOF with pi-conjugated Cu-O-C centres; Cu-O coordination number near 3.8 ex situ is consistent with planar Cu1-O4 motifs.3 · 3.1 Morphology and structure characterization · Fig. 1; Table S2
Cu-HHTP phase in hybrid film2022 · Conductive Hybrid Cu-HHTP-TCNQ Metal–Organic Frameworks for Chemiresistive SensingCu-HHTPCu(II) / Cu2+ ions · HHTP2D · PristineAssigned from XRD reflections (100), (200), and (001), and from oxygen-rich filamentous continuous regions.5 · 2.5. X-Ray Diffraction · Figure 3f,g
Cu-HHTP-TCNQ hybrid metal-organic framework film2022 · Conductive Hybrid Cu-HHTP-TCNQ Metal–Organic Frameworks for Chemiresistive SensingCu-HHTP-TCNQCu(II) / Cu2+ ions · 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP); 7,7,8,8-tetracyanoquinodimethane (TCNQ)unknown · CompositeHybrid low-long-range-order coordination polymer/MOF-like film containing Cu-HHTP filamentous continuous regions and Cu-TCNQ(I) cubic crystalline regions, with high amorphous background.2 · Introduction / Results and Discussion
Cu3(HHTP)22022 · Oxidative control over the morphology of Cu3(HHTP)2, a 2D conductive metal-organic frameworkCu3(HHTP)2; HHTP = 2,3,6,7,10,11-hexahydroxytriphenyleneCu catecholate nodes in an extended 2D conductive framework · HHTP tricatecholate linker2D · PristineLayered 2D conductive metal-organic framework; rod, block, and flake products have PXRD patterns matching expected Cu3(HHTP)2.p001 / article p.10472 · Abstract and Introduction
Cu3(HHTP)22022 · Enhancing the energy storage performances of metal-organic frameworks by controlling microstructureCu3(HHTP)2Cu(II)-catecholate nodes in conductive Cu-O framework · HHTP = 2,3,6,7,10,11-hexahydroxytriphenylene2D · PristineLayered conductive MOF formed from pi-d conjugated two-dimensional sheets that stack into an extended three-dimensional pore network; samples show eclipsed/near-eclipsed stacking differences.p002 / journal p9211 · Results & discussion · Fig. 1
Cu3(HHTP)2 composite supercapacitor electrode film2022 · Enhancing the energy storage performances of metal-organic frameworks by controlling microstructure85 wt% Cu3(HHTP)2 + 10 wt% acetylene black + 5 wt% PTFECu nodes from Cu3(HHTP)2 component · HHTP in Cu3(HHTP)2 component2D · CompositeFreestanding composite electrode film retaining the powder microstructures of the Cu3(HHTP)2 component.p005 · Electrode Preparation
Cu3(HHTP)2 conductive metal-organic framework2022 · Conductive metal organic framework for ion-selective membrane-free solid-contact potentiometric Cu2+ sensingCu3(HHTP)2Cu metallic nodes / Cu centres with Cu2+/Cu1+ redox activity discussed for ion-to-electron transduction. · 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP) triphenylene-based organic linker.2D · Pristine2D conductive MOF formed by layer stacking with hexagonal pores; SEM/TEM show nanoscale polyhedron and rod-like crystals; XRD matches reported Cu3(HHTP)2 patterns.p002 · Introduction
Cu3(HHTP)2 conductive metal-organic framework2022 · The Growth Mechanism of a Conductive MOF Thin Film in Spray-based Layer-by-layer Liquid Phase EpitaxyCu3(HHTP)2; growth-cycle films denoted Cu3(HHTP)2-xCCu ions derived from copper acetate · HHTP = 2,3,6,7,10,11-hexahydrotriphenylene / 2,3,6,7,10,11-hexahydroxytriphenylene2D · PristineExtended two-dimensional hexagonal pi-conjugated layers assembled in slipped-parallel ab packing to form a porous honeycomb structure; thin films assigned as c-axis oriented with in-plane hk0 diffraction and out-of-plane 00l diffraction.p002 · Results and Discussion · Scheme 1; Figure S1
Cu3(HHTP)2 conductive metal-organic framework comparison/control2022 · Conjugated Metal-Organic Macrocycles: Synthesis, Characterization, and Electrical ConductivityCu3(HHTP)2Copper-catecholate nodes in a 2D conductive framework. · HHTP = 2,3,6,7,10,11-hexahydroxytriphenylene.2D · Pristine2D honeycomb conductive metal-organic framework with slipped pi-pi stacking between layers.main p.2 · Figure 1 caption · Figure 1
Cu3(HHTP)2 two-dimensional conductive metal-organic framework2022 · Dense Conductive Metal-Organic Frameworks as Robust Electrocatalysts for BiosensingCu3(HHTP)2Square-planar coordinated Cu2+ nodes with mixed Cu+/Cu2+ valence observed by XPS. · 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP).2D · PristineExpected 2D hexagonal conductive MOF; PXRD matched reported/simulated patterns and HRTEM showed ordered lattice fringes and hexagonal meshes.main p.4, article p.17180 · Characterization of 2D cMOFs · Figures 1-2
Cu3(HHTP)2 two-dimensional metal-organic framework2022 · Tunable Carrier Type of a Semiconducting 2D Metal-Organic Framework Cu3(HHTP)2Cu3C36H18O12; abbreviated Cu3(HHTP)2Cu ions coordinated to HHTP ligands; Cu(II)/Cu(I) ratios probed by Cu 2p XPS. · 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP)2D · PristineExtended two-dimensional sheets stacked along the crystallographic c direction; AA-packed sheets with ca. 18 A pores and ca. 3.3 A interlayer spacing.main p.2, article p.12405 · Introduction · Figure 1
Cu3HHTP2 conductive MOF2022 · Wet-Adhesive On-Skin Sensors Based on Metal–Organic Frameworks for Wireless Monitoring of Metabolites in SweatCu3HHTP2Copper nodes in a HHTP-based conductive MOF. · HHTP = 2,3,6,7,10,11-hexahydroxytriphenylene.2D · PristineStructurally analogous Cu-cMOF comparator; PXRD compared with the Ni cMOFs.3 · Results and Discussions · Figure S9
Simulated Cu3(HHTP)2 eclipsed and near-eclipsed structures2022 · Enhancing the energy storage performances of metal-organic frameworks by controlling microstructureCu3(HHTP)2Cu nodes in simulated Cu3(HHTP)2 structures · HHTP2D · Model SystemHexagonal eclipsed P6/mmm and monoclinic near-eclipsed C2/m structures used for XRD/FFT comparison.p008 · Table S1 · Table S1
Cu-HHTP2021 · A comparative study of honeycomb-like 2D π-conjugated metal-organic framework chemiresistors: conductivity and channelsCu3(HHTP)2CuO4 square-planar nodes · HHTP (2,3,6,7,10,11-hexahydroxytriphenylene; source text writes hexahydrotriphenylene)2D · PristineHoneycomb-like 2D pi-conjugated cMOF; hexagonal P6/mmm-type lattice; AB slipped-parallel stacking.p003; article page 13237 · Results and discussion · Fig. 1
Cu-HHTP2021 · Coordination environment dependent selectivity of single-site-Cu enriched crystalline porous catalysts in CO2 reduction to CH4Not specifiedCu-O4 sites · 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP)2D · Pristine2D conductive MOF comparator with Cu-O4 sites; post-test structural transition to Cu2O noted.p005-p006 · ECR performances of crystalline single-site Cu electrocatalysts · Fig. 3a; Supplementary Fig. 17
Cu-HHTP / Cu3(HHTP)22021 · Layer-by-layer assembled dual-ligand conductive MOF nano-films with modulated chemiresistive sensitivity and selectivityCu3(HHTP)2Cu ions / Cu-ligand sheets · 2,3,6,7,10,11-hexahydroxytriphenylene or hexahydrotriphenylene as printed (HHTP, -OH)2D · PristineHoneycomb-like porous framework with 2D hexagonal Cu-ligand layers in the ab plane, slipped-parallel AB stacking along c, and 1D channels.p002 / article p.439 · Results and discussion · Fig. 1
Cu-MOF2021 · Cu-Based Conductive MOF Grown in situ on Cu Foam as a Highly Selective and Stable Non-Enzymatic Glucose SensorCu-HHTP MOF; article does not give a full empirical formulaCu(II) · 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP)2D · PristineConductive copper catecholate MOF built from HHTP and copper acetate; PXRD peaks assigned to (100), (200), (130), (201) and (002) planes.1 · Abstract
Cu-MOF/CF2021 · Cu-Based Conductive MOF Grown in situ on Cu Foam as a Highly Selective and Stable Non-Enzymatic Glucose SensorCu-HHTP MOF grown on Cu foamCu(II) in Cu-MOF; metallic Cu foam substrate · HHTP in the MOF component2D · CompositeComposite/electrode consisting of Cu-MOF nanorod arrays completely and uniformly covering copper foam.7 · Conclusion
Cu3(HHTP)22021 · Insights into the electric double-layer capacitance of two-dimensional electrically conductive metal-organic frameworksCu3(HHTP)2Cu nodes; Cu(II) dominant in as-synthesised powder · HHTP = 2,3,6,7,10,11-hexahydroxytriphenylene2D · PristineLayered pi-d conjugated 2D sheets stacking into a 3D honeycomb pore/channel structure; PXRD compatible with eclipsed and near-eclipsed models, XANES supports near-eclipsed structure.p001 · Abstract; Introduction · Fig. 1
Cu3(HHTP)22021 · Metal-organic framework transistors for dopamine sensingCu3(HHTP)2Cu nodes · HHTP (2,3,6,7,10,11-hexahydroxytriphenylene)2D · PristineSemiconducting 2D conductive MOF film; GIXRD matches reported Cu3(HHTP)2 crystallinity and confirms a 2D honeycomb lattice with preferential [001] oriented growth on glass.p002 / 3423 · Results and discussion · Fig. 1b, Fig. 2b
Cu3(HHTP)22021 · Large-area synthesis of nanoscopic catalyst-decorated conductive MOF film using microfluidic-based solution shearingCu3(HHTP)2Cu nodes · 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP)2D · PristineConductive 2D metal-catecholate framework with rigid pores; PXRD peaks assigned to (100), (200), (210), (220), and (001).2 · Results · Fig. 1
Cu3(HHTP)22021 · Promoting ethylene production over a wide potential window on Cu crystallites induced and stabilized via current shock and charge delocalizationCu3(HHTP)2; HHTP = 2,3,6,7,10,11-hexahydroxytriphenyleneCu nodes · 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP)2D · PristineSimilar semiconductive Cu MOF used to test whether the Ketjen Black effect extends beyond Cu3(HITP)2.8 · Universality of the observations · Supplementary Figs. 30-33
Cu3(HHTP)22021 · Two-Dimensional Conductive Metal-Organic Frameworks as Highly Efficient Electrocatalysts for Lithium-Sulfur BatteriesCu3(HHTP)2Cu transition-metal nodes coordinated by N/O/S donor atoms in the 2D framework · HHTP (2,3,6,7,10,11-hexahydroxytriphenylene; C18H6O6)2D · Model SystemO-coordinated TM3(HHTP)2 kagome 2D MOF; periodic monolayer slab model with kagome sublattice where applicable.PDF p2 / article p.61206 · Introduction
Cu3(HHTP)2 composite electrode film2021 · Insights into the electric double-layer capacitance of two-dimensional electrically conductive metal-organic frameworks85 wt% Cu3(HHTP)2 / 10 wt% acetylene black / 5 wt% PTFECu nodes from Cu3(HHTP)2 · HHTP from Cu3(HHTP)22D · CompositeComposite film containing layered Cu3(HHTP)2 powder plus conductive carbon and PTFE binder.p003 · Results and discussion
Cu3(HHTP)2 two-dimensional metal-organic framework2021 · Electrochemical Synthesis of Large Area Two-Dimensional Metal–Organic Framework Films on Copper AnodesCu3(HHTP)2Cu2+ coordination nodes released from Cu anode or supplied by CuSO4.5H2O for powder control. · HHTP = 2,3,6,7,10,11-hexahydroxytriphenylene.2D · PristineA-A stacked hexagonal 2D framework; GIWAXS peaks assigned to (100), (200), (210), and (002) planes; TEM/SAED show hexagonal lattice and honeycomb-like HRTEM structure.main p.1 · Abstract/Introduction
KB@Cu3(HHTP)22021 · Promoting ethylene production over a wide potential window on Cu crystallites induced and stabilized via current shock and charge delocalizationCu3(HHTP)2 plus Ketjen BlackCu nodes from Cu3(HHTP)2, reconstructed during CO2RR · HHTP-derived residual ligands after reconstruction2D · CompositeConductive carbon-supported Cu3(HHTP)2 composite catalyst.8 · Universality of the observations · Supplementary Fig. 32
Pt@Cu3(HHTP)22021 · Large-area synthesis of nanoscopic catalyst-decorated conductive MOF film using microfluidic-based solution shearingPt@Cu3(HHTP)2Cu nodes plus Pt nanoparticles · 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP)2D · CompositePt nanocatalyst particles embedded within pores of Cu3(HHTP)2; PXRD pattern remains similar to pristine Cu3(HHTP)2.2 · Results · Fig. 1
Cu2O@CuHHTP2020 · Highly Selective CO2 Electroreduction to CH4 by In Situ Generated Cu2O Single-Type Sites on a Conductive MOF: Stabilizing Key Intermediates with Hydrogen BondingCu2O quantum dots on CuHHTPResidual CuHHTP Cu-O4 nodes plus in situ reduced Cu2O(111) sites · HHTP; uncoordinated hydroxyl groups exposed after partial reduction2D · CompositeComposite retaining CuHHTP framework with Cu2O(111) quantum dots; no Cu, CuO or Cu(OH)2 detected in main 30 min sample.p003 / 23643 · Results and Discussion · Figure 1
Cu3(HHTP)22020 · Electrochemical deposition and thermoelectric characterisation of a semiconducting 2-D metal-organic framework thin filmCu3(2,3,6,7,10,11-hexahydroxytriphenylene)2; framework formula reported as Cu3C36H18O12Cu ions / copper catecholate nodes · 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP)2D · Pristine2D hexagonal lattice; honeycomb-like porous structure along c-axis; bulk refined to P6/mmm hexagonal AA model, while Fig. 1 depicts slipped-parallel AB packing.3 · Introduction · Figure 1
Cu3(HHTP)22020 · A Dual-Ligand Porous Coordination Polymer Chemiresistor with Modulated Conductivity and PorosityCu3(C18O6H6)2Cu square-planar nodes · HHTP2D · PristineSingle-ligand hexagonal 2D pi-conjugated EC-MOF used as a literature comparator and possible impurity/control phase.173 · Results and discussion · Figure 1a; Figure S1
Cu3(HHTP)22020 · Quantum spin liquid state in a two-dimensional semiconductive metal−organic frameworkCu3(HHTP)2Cu cations; mainly Cu(II) S = 1/2 with detectable Cu(I) defects · 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP)2D · PristineTwo-dimensional semiconductive metal-organic framework with honeycomb layers and a Kagome lattice arrangement of Cu(II) cations.main p.1 · Introduction · Figure 1
Cu3(HHTP)2 2D conductive MOF2020 · 2D Semiconducting Metal–Organic Framework Thin Films for Organic Spin ValvesCu3(HHTP)2; HHTP = 2,3,6,7,10,11-hexahydroxytriphenyleneCu ions in square-planar coordination; XPS indicates mixed Cu(II)/Cu(I) centres. · Hexadentate HHTP ligands, reported as semiquinonate/catecholate redox states.2D · Pristine2D honeycomb layers with slipped-parallel AB stacking; face-on oriented films on LSMO/STO by GIXRD and simulated PXRD comparison.1119 · Results and Discussion · Figure 1; Figure 2
Cu3(HHTP)2 conductive metal-organic framework2020 · Solid-solid interface growth of conductive metal-organic framework nanowire arrays and their supercapacitor applicationCu3(HHTP)2; HHTP = 2,3,6,7,10,11-hexahydroxytriphenyleneCu(II) centres coordinated to deprotonated HHTP linkers; XPS also shows a weak Cu+ component. · 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP), deprotonated/semiquinone form during formation2D · PristineStacking of 2D hexagonal extended layers in slipped-parallel AB packing; nanowires are described as hexagonal columns assembled from 2D Cu3(HHTP)2 nanosheets.main p.3, article p.245 · Results and discussion; Morphology and structural characterization · Fig. 1b
Cu3(HHTP)2 structural model2020 · 2D Semiconducting Metal–Organic Framework Thin Films for Organic Spin ValvesDFTB+/Material Studio model of Cu3(HHTP)2Modelled Cu nodes in the Cu3(HHTP)2 framework. · Modelled HHTP ligands.2D · Model SystemRelaxed slipped-parallel AB packing model with space group P1.S8 · Section 3. Structure Simulation and Calculation of Crystalline Domain Size · Figure S6; Figure S7; Table S1
CuHHTP2020 · Highly Selective CO2 Electroreduction to CH4 by In Situ Generated Cu2O Single-Type Sites on a Conductive MOF: Stabilizing Key Intermediates with Hydrogen BondingCuHHTP; copper 2,3,6,7,10,11-hexahydroxytriphenylene frameworkCu-O4 nodes; Cu2+ centres coordinated to HHTP/tricatecholate ligand · 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP)2D · PristineCrystalline conductive Cu-based MOF with hexagonal array of 1D pores; PXRD similar to literature.p003 / 23643 · Results and Discussion · Scheme 1; Figure 1
Co3O4@CuCAT core-shell nanowire hybrid2019 · Co 3 O 4 @Cu-Based Conductive Metal–Organic Framework Core–Shell Nanowire Electrocatalysts Enable Efficient Low-Overall-Potential Water SplittingCo3O4@Cu3(HHTP)2Co3O4 core plus Cu sites in CuCAT-derived shell · HHTP-derived CuCAT shell; NMP-derived nitrogen incorporated after coating1D · CompositeCore-shell nanowire-array composite containing BCC substrate, Co3O4, and CuCAT phases; TEM/HRTEM show a CuCAT shell around Co3O4 and XPS/DFT support Cu-O-Co interactions.p002-p003 / journal pp.6576-6577 · Results · Scheme 1; Figure 1
Cu-CAT-12019 · Oriented Thin Films of Electroactive Triphenylene Catecholate-Based Two-Dimensional MetalOrganic FrameworksIdealised Cu3(HHTP)2 / Cu3(C18H6O6)2; exact empirical formula not reported in this paperSquare-planar Cu(II) catecholate nodes within extended 2D sheets. · 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP) tricatecholate linker.2D · PristineLayered triphenylene metal-catecholate Cu-CAT-1; reported to differ slightly from Ni/Co analogues and show split reflections in PXRD.S12 · Characterization of the M-CAT-1 bulk material · Figure S3.2
Cu3(2,3,6,7,10,11-hexahydroxytriphenylene)22019 · Conductive metal–organic framework with redox metal center as cathode for high rate performance lithium ion batteryCu3(HHTP)2Cu2+ single-ion secondary building units; redox-active Cu2+/Cu+ centres · 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP) tricatecholate2D · PristineLayered 2D hexagonal conductive MOF with slipped-parallel stacking along the c-axis.1 · Abstract
Cu3(hexahydroxytriphenylene)22019 · Catalytic Metal Nanoparticles Embedded in Conductive Metal–Organic Frameworks for Chemiresistors: Highly Active and Conductive Porous MaterialsCu3(HHTP)2Cu nodes; open Cu sites discussed as gas adsorption sites · 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP)2D · PristineElectrically conductive 2D extended framework with permanent pores of about 2 nm; XRD shows (200), (210), and (004) planes.p002 · Results and Discussion · Figure 1a
Cu3(HHTP)22019 · Single Crystals of Electrically Conductive Two-Dimensional Metal-Organic Frameworks: Structural and Electrical Transport PropertiesCu3(2,3,6,7,10,11-hexahydroxytriphenylene)2Cu/O coordination nodes in a layered 2D framework. · HHTP, 2,3,6,7,10,11-hexahydroxytriphenylene.2D · PristineLayered conductive 2D MOF; HRTEM/FFT and synchrotron PXRD support tilted/non-eclipsed stacking rather than the Ni3(HITP)2 near-eclipsed model.main p.3-4, article pp.1961-1962 · Results and Discussion · Figures 3 and 4b-c
Cu3(HHTP)22019 · Conductive 2D metal-organic framework for high-performance cathodes in aqueous rechargeable zinc batteriesCu3(HHTP)2; HHTP = 2,3,6,7,10,11-hexahydroxytriphenyleneCu coordination nodes · 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP)2D · PristineHexagonal 2D sheets stacked in a slipped-parallel configuration along the c axis; indexed to space group P6/mmm with large one-dimensional channels.rendered page 2 / article p.2 · Results - Synthesis and characterization of Cu3(HHTP)2 · Figures 1b and 2a
Cu3(HHTP)22019 · Two-dimensional π-conjugated metal-organic framework with high electrical conductivity for electrochemical sensingCu3(HHTP)2Cu(II) centres / Cu2+ nodes · 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP)2D · PristineTwo-dimensional pi-conjugated honeycomb framework with square-planar Cu coordination environments and layered PXRD order.p001 (journal p.522) · Abstract
Cu3(HHTP)2 monolayer model2019 · Conductive 2D metal-organic framework for high-performance cathodes in aqueous rechargeable zinc batteriesCu3(HHTP)2 monolayerCu coordination nodes · HHTP2D · Model SystemDFT monolayer model with approximately 20 A vacuum in z direction; long-range order of bulk Cu3(HHTP)2 was not identified.rendered page 8 / article p.8 · Methods - DFT calculations · Figures 4d and Supplementary Fig. 11
CuCAT / Cu3(HHTP)2 conductive copper MOF2019 · Co 3 O 4 @Cu-Based Conductive Metal–Organic Framework Core–Shell Nanowire Electrocatalysts Enable Efficient Low-Overall-Potential Water SplittingCu3(HHTP)2Open copper sites coordinated to deprotonated HHTP ligands · HHTP = hexahydroxytriphenylene2D · PristineTwo-dimensional hexagonal conductive MOF; PXRD shows successful CuCAT synthesis and retention after immersion in 1 M KOH for 3 days.p002 / journal p.6576 · Introduction
Pd nanoparticle-loaded Cu3(HHTP)22019 · Catalytic Metal Nanoparticles Embedded in Conductive Metal–Organic Frameworks for Chemiresistors: Highly Active and Conductive Porous MaterialsPd@Cu3(HHTP)2Cu nodes in Cu3(HHTP)2 plus embedded Pd/PdO nanoparticles · HHTP2D · CompositePd nanoparticles embedded in the cavities of conductive Cu3(HHTP)2; XRD shows fcc Pd reflections and retained Cu3(HHTP)2 structure.p002 · Results and Discussion · Figure 1b
Pt nanoparticle-loaded Cu3(HHTP)22019 · Catalytic Metal Nanoparticles Embedded in Conductive Metal–Organic Frameworks for Chemiresistors: Highly Active and Conductive Porous MaterialsPt@Cu3(HHTP)2Cu nodes in Cu3(HHTP)2 plus embedded Pt/PtO nanoparticles · HHTP2D · CompositePt nanoparticles embedded in the cavities of conductive Cu3(HHTP)2; XRD shows fcc Pt reflections and retained Cu3(HHTP)2 structure.p002 · Results and Discussion · Figure 1b
Zn-inserted Cu3(HHTP)22019 · Conductive 2D metal-organic framework for high-performance cathodes in aqueous rechargeable zinc batteriesZn3.45[Cu3(HHTP)2] for the overall discharged battery formulaCu coordination nodes with inserted Zn2+ ions · HHTP2D · UnknownGuest-loaded discharged form inferred from Zn insertion into the Cu3(HHTP)2 pores with retained framework diffraction peaks.SI p.10 · Supplementary Note 2
Cu3(HHTP)2 hexagonal MOF2018 · Modular O2 electroreduction activity in triphenylene-based metal-organic frameworksCu3(HHTP)2; HHTP = 2,3,6,7,10,11-hexahydroxytriphenyleneDivalent Cu coordinated by HHTP-derived O donors in a 2D honeycomb lattice. · HHTP / hexahydroxytriphenylene.2D · PristineHexagonal crystal system; 2D honeycomb lattice stacked in a slipped parallel configuration along c.1 · Results and discussion · Fig. 1
Cu3HHTP2 MOF2018 · Conductive Metal-Organic Frameworks as Ion-to-Electron Transducers in Potentiometric SensorsCu3HHTP2Cu · HHTP2D · PristineLayered conductive metal-catecholate MOF; PXRD consistent with slipped parallel packing; XPS shows mixed Cu+/Cu2+ valency.3 · Characterization of M3HHTP2 MOFs · Figures S3-S5
Cu-CAT / Cu-HHTP conductive MOF2017 · Conductive Metal–Organic Framework Nanowire Array Electrodes for High-Performance Solid-State SupercapacitorsCu-CAT; commonly Cu3(HHTP)2Cu ions coordinated to HHTP ligands in the ab plane. · 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP).2D · Pristine2D hexagonal lattice packed along the c-axis with slipped-parallel AB stacking, forming honeycomb-like 1D channels along c.p.2 · Morphology and Structural Analysis · Figure 1a
Cu3(HHTP)2 conductive metal-organic framework2017 · Layer-by-Layer Assembled Conductive Metal–Organic Framework Nanofilms for Room-Temperature Chemiresistive SensingCu3(HHTP)2Cu ions coordinated to HHTP ligands in two-dimensional hexagonal layers. · HHTP = 2,3,6,7,10,11-hexahydroxytriphenylene2D · PristineTwo-dimensional hexagonal layers stacked along the c-axis in a slipped-parallel AB stacking model; honeycomb-like porous structure with one-dimensional channels.main p.1, article p.16510 · Introduction and Figure 1 discussion · Figure 1
Cu3HHTP22017 · Drawing sensors with ball-milled blends of metal-organic frameworks and graphiteCu3(HHTP)2Cu acetate-derived Cu nodes · 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP)2D · Pristineisoreticular 2D M3HHTP2 metal-catecholate framework3 of 17 · Introduction / Results 3.1 · Figure 1A
Cu3HHTP2/graphite blend2017 · Drawing sensors with ball-milled blends of metal-organic frameworks and graphiteCu3(HHTP)2 + graphite, 9:1 MOF:graphite by massCu nodes in MOF component · HHTP in MOF component; graphite conductive additive2D · Compositeball-milled MOF/graphite composite retaining MOF component; graphite (002) peak retained6-7 of 17 · Results 3.2 · Figure 2 and Figure S8
Cu3(HHTP)2 (MOF 1)2015 · Chemiresistive Sensor Arrays from Conductive 2D Metal-Organic FrameworksCu3(HHTP)2Cu square-planar metal centres · HHTP (2,3,6,7,10,11-hexahydroxytriphenylene)2D · PristineConductive layered hexagonal 2D MOF; sheets stack in eclipsed or slipped-parallel conformations with extended 1D pores.main p002 / article page 13781 · Results · Figure 1